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31. 发明授权

EP2089463B1 AQUEOUS PROCESS FOR MAKING FLUOROPOLYMERS 有权转让
标题翻译：含水工艺用于生产聚合物FLUOR
公开(公告)号：EP2089463B1
公开(公告)日：2013-02-13
申请号：EP07864661.9
申请日：2007-11-20
申请人： Arkema, Inc.
发明人： AMIN-SANAYEI, Ramin , DURALI, Mehdi , KAPPLER, Patrick , BURCH, Greylan
IPC分类号： C08L27/12 , C08L1/00 , C08F14/18 , C08F2/30 , C08F214/22
CPC分类号： C08F14/18 , C08F214/22 , C08K5/06 , C08L27/16 , C08L71/02 , C08F2/30 , C08F2/20 , C08L27/12 , C08L2666/14

32. 发明公开

EP2513170A1 PROCESS FOR PREPARING A HALOGENATED POLYMER AND DEVICE FOR THE IMPLEMENTATION THEREOF 审中-公开
标题翻译：用于生产卤化聚合物和设备用于实施该方法
公开(公告)号：EP2513170A1
公开(公告)日：2012-10-24
申请号：EP10790950.9
申请日：2010-12-13
申请人： SOLVAY SA
发明人： DE FRANCISCO, Manuel , CLAEYS, Ivan
IPC分类号： C08F14/00 , B01J3/00
CPC分类号： B01J19/242 , B01J3/008 , B01J2219/00006 , B01J2219/00094 , B01J2219/00108 , B01J2219/0011 , B01J2219/00162 , C08F2/04 , C08F14/00 , C08F14/06 , Y02P20/544 , C08F2/20
摘要： Continuous process for preparing a halogenated polymer comprising a step of polymerization of at least one halogenated monomer in a medium comprising carbon dioxide in the liquid or supercritical state, in at least one pressurized reactor, said process comprising at least : - (1) an expansion of the suspension resulting from the reactor; - (2) a separation of the expanded suspension resulting from the reactor into a first stream, containing the solid phase comprising the halogenated polymer and into a liquid, gaseous or supercritical second stream, which is a mixture Of CO2 and of monomer not converted to polymer; and the recovery of this first stream and of this second stream; the expansion (1) of the suspension resulting from the reactor and its separation (2) into first and second streams are carried out in several steps at successively decreasing pressures. - (3) an optional reheating, applied to the expanded suspension, before or after its separation into first and second streams, with optional recovery of the cold energy generated by the expansion; - (4) a recompression of the second stream, and the optional cooling thereof, in order to recycle it to the reactor feed, with a fresh monomer make-up and, possibly, a CO2 make-up; - (5) a final step of degassing the halogenated polymer, optionally in combination with a continuous technique of forming the polymer into granules. Device for implementing the process.

33. 发明公开

EP2513168A1 PROCESS FOR PREPARING A HALOGENATED POLYMER AND DEVICE FOR THE IMPLEMENTATION THEREOF 审中-公开
标题翻译：制备卤化聚合物的方法及其实施方法
公开(公告)号：EP2513168A1
公开(公告)日：2012-10-24
申请号：EP10787799.5
申请日：2010-12-13
申请人： SOLVAY SA
发明人： DE FRANCISCO, Manuel , CLAEYS, Ivan
IPC分类号： C08F14/00 , B01J3/00
CPC分类号： C08F14/00 , B29C47/76 , C08F2/04 , C08F14/06 , Y02P20/544 , C08F2/20
摘要： Continuous process for preparing a halogenated polymer comprising a step of polymerization of at least one halogenated monomer in a medium comprising carbon dioxide in the liquid or supercritical state (L/SC-CO2), in at least one pressurized reactor, said process comprising at least: - (1) an expansion of the suspension resulting from the reactor; - (2) a separation of the expanded suspension resulting from the reactor into a first stream, containing the solid phase comprising the halogenated polymer and into a liquid, gaseous or supercritical second stream, which is a mixture of CO2 and of monomer not converted to polymer; and the recovery of this first stream and of this second stream; - (3) an optional reheating, applied to the expanded suspension, before or after its separation into first and second streams, with optional recovery of the cold energy generated by the expansion; - (4) a recompression of the second stream and the optional cooling thereof in order to recycle it to the reactor feed, with a fresh monomer make-up and, possibly, a CO2 make-up; - a final step (5) of degassing the halogenated polymer, combined with a continuous technique of forming the polymer into granules. Device for implementing the process.
摘要翻译：用于制备卤化聚合物的连续方法，其包括在至少一个加压反应器中在包含液态或超临界态（L / SC-CO2）的二氧化碳的介质中聚合至少一种卤代单体的步骤，所述方法至少包括：（1）由反应器产生的悬浮液的膨胀; - （2）将由反应器产生的膨胀悬浮液分离成含有含卤化聚合物的固相的第一物流和分离成液体，气体或超临界第二物流，该第二物流是CO2和未转化成单体的混合物聚合物; 并回收这第一股流和这第二股流; - （3）在分离成第一和第二物流之前或之后，对膨胀的悬浮液进行任选的再加热，同时可任意回收由膨胀产生的冷能; - （4）第二物流的再压缩和其任选的冷却以将其再循环到反应器进料中，其中新鲜的单体构成和可能的CO 2构成; - 脱卤卤化聚合物的最后一步（5），以及将聚合物形成颗粒的连续技术。实施过程的设备。

