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    • 22. 发明公开
    • Dispersion stablizer for suspension polymerization of vinyl compound
    • Dispersionsstabilisatorfürdie Suspensionpolymerise von Vinyl-Verbindungen
    • EP1174444A1
    • 2002-01-23
    • EP01117140.2
    • 2001-07-13
    • Kuraray Co., Ltd., Kurashiki Plant
    • Kato, MasakiInomata, NaokiyoTanimoto, Seiji
    • C08F14/06C08F2/20C08F261/04C08L29/04
    • C08F261/04C08F2/20C08F14/06C08L29/04C08L2666/04
    • The invention discloses a dispersion stabilizer for suspension polymerization of a vinyl compound comprising a vinyl alcohol polymer (A) having a content of an ethylene unit of 0.5 to 10 mol%, a degree of saponification of 60 mol% or more and a degree of polymerization of 600 or more and a vinyl alcohol polymer (B) selected from a vinyl alcohol polymer (B1) having a content of an ethylene unit of 0.5 to 10 mol%, a degree of saponification of 20 to 80 mol% and a degree of polymerization of 100 to 600, a vinyl alcohol polymer (B2) having a degree of saponification of 20 to 60 mol% and a degree of polymerization of 100 to 600 and a vinyl alcohol polymer (B3) having a content of an ethylene unit of 0.5 to 10 mol%, a degree of saponification of 90 mol% or more and a degree of polymerization of 1,000 or more. Further, the invention discloses a process for suspension polymerization of a vinyl compound using the dispersion stabilizer for suspension polymerization.
      The dispersion stabilizer for suspension polymerization of the vinyl compound in the invention, by the use of a small amount, exhibits quite an excellent suspension polymerization stability. Further, the suspension polymerization of a vinyl compound using this dispersion stabilizer can produce porous vinyl polymer granules having a sharp particle size distribution and a high bulk density. In the polymer granules, a rate of plasticizer absorption is high to give a high processability, a monomer remaining in polymer granules is easy to remove, and fish eyes in a molded product are decreased in the molding.
    • 本发明公开了一种乙烯基化合物的悬浮聚合用分散稳定剂,其含有乙烯单元的含量为0.5〜10摩尔%,皂化度为60摩尔%以上且聚合度的乙烯醇系聚合物(A) 为600以上,乙烯醇系聚合物(B)选自乙烯单元为0.5〜10摩尔%,皂化度为20〜80摩尔%的乙烯醇系聚合物(B1)和聚合度 为100〜600,皂化度为20〜60摩尔%,聚合度为100〜600的乙烯醇系聚合物(B2)和乙烯单元的含量为乙烯单元的乙烯醇系聚合物(B3)为0.5〜 10摩尔%,皂化度为90摩尔%以上,聚合度为1000以上。 此外,本发明公开了使用悬浮聚合用分散稳定剂的乙烯基化合物的悬浮聚合方法。 本发明中的乙烯基化合物的悬浮聚合用分散稳定剂,通过使用少量,具有非常优异的悬浮聚合稳定性。 此外,使用该分散稳定剂的乙烯基化合物的悬浮聚合可以制造具有尖锐的粒度分布和高堆积密度的多孔乙烯基聚合物颗粒。 在聚合物颗粒中,增塑剂吸收率高,可以提高加工性,聚合物颗粒中残留的单体易于除去,成型体中的成型品中的鱼眼降低。
    • 23. 发明公开
    • Vinyl acetate based polymer latex composition, especially for adhesives
    • 聚合物胶乳Zusammensetzung auf Basis von Vinylacetat,speziellfürKlebstoffe
    • EP1170311A1
    • 2002-01-09
    • EP00114097.9
    • 2000-07-07
    • AIR PRODUCTS POLYMERS, L.P.
    • Zecha, HelmutWeissgerber, RudolfGeiger, Frank
    • C08F218/04C08F261/04C09J131/04
    • C08F218/04C08F261/04
    • The present invention relates to a vinyl acetate based polymer latex composition obtained by emulsion polymerization, the polymer comprising PVOH, and a monomer mixture, said monomer mixture comprising vinyl acetate, and a pre-crosslinking monomer selected from one or more polyethylenically unsaturated compounds wherein said pre-crosslinking monomer is present in amount of less than 0.01% by weight based on the total monomer content and which pre-crosslinking monomer is initially charged to the polymerization reaction mixture. The invention further relates to use of the vinyl acetate based polymer latex in an adhesive, preferably a woodworking adhesive and to an adhesive, preferably a woodworking adhesive comprising said latex.
    • 本发明涉及通过乳液聚合获得的乙酸乙烯酯基聚合物胶乳组合物,包含PVOH的聚合物和单体混合物,所述单体混合物包含乙酸乙烯酯和选自一种或多种多烯属不饱和化合物的预交联单体,其中所述 预交联单体的存在量相对于总单体含量小于0.01重量%,并且哪些预交联单体最初加入到聚合反应混合物中。 本发明还涉及在粘合剂,优选木工粘合剂和粘合剂,优选包含所述胶乳的木工粘合剂中使用乙酸乙烯酯基聚合物胶乳。