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    • 19. 发明公开
    • SYSTEM AND METHOD TO CONTROL H2O2 LEVEL IN ADVANCED OXIDATION PROCESSES
    • 在先进氧化过程中控制H2O2水平的系统和方法
    • EP3213365A1
    • 2017-09-06
    • EP15787184.9
    • 2015-10-27
    • Danmarks Tekniske Universitet
    • ANGELIDAKI, IriniZHANG, Yifeng
    • H01M8/16C02F1/00C25B1/30C25B9/00
    • C02F3/005C02F1/4672C02F2303/18C02F2305/023C25B1/30C25B9/08C25B15/08H01M8/16Y02E60/527Y02P70/56Y02W10/33Y02W10/37
    • The present invention relates to a bio-electrochemical system (BES) and a method of in-situ production and removal of H2O2 using such a bio-electrochemical system (BES). Further, the invention relates to a method for in-situ control of H 2O2 content in an aqueous system of advanced oxidation processes (AOPs) involving in-situ generation of hydroxyl radical (OH) by using such a bio-electrochemical system (BES) and to a method for treatment of wastewater and water disinfection. The bio-electrochemical system (BES) according to the invention comprises:—an aqueous cathode compartment comprising a first cathode and a second cathode,—an aqueous anode compartment comprising an anode at least partly covered in biofilm, wherein the first cathode is connected to a first circuit and the second cathode is connected to a second circuit, wherein the first and the second circuit are connected to the system by an external switch.
    • 本发明涉及生物电化学系统(BES)以及使用这种生物电化学系统(BES)原位生产和去除H 2 O 2的方法。 此外,本发明涉及一种用于通过使用这样的生物电化学系统(BES)原位生成羟基自由基(OH)的高级氧化工艺(AOP)的含水系统中原位控制H 2 O 2含量的方法, 并涉及一种处理废水和水消毒的方法。 根据本发明的生物电化学系统(BES)包括: - 含有第一阴极和第二阴极的水性阴极室, - 含水阳极室,其包含至少部分被生物膜覆盖的阳极,其中第一阴极连接到 第一电路和第二阴极连接到第二电路,其中第一和第二电路通过外部开关连接到系统。
    • 20. 发明公开
    • METHOD FOR PRODUCING OXIDIZED WATER FOR STERILIZATION USE WITHOUT ADDING ELECTROLYTE
    • VERFAHREN ZUR HERSTELLUNG VON OXIDIERTEN WASSER ZUR STERILISATIONSVERWENDUNG OHNE ELEKTROLYTZUGABE
    • EP3081535A4
    • 2017-08-23
    • EP14869652
    • 2014-12-08
    • TECH CORP CO LTD
    • SUMITA OSAO
    • C02F1/461A61L2/03C02F1/42C25B1/26
    • C02F1/4618A61L2/035C02F1/42C02F1/46109C02F2001/422C02F2001/425C02F2001/46138C02F2001/46161C02F2001/46185C02F2201/46115C02F2201/46195C02F2209/29C02F2209/40C02F2301/043C02F2303/04C02F2305/02C25B1/26C25B9/08C25B11/035C25B15/08
    • [Problem] To provide an electrolysis method, whereby it becomes possible to produce oxidized water for sterilization/disinfection use in a neutral pH range by anodically oxidizing raw water, e.g., tap water, effectively utilizing halogen ions, e.g., chlorine ions, contained in the raw water. [Solution] A method for producing oxidized water for sterilization use which contains chlorine dioxide, said method comprising: electrolyzing tap water containing chlorine ions using a three-chamber-type electrolysis vessel, then trapping the chlorine ions dissolved in the tap water, and then electrolytically oxidizing the trapped chlorine ions on an anode electrode. The three-chamber-type electrolysis vessel is composed of an anode chamber, a cathode chamber and an intermediate chamber which is located between the anode chamber and the cathode chamber and is formed by providing partitioning membranes between the anode chamber and the cathode chamber. In the three-chamber-type electrolysis vessel, a partitioning membrane that isolates the anode chamber from the intermediate chamber is composed of a fluorine-containing cation exchange membrane and an anion exchange membrane, wherein a porous anode electrode is adhered onto the fluorine-containing cation exchange membrane in the partitioning membrane; a partitioning membrane that isolates the cathode chamber from the intermediate chamber is composed of a cation exchange membrane or an anion exchange membrane, wherein a porous cathode electrode is adhered onto the partitioning membrane; and an anion exchange resin is filled in the intermediate chamber.
    • 本发明的目的在于提供一种电解方法,通过对例如自来水等原水进行阳极氧化,能够在中性pH范围内生成杀菌消毒用的氧化水,从而有效地利用氯离子等卤素离子 原水。 所述方法包括:使用三室型电解容器电解含有氯离子的自来水,然后捕获溶解在自来水中的氯离子,然后 电解氧化阳极上的捕获的氯离子。 三室型电解槽由阳极室,阴极室和位于阳极室和阴极室之间的中间室组成,并且通过在阳极室和阴极室之间设置分隔膜而形成。 在三室型电解槽中,将阳极室与中间室隔离开的分隔膜由含氟阳离子交换膜和阴离子交换膜构成,其中多孔阳极电极粘附到含氟阳离子交换膜 阳离子交换膜在分隔膜中; 将阴极室与中间室隔离的分隔膜由阳离子交换膜或阴离子交换膜组成,其中多孔阴极电极粘附在分隔膜上; 并在中间室中填充阴离子交换树脂。