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    • 22. 发明公开
    • ION EXCHANGE MEMBRANE FOR ALKALI CHLORIDE ELECTROLYSIS, AND ALKALI CHLORIDE ELECTROLYSIS APPARATUS
    • IONENAUSTAUSCHERMEMBRANFÜRALKALICHLORID-ELEKTROLYSE UND ALKALICHLORID-ELEKTROLYSEVORRICHTUNG
    • EP3184671A4
    • 2017-08-23
    • EP15834315
    • 2015-08-20
    • ASAHI GLASS CO LTD
    • KANEKO TAKAYUKIKUSANO HIROMITSUYAMAKI YASUSHINISHIO TAKUO
    • C25B1/46B01J39/00B01J39/20B01J47/12C08J5/22C25B13/08
    • C25B13/08B01J39/20B01J47/12C08J5/22C08J5/2281C08J2327/18C08J2329/10C08J2427/18C08J2467/00C25B1/46C25B9/00
    • To provide an ion exchange membrane for alkali chloride electrolysis, which has low membrane resistance and which reduces the electrolysis voltage during alkali chloride electrolysis, even if the spacing between reinforcing yarns is made narrow to increase the membrane strength. This ion exchange membrane 1 for alkali chloride electrolysis comprises a fluoropolymer containing ion exchange groups; a reinforcing material embedded in the fluoropolymer and formed of reinforcing yarns and optionally contained sacrificial yarns; and elution holes of the sacrificial yarns present between the reinforcing yarns, wherein in a cross section perpendicular to the length direction of the reinforcing yarns forming the reinforcing material, the average distance (d1) from the center of a reinforcing yarn 22 to the center of the adjacent reinforcing yarn 22 is from 750 to 1,000 µm, the total area (S) obtained by adding the cross-sectional area of an elution hole 28 and the cross-sectional area of a sacrificial yarn 24 remaining in the elution hole 28 is from 500 to 5,000 µm 2 per elution hole, and the number n of elution holes 28 between adjacent reinforcing yarns 22 is from 4 to 6.
    • 为了提供碱金属氯化物电解用的离子交换膜,即使增强线之间的间隔变窄以增加膜强度,其具有低的膜电阻并降低碱金属氯化物电解期间的电解电压。 该碱金属氯化物电解用离子交换膜1包含含有离子交换基团的含氟聚合物, 嵌入含氟聚合物中并由增强纱线和任选含有牺牲纱线形成的增强材料; 和存在于增强纱线之间的牺牲纱线的洗脱孔,其中在与形成增强材料的增强纱线的长度方向垂直的横截面中,从增强纱线22的中心到中心的平均距离(d1) 相邻的增强纱线22为750〜1000μm,将洗脱孔28的截面积与留在洗脱孔28内的牺牲纱线24的截面积相加得到的总面积(S)为 每个洗脱孔500-5,000μm2,并且相邻增强纱线22之间的洗脱孔28的数量n为4-6。
    • 24. 发明公开
    • ION EXCHANGE MEMBRANE FOR ALKALI CHLORIDE ELECTROLYSIS, AND ALKALI CHLORIDE ELECTROLYSIS APPARATUS
    • 氯化碱电解用离子交换膜和氯化碱电解装置
    • EP3184671A1
    • 2017-06-28
    • EP15834315.2
    • 2015-08-20
    • Asahi Glass Company, Limited
    • KANEKO, TakayukiKUSANO, HiromitsuYAMAKI, YasushiNISHIO, Takuo
    • C25B13/08B01J39/00B01J47/12C08J5/22C25B9/00
    • To provide an ion exchange membrane for alkali chloride electrolysis, which has low membrane resistance and which reduces the electrolysis voltage during alkali chloride electrolysis, even if the spacing between reinforcing yarns is made narrow to increase the membrane strength. This ion exchange membrane 1 for alkali chloride electrolysis comprises a fluoropolymer containing ion exchange groups; a reinforcing material embedded in the fluoropolymer and formed of reinforcing yarns and optionally contained sacrificial yarns; and elution holes of the sacrificial yarns present between the reinforcing yarns, wherein in a cross section perpendicular to the length direction of the reinforcing yarns forming the reinforcing material, the average distance (d1) from the center of a reinforcing yarn 22 to the center of the adjacent reinforcing yarn 22 is from 750 to 1,000 µm, the total area (S) obtained by adding the cross-sectional area of an elution hole 28 and the cross-sectional area of a sacrificial yarn 24 remaining in the elution hole 28 is from 500 to 5,000 µm 2 per elution hole, and the number n of elution holes 28 between adjacent reinforcing yarns 22 is from 4 to 6.
    • 为了提供碱金属氯化物电解用的离子交换膜,即使增强线之间的间隔变窄以增加膜强度,其具有低的膜电阻并降低碱金属氯化物电解期间的电解电压。 该碱金属氯化物电解用离子交换膜1包含含有离子交换基团的含氟聚合物, 嵌入含氟聚合物中并由增强纱线和任选含有牺牲纱线形成的增强材料; 和存在于增强纱线之间的牺牲纱线的洗脱孔,其中在与形成增强材料的增强纱线的长度方向垂直的横截面中,从增强纱线22的中心到中心的平均距离(d1) 相邻的增强纱线22为750〜1000μm,将洗脱孔28的截面积与留在洗脱孔28内的牺牲纱线24的截面积相加得到的总面积(S)为 每个洗脱孔500-5,000μm2,并且相邻增强纱线22之间的洗脱孔28的数量n为4至6。
    • 30. 发明公开
    • WATER TREATMENT METHOD AND APPARATUS
    • WASSERBEHANDLUNGSVERFAHREN UND -VORRICHTUNG
    • EP2029490A1
    • 2009-03-04
    • EP07733056.1
    • 2007-06-04
    • OTV SA
    • MORTIMER, Alan DentonEMERY, Nigel PhilipWHITEHEAD, PaulWALKER, John Andrew
    • C02F1/42C02F1/469B01J39/00B01J47/00
    • C02F1/469B01J47/016B01J47/08C02F1/4695
    • A method of manufacturing a water treatment apparatus having one or more chambers comprising the step of: filling at least one chamber with ion exchanger resin; wherein at least one ion exchanger resin is dry. Preferably, the dry ion exchange resin has a water content of 0-40 wt%, preferably 0-20 wt%, and more preferably 0-10 wt%, such that the volume of the dry ion exchange resin is 25-50 vol% less than the volume of the same ion exchange resin in a moist or wetted form. One form of suitable water treatment apparatus is an EDI apparatus comprising a plurality of chambers to form a stack, for the purification of the water. The present invention provides an easier method of filling of chambers compared with the use of wetted or moist resins, and 'over filling' of the cells of water treatment apparatus, in order to achieve results desired, and a greater flexibility of performance parameters.
    • 一种制造具有一个或多个室的水处理设备的方法,包括以下步骤:用离子交换树脂填充至少一个室; 其中至少一种离子交换树脂是干的。 优选地,干燥离子交换树脂的水含量为0-40重量%,优选为0-20重量%,更优选为0-10重量%,使得干燥离子交换树脂的体积为25-50体积% 小于潮湿或湿润的相同离子交换树脂的体积。 合适的水处理装置的一种形式是EDI装置,其包括多个室以形成堆叠,用于净化水。 与使用湿润树脂或潮湿树脂相比,本发明提供了一种更容易的填充室的方法,以及“过度填充”水处理设备的单元。