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    • 21. 发明公开
    • METHOD OF POLYMERIZING ETHYLENICALLY-UNSATURATED MATERIALS USING IONIZING RADIATION
    • 工艺聚合烯属不饱和材料的防护作用
    • EP2931757A4
    • 2016-07-13
    • EP13863135
    • 2013-12-06
    • 3M INNOVATIVE PROPERTIES CO
    • MYERS SASHA BO'NEAL DANIEL JRICHTER KARL BTRAN THU-VAN THAMER CRAIG E
    • C08F2/46C08F2/38C08F2/44C08F2/54C08F20/10C09J133/04
    • C09J133/26C08F2/38C08F2/46C08F2/54C08F22/10C08F22/38C08F220/18C09J133/02C09J133/08C09J133/10C08F2220/1825C08F220/06C08F2220/1858C08F220/54
    • Methods of (co)polymerizing ethylenically-unsaturated materials, including the steps of providing a non-deaerated mixture of free radically (co)polymerizable ethylenically-unsaturated material in a batch reactor, exposing the non-deaerated mixture to a source of ionizing radiation for a time sufficient to initiate (co)polymerization of at least a portion of the free radically (co)polymerizable ethylenically-unsaturated material, and allowing the free radically (co)polymerizable ethylenically-unsaturated material to (co)polymerize under essentially adiabatic conditions while continuing to expose the mixture to the source of ionizing radiation for a time sufficient to yield an at least partially (co)polymerized (co)polymer. The ethylenically-unsaturated materials are selected from vinyl-functional monomers, vinyl-functional oligomers, vinyl-functional macromers, and combinations thereof. The mixture is preferably free of thermally-induced or UV-induced free radical polymerization initiators. The source of ionizing radiation may be a gamma ray source, an x ray source, an electron beam source with an emission energy greater than 300 keV, and combinations thereof.
    • 的(共)的方法进行聚合的烯键式不饱和材料,包括在间歇反应器中提供的可自由基(共)聚合烯属不饱和材料的非脱气混合物中,非脱气混合物暴露于电离辐射的源的步骤 足以引发可自由基(共)聚合烯属不饱和材料的至少一部分的(共)聚合,并允许所述可自由基(共)聚合烯属不饱和材料的时间(共)而基本绝热的条件下聚合 继续暴露混合物于电离辐射足够长的时间以得到至少部分地(共)聚合的(共)聚合物的来源。 烯属不饱和材料选自乙烯基官能单体,乙烯基官能低聚物,乙烯基官能化大分子单体,以及它们的组合。 该混合物优选不含热致或UV诱导的自由基聚合引发剂。 电离辐射的源可以是γ射线源,X射线源,电子束源与emissionenergy大于300千电子伏,以及它们的组合。
    • 30. 发明公开
    • METHOD FOR MANUFACTURING HYDROPHILIC POLYMER PARTICLE
    • VERFAHREN ZUR HERSTELLUNG VON HYDROPHILEN POLYMERTEILCHEN
    • EP2889314A1
    • 2015-07-01
    • EP13830294.8
    • 2013-07-31
    • Kao Corporation
    • NAITO, KazukiKAKU, Shuichi
    • C08F2/32A61K8/81A61Q5/02A61Q19/10
    • C08F220/56A61K8/0241A61K8/8158A61Q5/02A61Q19/10C08F2/32C08F220/54C08F2220/585C08F2222/1013
    • In a method for producing hydrophilic polymer particles, a dispersion in which an aqueous-phase component including hydrophilic monomers and a polymerization initiator is dispersed in an oil-phase component including a hydrophobic solvent is prepared. Then, the concentration of dissolved oxygen in the dispersion is reduced. Thereafter, the hydrophilic monomers are polymerized in the aqueous phase by supplying oxygen to a reaction vessel and, while oxygen is being supplied, heating the dispersion whose dissolved oxygen concentration was reduced in the reaction vessel so that the temperature of the dispersion is increases. The time from the start of reduction of the dissolved oxygen concentration of the dispersion to the start of the heating is 0.1 hour or more and 3.5 hours or less. The amount of oxygen supplied to the reaction vessel is greater than or equal to 0.02 volume %/h and less than or equal to 0.9 volume %/h with respect to the volume of the dispersion under standard conditions.
    • 在制备亲水性聚合物颗粒的方法中,制备将包含亲水性单体和聚合引发剂的水相成分分散在包含疏水性溶剂的油相成分中的分散液。 然后,分散体中溶解氧的浓度降低。 然后,通过向反应容器供给氧而使亲水性单体在水相中聚合,在供给氧的同时,在反应容器中加热溶解氧浓度降低的分散体,使分散液的温度上升。 从分散体的溶解氧浓度的降低开始到开始加热的时间为0.1小时以上且3.5小时以下。 相对于在标准条件下的分散体积,供给到反应容器的氧气的量大于或等于0.02体积%/ h且小于或等于0.9体积%/ h。