34. 发明公开

EP2401304A4 POLYMER PARTICLES 审中-公开
标题翻译：聚合物粒子
公开(公告)号：EP2401304A4
公开(公告)日：2012-09-05
申请号：EP10745726
申请日：2010-02-24
申请人： UNIV SYDNEY
发明人： HAWKETT BRIAN STANLEY , PHAM THI THUY BINH , SUCH CHRISTOPHER HENRY
IPC分类号： C08F2/22 , C08F257/00 , C08F279/06 , C08F287/00
CPC分类号： C08F2/20 , C08F2/38 , C08F285/00 , C08F287/00 , C08F293/005 , C08F2438/03 , C08L2666/02 , C09D151/003 , C09J151/003 , C08F212/08 , C08F220/14 , C08F212/36
摘要： The present invention relates to a method of forming polymer on the surface of polymer particles, the method comprising: (i) providing a dispersion comprising a continuous aqueous phase, a dispersed organic phase comprising one or more ethylenically unsaturated monomers, and a RAFT agent as a stabiliser for said organic phase; (ii) polymerising the one or more ethylenically unsaturated monomers under the control of the RAFT agent to form an aqueous dispersion of seed polymer particles; (iii) crosslinking the seed polymer particles; (iv) swelling the crosslinked seed particles with one or more ethylenically unsaturated monomers to form an aqueous dispersion of monomer swollen crosslinked seed polymer particles; (v) increasing the temperature of the monomer swollen crosslinked seed polymer particles to expel at least some of the monomer therein onto the surface of the particles; and polymerising at least the expelled monomer to form polymer on the surface of the particles.

35. 发明授权

EP2285850B1 PROCEDE DE PREPARATION D'UNE DISPERSION DE PARTICULES POLYMERIQUES EN MILIEU AQUEUX 有权
标题翻译：一种用于生产聚合物粒子分散在水介质中
公开(公告)号：EP2285850B1
公开(公告)日：2012-06-20
申请号：EP09761918.3
申请日：2009-05-19
申请人： Arkema France , Centre National de la Recherche Scientifique , UNIVERSITE PIERRE ET MARIE CURIE (PARIS 6)
发明人： DIRE, Charlotte , CHARLEUX, Bernadette , MAGNET, Stéphanie , COUVREUR, Laurence
IPC分类号： C08F293/00 , C08F2/16
CPC分类号： C08F2/20 , C08F2/38 , C08F293/005 , C08F2438/02 , C08L53/00 , C08L2666/02 , C09D153/00 , C09J153/00
摘要： The invention relates to a method for preparing an aqueous dispersion of polymer particles in an aqueous medium using a living macro-primer requiring a re-priming temperature lower than 1000°C. The particles thus obtained can be used in the field of surface coatings.

