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    • 27. 发明公开
    • REACTOR FOR CHLORINE PRODUCTION AND PROCESS FOR PRODUCING CHLORINE
    • REAKTOR ZUR HERSTELLUNG VON CHLOR UND VERFAHREN ZUR HERSTLELUNG VON CHLOR
    • EP1894885A1
    • 2008-03-05
    • EP06767555.3
    • 2006-06-22
    • Sumitomo Chemical Company, Limited
    • MORI, Yasuhiko
    • C01B7/04B01J23/46
    • C01B7/04B01J8/067B01J21/063B01J23/462B01J35/0006B01J37/0009B01J37/0201B01J2208/00053B01J2208/00061B01J2208/00212B01J2208/00221B01J2208/00256B01J2208/0053B01J2208/025B01J2219/002B01J2219/00204B01J2219/0022B01J2219/00238F28D7/0066F28D7/0091F28F27/00
    • A rector for producing chlorine according to the present invention is a multi-tubular heat exchanger type reactor for use in producing chlorine by oxidizing hydrogen chloride with oxygen, characterized in that
      an interior of a reactor shell is divided in a tube-axis direction by a partition into a plurality of regions such that heat mediums individually circulate through respective ones of the divided regions;
      said reactor comprising a temperature control means for controlling the temperature of at least one heat medium selected from said heat mediums, the temperature control means being a cooler and/or a heater;
      catalysts having different catalytic activities are charged in the form of layers from inlets towards outlets of reaction tubes of the reactor, the catalysts being ruthenium oxide catalysts; and
      40% or less of the whole ruthenium is in the region of the reaction tubes ranging from the reaction tube inlet to less than 50% of the reaction tube length, whereas 60% or more of the whole ruthenium is in the region of the reaction tubes ranging from 50 to 100% of the reaction tube length from the reaction tube inlet.
      A process for producing chlorine according to the present invention is characterized in that the process is carried out by using the above reactor, and comprises the step of supplying a hydrogen chloride-containing gas and an oxygen-containing gas into the above reactor so as to oxidize the hydrogen chloride with the oxygen at a pressure of 0.1 to 1 MPaG and a temperature of 200 to 500 °C.
    • 根据本发明的用于生产氯的反应器是一种用于通过用氧气氧化氯化氢生产氯的多管式热交换器型反应器,其特征在于反应器壳体的内部在管轴方向上被分开 分隔成多个区域,使得热介质分别通过相应的分割区域循环; 所述反应器包括用于控制选自所述热介质的至少一种热介质的温度的温度控制装置,所述温度控制装置是冷却器和/或加热器; 具有不同催化活性的催化剂以从反应器的反应管的入口到出口的层的形式进料,催化剂是氧化钌催化剂; 并且整个钌的40%或更少在反应管的范围内从反应管入口到反应管长度的小于50%,而整个钌的60%或更多在反应区域 管的反应管长度从反应管入口的50至100%。 根据本发明的氯的制造方法的特征在于,该方法通过使用上述反应器进行,并且包括向上述反应器中供给含氯化氢的气体和含氧气体的步骤,以便 在0.1至1MPaG的压力和200至500℃的温度下用氧气氧化氯化氢。
    • 28. 发明公开
    • Steam-heating apparatus
    • 蒸汽加热装置
    • EP1795845A3
    • 2007-07-04
    • EP07006790.5
    • 2000-12-15
    • TLV CO. LTD.
    • Kumamoto, Tadaaki
    • F28D1/06B01J19/00
    • F01K3/002B01J19/0013B01J2219/0006B01J2219/00063B01J2219/00094B01J2219/002B01J2219/00204B01J2219/00213B01J2219/00231B01J2219/00238F22G1/14F22G1/16F28B9/02F28B9/10F28B11/00F28D1/06
    • In a steam-heating apparatus in which a heating section (2) formed in a heat exchanger (1) is connected to a steam supply pipe (3) for receiving supply of heating steam and connected also to a condensate recovering unit apparatus includes a steam ejector (5) including a suction chamber (13) connected to the heating section (2) and an inlet for receiving supply of the steam. The apparatus comprising a condensate tank (11) disposed between the heating section (2) and the condensate recovering unit (6). When the temperature of the heating section (2) or between the heating section (2) and the condensate recovering unit (6) is dropped by a predetermined value, steam is supplied from the steam supply pipe (3) to the inlet of the steam ejector (5) and gas in the heating section (2) is sucked into the suction chamber (13) of the steam ejector (5).
    • 在形成于热交换器(1)中的加热部分(2)连接到用于接收加热蒸汽的供应的蒸汽供应管(3)并且还连接到冷凝物回收单元装置的蒸汽加热装置中,蒸汽加热装置包括蒸汽 包括连接到加热部分(2)的吸入室(13)和用于接收蒸汽供应的入口的喷射器(5)。 该设备包括设置在加热部分(2)和冷凝水回收单元(6)之间的冷凝水箱(11)。 当加热部分(2)或加热部分(2)与冷凝物回收单元(6)之间的温度下降预定值时,蒸汽从蒸汽供应管(3)供应到蒸汽入口 喷射器5和加热部分2中的气体被吸入蒸汽喷射器5的吸入室13中。