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    • 31. 发明公开
    • Superhigh purity ionic liquid
    • Hochreine ionischeFlüssigkeiten
    • EP1707265A1
    • 2006-10-04
    • EP06002975.8
    • 2006-02-14
    • DAI-ICHI KOGYO SEIYAKU CO., LTD.
    • Uchimura, HirofumiKikuta, Manabu
    • B01J35/12C07D233/54
    • C07D233/54B01J35/12H01G11/20H01G11/60H01G11/62
    • An ionic liquid with an extremely low content of an impurity such as halogen ions which can be obtained easily at a relatively reduced cost, the ionic liquid comprising a pair of a cation K + and an anion A - represented by the general formula (1) in which the content of an alkali metal as an impurity is 5 ppm or less and the content of a halogen ion is 1 ppm or less, the cation being preferably selected from the group represented by the following general formula (2) obtained by quarternizing a tertiary amine compound or a tertiary phosphine compound by using an acid ester represented by the following general formula (3) and then conducting salt exchange:
      General formula (2):



      General formula (3): ROY



      in which R 1 to R 4 in the formula (2) each independently represents a linear or branched alkyl group of 1 to 8 carbon atoms, X represents a hetero atom and R in the formula (3) represents a linear or branched alkyl group of 1 to 8 carbon atoms.
    • 作为能够以相对降低的成本容易地获得的杂质如卤素离子含量极低的离子液体,由通式(1)表示的一对阳离子K +和阴离子A, 其中作为杂质的碱金属的含量为5ppm以下,卤素离子的含量为1ppm以下,所述阳离子优选选自下述通式(2)表示的基团,其通过季铵化 叔胺化合物或叔膦化合物,通过使用下述通式(3)表示的酸酯,然后进行盐交换:通式(2):通式(3):其中R 1〜R 4在 式(2)各自独立地表示1〜8个碳原子的直链或支链烷基,X表示杂原子,式(3)中的R表示碳原子数为1〜8的直链或支链烷基。
    • 39. 发明公开
    • Brominated polyphenylene oxide and its use as flame retardant
    • Bromiertes Polyphenenoxid und dessen Verwendung als Flammschutzmittel
    • EP1391475A1
    • 2004-02-25
    • EP03013723.6
    • 2003-06-17
    • DAI-ICHI KOGYO SEIYAKU CO., LTD.
    • Onishi, Hideaki
    • C08G65/38C08L71/12C09K21/14
    • C09K21/14C08G65/485
    • A brominated polyphenylene oxide having a molecular skeleton obtained by condensing tribromophenols and satisfying the requirements: (A) its 20 wt.% solution in chloroform has an absorbance at 600 nm of not larger than 0.6; (B) when 50 ml of ion-exchanged water is added to its 1.00 g/30 ml solution in dioxane, the resulting solution has an electroconductivity of not larger than 10 µS/cm measured at 25°C; and (C) when a mixture comprised of 20 % by weight of the brominated polyphenylene oxide and 80 % by weight of triphenyl phosphate is heated at 280°C for 20 minutes, the halide ion increase therein is not larger than 10 µmols per gram of the brominated polyphenylene oxide, is used as a flame retardant. When it is added to resin, the resin moldings are excellent in its flame retardancy, electric properties, physical properties, thermal stability and appearance (color hue), and they do not corrode molds.
    • 具有分子骨架的溴化聚苯醚,其通过使三溴酚缩合并满足以下要求:(A)其20重量%氯仿溶液中的吸光度在600nm处不大于0.6; (B)当向其1.00g / 30ml二恶烷溶液中加入50ml离子交换水时,得到的溶液在25℃下测得的电导率不大于10μS/ cm; 和(C)当将由20重量%的溴化聚苯醚和80重量%的磷酸三苯酯组成的混合物在280℃下加热20分钟时,其中的卤离子增加量不大于10克/克 的溴化聚苯醚,用作阻燃剂。 当树脂加入树脂时,其阻燃性,电性能,物理性能,热稳定性和外观(色调)优异,并且不会腐蚀模具。