36. 发明授权

EP2048165B1 PROCESS FOR PRODUCING FINE POLYMER PARTICLE 有权
标题翻译：制备细聚合物
公开(公告)号：EP2048165B1
公开(公告)日：2011-09-14
申请号：EP07768247.4
申请日：2007-07-05
申请人： Toagosei Co., Ltd
发明人： MATSUZAKI, Hideo c/o TOAGOSEI CO., LTD. , GOTOU, Akihiro c/o TOAGOSEI CO., LTD. , MIZUNO, Tomotaka c/o TOAGOSEI CO., LTD. , KAAI, Michihiro c/o TOAGOSEI CO., LTD.
IPC分类号： C08F2/20 , C08F220/06 , C08F228/02 , C08F290/04
CPC分类号： C08F2/20 , C08F220/06 , C08F220/58 , C08F222/1006 , C08F265/00 , C08F265/04 , C08F290/04 , C08F290/06 , C08F290/061
摘要： [PROBLEMS] To provide a process by which fine polymer particles having evenness of particle diameter in the range of several micrometers to several tens of micrometers are produced by suspension polymerization with satisfactory productivity while preventing the particles from coagulating, agglomerating, sedimenting, or adhering to the polymerizer and while maintaining a satisfactory stable dispersion state. [MEANS FOR SOLVING PROBLEMS] The process, which is for producing fine polymer particles by suspension-polymerizing a vinyl monomer, comprises using a macromonomer comprising a polymer derived from a vinyl monomer and having a radical-polymerizable unsaturated group at an end thereof as a dispersion stabilizer to conduct the suspension polymerization of a vinyl monomer.

37. 发明公开

EP1832607A4 CROSSLINKED POLYMER PARTICLE AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：网络化聚合物及其制造方法
公开(公告)号：EP1832607A4
公开(公告)日：2011-09-07
申请号：EP05822683
申请日：2005-12-28
申请人： KANEKA CORP
发明人： MORI TOSHIYUKI , FUJITA KOJI , USHIZAKI KOSHIN
IPC分类号： C08F8/12 , A61M1/02 , A61M1/36 , B01J20/26 , C08F2/20 , C08F216/06 , C08F218/04 , C08F218/08 , C08F220/14 , C08F220/28 , C08F226/06 , C08F265/06
CPC分类号： B01J20/26 , A61M1/3679 , C08F2/20 , C08F8/12 , C08F218/08 , C08F226/02 , C08F226/06 , C08F265/06 , C08F2222/1013 , C08F220/28
摘要： Crosslinked polymer particles that are useful as an adsorbent, or carrier thereof, for treatment of a liquid containing physiological substance and/or cells, etc., such as body fluid, and that is reduced in the activation of complement system and leukocytes; and a process for producing polymer particles being useful as an adsorbent/ treating material, or carrier thereof, for treatment of body fluid. In particular, there are provided crosslinked polymer particles comprising as a constituent a polymerization unit containing a vinyl alcohol unit and nitrogen-containing polymerization unit, wherein the content of nitrogen base on the whole weight of grains in the dry state as determined by elementary analysis is in the range of 7.0 to 13.0 weight %, and wherein the surface nitrogen content determined by X-ray photoelectron spectroscopy (XPS) is in the range of 5.0 to 15.0 at%. Further, there are provided crosslinked polymer particles of 50 to 3000 µm volume average particle diameter, of which ‰¥80 volume % particles have a diameter of 0.8 to 1.2 times the volume average particle diameter, obtained by first forming liquid drops of uniform diameter consisting of a monomer mixture in a dispersion medium and subsequently polymerizing the liquid drops under conditions avoiding cohesion or additional dispersion thereof, optionally further conducting treatment or modification; and is provided a relevant process for producing polymer particles.

38. 发明公开

EP2344549A1 FLUORO OLEFIN POLYMERIZATION 审中-公开
标题翻译：氟烯烃聚合
公开(公告)号：EP2344549A1
公开(公告)日：2011-07-20
申请号：EP09753292.3
申请日：2009-11-06
申请人： E. I. du Pont de Nemours and Company
发明人： PENG, Sheng , HUNG, Ming-Hong , JUNK, Christopher, P.
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F2/20
摘要： A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, wherein said polymerization agent is a compound of the formula (I): R
1 -O-(CF
2 )
n -COOX (I) wherein R
f is CF
3 CF
2 CF
2 -, n is an integer equal to 3, 5 or 7, and X is H, NH
4 , Li, Na or K.

