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21. 发明公开

EP3374357A1 DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS 有权
公开(公告)号：EP3374357A1
公开(公告)日：2018-09-19
申请号：EP16816743.5
申请日：2016-11-11
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , PROTO, Antonio Alfonso
IPC分类号： C07D417/14 , C09K11/06 , H01L31/055
CPC分类号： C07D417/14 , C09K11/06 , C09K2211/1007 , C09K2211/1051 , C09K2211/1092 , H01L31/055 , Y02E10/52
摘要： Disubstituted diaryloxybenzoheterodiazole compound having general formula (I) or (II) wherein - Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group wherein R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; - R1, R2 and R3, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1, R2, may optionally be bound together to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; - or R2 and R3, may optionally be bound together so as to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; - R4, identical or different, represent a hydrogen atom; or are selected from linear or branched, preferably linear, C1-C20, preferably C1-C8, alkyl groups; - R5, identical or different, are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups; - n and m, identical or different, are 0 or 1, provided that at least one of n and m is 1. Said diaryloxybenzoheterodiazole compound having general formula (I), as such or after (co)polymerization, and said disubstituted diaryloxybenzoheterodiazole compound having general formula (II) as such, may be advantageously used as spectrum converters in luminescent solar concentrators (LSCs), which are in turn able to improve the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid and flexible supports.

22. 发明授权

EP2828260B1 PROCESS FOR THE PREPARATION OF TETRACARBOXYNAPHTHALENEDIIMIDE COMPOUNDS DISUBSTITUTED WITH HETEROARYL GROUPS 有权
标题翻译：制备杂芳基基团取代四氮杂苯并卟啉化合物的方法
公开(公告)号：EP2828260B1
公开(公告)日：2017-11-29
申请号：EP13721079.5
申请日：2013-03-18
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , PELLEGRINO, Andrea , CHIABERGE, Stefano , BIANCHI, Gabriele
IPC分类号： C07D471/06
CPC分类号： C07D471/06 , C09B57/08

23. 发明授权

EP2742041B1 PROCESS FOR THE PREPARATION OF BENZOHETERO [ 1, 3]- DIAZOLE COMPOUNDS DISUBSTITUTED WITH HETEOARYL GROUPS 有权
标题翻译：制备苯并噻吩的方法[1,3] - 用水杨酰基取代的二唑化合物
公开(公告)号：EP2742041B1
公开(公告)日：2015-10-21
申请号：EP12759261.6
申请日：2012-08-01
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , BIANCHI, Gabriele
IPC分类号： C07D409/14 , C07D413/14 , C07D417/14 , C07D519/00
CPC分类号： C07D417/14 , C07D409/14 , C07D413/14 , C07D495/04 , C07D519/00
摘要： Process for the preparation of a benzohetero[1,3]diazole compound disubstituted with heteroaryl groups which comprises reacting at least one benzohetero[1,3]diazole compound disubstituted with at least one heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of luminescent solar concentrators (LSC). Furthermore, said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can also be advantageously used as a precursor of monomeric units in the preparation of semiconductor polymers.

24. 发明公开

EP2841507A1 ORGANIC DYE FOR A DYE-SENSITIZED SOLAR CELL 有权
标题翻译：用于染料敏化太阳能电池的有机染料
公开(公告)号：EP2841507A1
公开(公告)日：2015-03-04
申请号：EP13717505.5
申请日：2013-04-19
申请人： ENI S.p.A. , Centre National de la Recherche Scientifique (CNRS)
发明人： BIAGINI, Paolo , DEMETER, Dora , LERICHE, Philippe , PELLEGRINO, Andrea , RONCALI, Jean , SCHIMPERNA, Giuliana
IPC分类号： C09B57/00 , H01G9/20 , H01L31/042
CPC分类号： H01G9/2059 , C07D333/08 , C09B57/00 , H01G9/2031 , H01L51/0067 , H01L51/0068 , Y02E10/542 , Y02E10/549
摘要： Organic dye for a dye-sensitized solar cell (DSSC) comprising at least one electron-acceptor unit and at least one π-conjugated unit. Said organic dye is particularly useful in a dye-sensitized photoelectric transformation element which, in its turn, can be used in a dye-sensitized solar cell (DSSC).
摘要翻译：用于包含至少一个电子受体单元和至少一个π共轭单元的染料敏化太阳能电池（DSSC）的有机染料。所述有机染料在染料敏化光电转换元件中特别有用，所述染料敏化光电转换元件又可用于染料敏化太阳能电池（DSSC）中。

25. 发明授权

EP2513198B1 COPOLYMERS FOR SOLAR CELLS BASED ON ACRIDONIC UNITS 有权
标题翻译：共聚物用于太阳能小区是基于ACRIDONEINHEITEN
公开(公告)号：EP2513198B1
公开(公告)日：2013-12-04
申请号：EP10795251.7
申请日：2010-12-15
申请人： ENI S.p.A.
发明人： CALDARARO, Maria , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , PO', Riccardo
IPC分类号： C08G73/06 , C07D409/14 , C08G61/12 , C09D11/10 , H01L51/00
CPC分类号： C07D409/14 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0043 , H01L51/4253 , Y02E10/549
摘要： The present invention relates to copolymers for solar cells based on acridonic units comprising: a monomeric unit (A) having general formula (I) wherein X is S or Se, Y is 0, S or NR′ and R′, R′, the same or different, are C4-C24 alkyl groups, aryl groups optionally substituted with other functional groups, acyl groups or thioacyl groups; at least one monomer unit (B) having general formula (II) wherein Z is 0, S, Se or N—R″, wherein R″ is a C4-C24 alkyl group, an aryl group op-tionally substituted with other functional groups, an acyl group or thioacyl group, said monomeric unit (B) being connected to any position available of a hetero-aromatic side ring of the unit (A) through one of the two positions indicated by the dashed lines in general formula (II). Photovoltaic devices comprising said alternating &pgr;-conjugated polymers are also described.

26. 发明公开

EP4059068A1 DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DI-SUBSTITUTED WITH THIENOTHIOPHENIC GROUPS 有权
公开(公告)号：EP4059068A1
公开(公告)日：2022-09-21
申请号：EP20807520.0
申请日：2020-11-12
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , ABBONDANZA, Luigi , PROTO, Antonio Alfonso , ZANARDI, Stefano
IPC分类号： H01L51/44

28. 发明授权

EP3374357B1 DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS 有权
公开(公告)号：EP3374357B1
公开(公告)日：2019-10-02
申请号：EP16816743.5
申请日：2016-11-11
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , PROTO, Antonio Alfonso
IPC分类号： C07D417/14 , C09K11/06 , H01L31/055

29. 发明授权

EP3197890B1 DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS 有权
公开(公告)号：EP3197890B1
公开(公告)日：2019-02-27
申请号：EP15767176.9
申请日：2015-09-24
申请人： ENI S.p.A.
发明人： ABBONDANZA, Luigi , ALESSI, Andrea , PROTO, Antonio Alfonso , SCHIMPERNA, Giuliana , GILA, Liliana
IPC分类号： C07D417/14 , C09K11/06 , H01L31/055

30. 发明授权

EP3230291B1 BIS-THIENOBENZOTHIENOTHIOPHENE COMPOUNDS AND PROCESS FOR THEIR PREPARATION 有权
公开(公告)号：EP3230291B1
公开(公告)日：2019-01-23
申请号：EP15813005.4
申请日：2015-12-11
申请人： Eni S.p.A.
发明人： BIANCHI, Gabriele , SCHIMPERNA, Giuliana
IPC分类号： C07D495/22 , C09K11/06

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