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    • 34. 发明公开
    • BICYCLIC ORGANOSILICON COMPOUNDS AS ELECTRON DONORS FOR POLYOLEFIN CATALYSTS
    • BICYCLISCHE SILICIUMORGANISCHE VERBINDUNGEN ALS ELEKTRONENDONATORENFÜRPOLYOLEFINKATALSATOREN
    • EP2419213A4
    • 2013-12-25
    • EP10765029
    • 2010-04-13
    • FORMOSA PLASTICS CORP USA
    • FANG YIQUNLU HONGLAN
    • C08F110/06B01J37/00C07F7/02C07F7/04C08F4/646
    • C08F10/00C07F7/025C07F7/045C08F110/06C08F4/6495C08F4/6465C08F2500/04C08F2500/12
    • Cyclic organosilicon compounds that may be employed as an electron donor for polymerization catalyst systems, polymerization catalyst systems employing the cyclic organosilicon compounds as an electron donor, methods of making the polymerization catalyst systems, and polymerization processes to produce polyolefin are disclosed. The organosilicon compounds, which are useful as electron donors in polymerization catalyst systems for the production of polyolefins, are represented by the formula: where Q1, Q2, Q3, and Q4 may be identical or different and are each hetero-atoms selected from the group consisting of N, O, S, Si, B, and P. R1, R2, R3, and R4 may be identical or different and are each hydrocarbon-based substituents to Q1, Q2, Q3, and Q4, respectively. The subscripts i, j, m, and n are independently 0 to 3. R5 and R6 may be identical or different and are each a bridging group with a backbone chain length between the two hetero-atoms Q1 and Q3, and Q2 and Q4, respectively, 1-8 atoms. The bridging group is selected from the group consisting of aliphatic, alicyclic, and aromatic bivalent radicals.
    • 可以用作聚合催化剂体系的电子给体的循环有机硅化合物,使用环状有机硅化合物作为电子给体的聚合催化剂体系,制备聚合催化剂体系的方法和聚合方法来制备聚烯烃。 可用作聚烯烃生产聚合催化剂体系中的电子供体的有机硅化合物由下式表示:其中Q1,Q2,Q3和Q4可以相同或不同,并且各自是选自基团的杂原子 由N,O,S,Si,B和P组成.R 1,R 2,R 3和R 4可以相同或不同,分别为Q1,Q2,Q3和Q4的烃基取代基。 下标i,j,m和n独立地为0至3.R 5和R 6可以相同或不同,并且各自是在两个杂原子Q1和Q3之间的主链长度以及Q2和Q4的桥连基团, 分别为1-8个原子。 桥连基团选自脂族,脂环族和芳族二价基团。