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    • 30. 发明公开
    • Phenyldioxane derivatives, liquid crystal compositions, and liquid crystal display elements
    • 苯基二氧化物,FlüssigkristallzusammensetzungenundFlüssigkristallanzeigeelemente
    • EP0819685A1
    • 1998-01-21
    • EP97112038.1
    • 1997-07-15
    • Chisso Corporation
    • Haseba, YasuhiroMatsui, ShuichiMiyazawa, KazutoshiTakeuchi, HiroyukiHisatsune, YasusukeTakeshita, FusayukiNakagawa, Etsuo
    • C07D319/06C09K19/34C09K19/42C09K19/44C09K19/46
    • C07D319/06C09K19/3402C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451C09K2019/3422
    • There is provided an electrically and chemically stable liquid crystalline compound which exhibits a significantly large value of De and a high voltage holding ratio. The compound is a phenyldioxane derivative represented by formula (1):
      wherein R represents a C1-C20 alkyl group; each of n1 and n2 represents 0 or 1; each of Q 1 through Q 6 represents a hydrogen atom, a fluorine atom, or a chlorine atom, provided that Q 3 is a fluorine atom or a chlorine atom when n2 is 0, and that at least one of Q 1 and Q 3 is a fluorine atom or a chlorine atom when n2 is 1; each of Za and Zb represents a single bond, -COO-, or -CF 2 O-; Zc represents a single bond or -CH 2 CH 2 -; Y represents a hydrogen atom, a halogen atom, or a C1-C5 halogenated alkyl group in which one or more non-adjacent methylene groups may be replaced by oxygen atoms or sulfur atoms; and each of the elements that constitute the compound may comprise isotopes of the element. The compound also exhibits excellent compatibility with previously known liquid crystalline compounds, and is advantageously used for low voltage driving of liquid crystal displays for TFTs. There are also provided liquid crystal compositions comprising the compound, as well as liquid crystal display elements constructed of the compositions.
    • 提供了电化学稳定的液晶化合物,其表现出显着的De值和高电压保持率。 该化合物是由式(1)表示的苯基二恶烷衍生物:其中R表示C1-C20烷基; n1和n2各自表示0或1; Q1至Q6中的每一个表示氢原子,氟原子或氯原子,条件是当n2为0时Q3为氟原子或氯原子,并且Q1和Q3中的至少一个为氟原子或 n2为1时为氯原子; Za和Zb各自表示单键-COO-或-CF2O-; Zc表示单键或-CH2CH2-; Y表示一个或多个不相邻的亚甲基可被氧原子或硫原子代替的氢原子,卤原子或C1-C5卤代烷基; 并且构成化合物的每个元素可以包含元素的同位素。 该化合物还与先前已知的液晶化合物表现出优异的相容性,并且有利地用于TFT的液晶显示器的低电压驱动。 还提供了包含该化合物的液晶组合物以及由该组合物构成的液晶显示元件。