39. 发明公开

EP2341084A1 Redispersible polymer powders stabilized with protective colloid compositions 有权转让
标题翻译： Mit ut ver ver ver ver ver ver ver ver ver ver ver ver ver ver ver ver ver ver ver
公开(公告)号：EP2341084A1
公开(公告)日：2011-07-06
申请号：EP10193622.7
申请日：2010-12-03
申请人： DOW Chemical Company
发明人： Bergman, Roger , Kalantar, Thomas , Harris, Keith , Kim-Habermehl, Linda , Ladika, Mladen , Hong, Liang
IPC分类号： C08F2/22 , C08F2/20
CPC分类号： C08F2/20 , C04B28/04 , C04B40/0042 , C04B2103/0057 , C04B2111/00637 , C08F2/22 , C08F4/40 , C08F212/08 , C08F236/10 , C08F222/02 , C04B2103/0053 , C04B2103/0066 , C04B2103/0086 , C04B24/04 , C04B24/12 , C04B24/121 , C04B24/123 , C04B24/163 , C04B24/18 , C04B24/2611 , C04B24/2623 , C04B24/2641 , C04B24/2652 , C04B24/2676 , C04B24/281 , C04B24/282 , C04B24/283 , C04B24/32 , C04B24/383 , C04B14/06 , C04B40/0608
摘要： A water redispersible polymer powder is produced by drying an aqueous mixture of a water insoluble film-forming polymer and a colloidal stabilizer which includes a chelating agent and at least one water soluble polymer. The amount of chelating agent is at least 0.1% by weight, based upon the weight of the water insoluble film-forming polymer, and the amount of the at least one water soluble polymer is at least 0.1% by weight, based upon the weight of the water insoluble film-forming polymer. Dispersions or polymer compositions containing a chelating agent and water soluble polymer as a colloidal stabilizer exhibit an unexpectedly low viscosity which facilitates spray drying and permits use of high solids content dispersions with low pressure spray drying to increase production efficiency. The colloidal stabilizer composition provides unexpectedly superior redispersibility for water insoluble film-forming polymers having very low carboxylation levels.
摘要翻译：通过干燥包含螯合剂和至少一种水溶性聚合物的水不溶性成膜聚合物和胶体稳定剂的水性混合物来制备水可再分散聚合物粉末。基于水不溶性成膜聚合物的重量，螯合剂的量为至少0.1重量％，至少一种水溶性聚合物的量为至少0.1重量％，基于水不溶性成膜聚合物。含有螯合剂和水溶性聚合物作为胶体稳定剂的分散体或聚合物组合物表现出意想不到的低粘度，其有助于喷雾干燥，并允许在低压喷雾干燥下使用高固体含量的分散体以提高生产效率。胶体稳定剂组合物为具有非常低的羧化水平的水不溶性成膜聚合物提供出人意料的优异的再分散性。

40. 发明授权

EP2087018B1 AQUEOUS POLYMERIZATION OF FLUORINATED MONOMERS USING POLYMERIZATION AGENT COMPRISING FLUOROPOLYETHER ACID OR SALT AND SILOXANE SURFACTANT 有权
标题翻译：水性聚合的含氟单体使用具有FLUORPOLYETHERSÄUREOR和聚合或其盐的硅氧烷
公开(公告)号：EP2087018B1
公开(公告)日：2011-05-25
申请号：EP07840003.3
申请日：2007-11-09
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： BROTHERS, Paul Douglas , GANGAL, Subash Vishnu
IPC分类号： C08F2/20 , C08F14/18
CPC分类号： C08F14/18 , C08F214/262 , C08F2/16 , C08F2/20
摘要： A process for polymerizing at least one fluorinated monomer in an aqueous polymerization medium in the presence of initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer having a fluoropolymers solids content of at least about 10% by weight. The polymerization agent is a combination of fluoropolyether acid or salt thereof and siloxane surfactant. The aqueous polymerization medium contains less than about 300 ppm of perfluoroalkane carboxylic acid or salt fluorosurfactants.

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