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    • 38. 发明公开
    • Highly oriented aromatic polyamide short fiber
    • Hochorientierte Kurzfasern aus aromatischen Polyamiden。
    • EP0104410A2
    • 1984-04-04
    • EP83108182.3
    • 1983-08-18
    • KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY
    • Yoon, Han SikSon, Tae Won
    • D01F6/60D01D5/38D21H13/26C08G69/32
    • D01D5/26C08G69/32D01D5/38D01F6/605D21H13/26Y10T428/2904Y10T428/2913Y10T428/2973Y10T428/2976
    • High oriented poly(p-phenylenetetraphthalamide) short fibers having an inherent viscosity of at least 5.0 and a dimension of 2-12 µm in diameter and 1000-5000 µm in length are provided. Those fibers further have a physical form of irregular cross-sections and needle point-like ends similar to those of natural wood pulp fibers, a crystalline properties such as a crystallinity of more than 50%, an orientation angle of less than 25° and an apparent crystallite size of more than 50A as determined from an X-ray diffractogram scan, and a cross-section with four extinction positions through 360° rotation when observed under a polarizing microscope. These fibers are prepared, without spinning steps, by subjecting the molecular chains of poly(p-phenyleneterephthalamide) to mechanical parallelization during the growth of the chains in a polymerization system therefor cotaining a pyridine/amide-based solvent.
    • 提供具有至少5.0的特性粘度和直径为2-12μm的尺寸和长度为1000-5000μm的高取向聚(对 - 亚硝基邻苯二甲酰胺)短纤维。 这些纤维还具有类似于天然木浆纤维的不规则横截面和针尖端的物理形式,结晶性如结晶度大于50%,取向角小于25°,和 由X射线衍射图扫描确定的超过50个ANGSTROM的表观微晶尺寸,以及在偏光显微镜下观察时具有四个消光位置360°旋转的横截面。 这些纤维在不纺丝步骤的情况下通过使聚(对苯二甲酰对苯二酰胺)的分子链在聚合体系中的链生长过程中机械平行化而制备,从而使吡啶/酰胺类溶剂混合。