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    • 32. 发明授权
    • RADICALLY CURABLE RESIN COMPOSITIONS
    • 自由基固化型树脂组合物
    • EP1756190B1
    • 2009-01-21
    • EP05735073.8
    • 2005-04-06
    • DSM IP Assets B.V.
    • JANSEN, Johan Franz Gradus AntoniusDRIESSEN, Marco, Marcus, MatheusVAN DIJCK, Michael, Alphonsus, Cornelis, Johannes
    • C08G61/00C08G75/00
    • C08G61/00C08G61/02
    • The present invention relates to resin compositions for radical curing comprising a component (I) containing reactive carbon-carbon unsaturations and a component (ll) containing XH-groups, with X not being C or O., which resin compositions (a) are substantially free of photoinitiators; (b.) have an average number of reactive carbon-carbon unsaturations of component (I) higher than 2; (c) have an average number of XH-groups of component (II) equal to or higher than 2, with at least one of the XH-groups of the XH-component being a thiol group, and; (d) whereby at least one of the average numbers of (b) and (c) is higher than 2; (e) and at most 5 mol% of the reactive unsaturations is capable of undergoing homopolymerisation; (f) respectively is present in the form of a mono-ene functional alkylene; and (g) the molar ratio of the XH-groups and of the reactive unsaturations is in the range of from 4 : 1 to 1 : 4; with the proviso that the RU component is not tris-(norborn-5-ene-2-carboxy) propoxypropane. The present invention also relates to processes for curing such resin compositions, in particular by cold curing. And finally, the present invention also relates to a new process for the synthesis of Diels-Alder adducts of cyclopentadiene and a resin component containing telechelic carbon-carbon unsaturation. The resin compositions are capable of providing constructive materials with tack-free surfaces by fast, and tunable, radical curing, and without any problems of so-called oxygen inhibition. Suitable applications are in chemical anchoring, roofing, flooring, (re)-lining, SMCs and BMCs.
    • 38. 发明公开
    • 2K THERMOSETTING POWDER COATING COMPOSITIONS
    • 2K-WÄRMEHÄRTENDEPULVERFÖRMIGEBESCHICHTUNGSZUSAMMENSETZUNGEN
    • EP3155051A1
    • 2017-04-19
    • EP15718167.8
    • 2015-04-08
    • DSM IP Assets B.V.
    • BONGAERTS, Johannes Gertrudis ChristianusWELLENBERG, Petrus Henricus MarinusJANSEN, Johan Franz Gradus Antonius
    • C09D5/03C09D15/00C09D167/06
    • C09D5/033B05D3/06C08K3/10C08K3/11C08K5/0025C08K5/14C09D15/00C09D167/06C08L67/06
    • The invention relates to a thermosetting powder coating composition C (PCC C) comprising a physical mixture of a thermosetting powder coating composition A (PCC A) with a separate, distinct thermosetting powder coating composition B (PCC B). The invention further relates to a process for making said thermosetting powder coating composition C and processes for coating an article with said thermosetting powder coating composition C. The invention further relates to a cured thermosetting powder coating composition C (c-PCC C). The invention further relates to an article having coated thereon said thermosetting powder coating composition C as well as to an article having coated and cured thereon said thermosetting powder coating composition C. The invention further relates to the use of PCC C for heat-curing at low temperatures. The invention relates also to a use of PCC C for making a cured PCC C, preferably said cured PCC C is a powder coating having one or multiple of properties such as excellent resistance to swelling, good smoothness, good chemical resistance, low gloss, low yellowness, in any combination. The invention further relates to the use of said thermosetting powder coating composition C, to the use of an article having coated thereon said thermosetting powder coating composition C and to the use of an article having coated and cured thereon said thermosetting powder coating composition C.
    • 本发明涉及一种热固性粉末涂料组合物C(PCC C),其包含热固性粉末涂料组合物A(PCC A)与独立的不同的热固性粉末涂料组合物B(PCC B)的物理混合物。 本发明还涉及制备所述热固性粉末涂料组合物C的方法和用所述热固性粉末涂料组合物C涂覆制品的方法。本发明还涉及固化的热固性粉末涂料组合物C(c-PCC C)。 本发明还涉及一种在其上涂覆有热固性粉末涂料组合物C的物品,以及在其上涂覆和固化其上的热固性粉末涂料组合物C的制品。本发明还涉及PCC C在低温下的热固化 温度。 本发明还涉及PCC C用于制造固化PCC C的优点,优选所述固化的PCC C是具有优异的耐溶胀性,良好的平滑性,良好的耐化学性,低光泽度,低光泽等一个或多个特性的粉末涂料 黄色,任意组合。 本发明还涉及所述热固性粉末涂料组合物C在使用其上涂覆有所述热固性粉末涂料组合物C的制品的用途,以及在其上涂覆并固化其上的热固性粉末涂料组合物C的用途。