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    • 13. 发明公开
    • COATING COMPOSITIONS FOR MARKING SUBSTRATES
    • 涂料组合物用于衬底打标
    • EP1861472A1
    • 2007-12-05
    • EP06777203.8
    • 2006-03-13
    • Ciba Specialty Chemicals Holding Inc.
    • CAMPBELL, JonathanWHITWORTH, JohnPLATT, AlanSTREET, Ian
    • C09D11/02C07F7/08C09D1/00
    • C07F7/1868B41M5/26B41M5/286C07F7/04C09D5/024C09D11/50
    • The present invention provides coating compositions for marking substrates, which comprises a colour former, an amine salt of an organic metal compound, a binder, a solvent, and optionally additional components, wherein the amine salt of the organic metal compound is of formula (I) in which X is silicon or boron, and E and F are the same or different and are selected from the group consisting of a, b, c, d, e, f, g, h in which R6 and R7 are the same or different are hydrogen, C1-4-alkyl, C1-4-alkoxy, halogen, amino or carboxy, and for X = silicon o = 1 and p = 0, and R1 is aryl, aralkyl or C1-4-alkyl, or o = 1 and p = 1 , and R1 and R2 together form a one residue selected from the group consisting of a, b, c, d, e, f, g and h, and for X = boron o= 0 and p = 0, and R3, R4 and R5 are the same or different and are hydrogen, C1-12-alkyl, C1-6-hydroxyalkyl, allyl, aralkyl or arylsulfonyl, in which aralkyl or arylsulfonyl can be substituted with C1-4-alkyl, or R3 and R4 together with the nitrogen to which they are attached form a morpholino or piperidino ring. The present invention also provides a process for the preparation of the composition of the present invention, substrates coated with these compositions, a process for preparing coated substrates, a process for preparing a marked substrate using these compositions, a marked substrate obtainable by the latter process and amine salts of the organic metal compounds of formula I.
    • 18. 发明公开
    • Strukturierte Pigmentbeschichtung und deren Herstellung sowie Verwendung
    • EP0742556A1
    • 1996-11-13
    • EP96810278.0
    • 1996-05-01
    • CIBA-GEIGY AG
    • Zambounis, John, Dr.Hofmann, Manfred, Dr.
    • G11B7/24C09B69/08D06P1/00
    • C07D487/22B41M5/286C08K5/0041Y10S430/146
    • Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung eines Materials enthaltend ein Substrat, an dessen Oberfläche mindestens eine aus einem oder mehreren Pigmenten der Formel (I) oder (II) oder Derivaten davon,

              A(D 1 (D 2 ) x    (I)



              Pc   (II)


         worin A den Rest eines Chromophors der Chinacridon-, Anthrachinon-, Perylen-, Indigo-, Azo-, Chinophthalon-, Isoindolinon-, Isoindolin-, Dioxazin-, Phthalocyanin- oder Diketopyrrolopyrrolreihe bedeutet, der mit D 1 und x D 2 verbundene N-Atome enthält, wobei jedes in A vorhandene N-Atom unabhängig von den anderen mit 0, 1 oder 2 Gruppen D 1 oder D 2 verbunden sein kann,
         D 1 und D 2 Wasserstoff, x eine ganze Zahl von 0 bis 4 bedeuten, und
         Pc ein Chromophor der Phthalocyanin-Reihe ist,
      bestehende Pigmentbeschichtung angebracht ist, durch

      (a) Beschichtung des Substrats mit einer Lösung oder Schmelze mindestens eines latenten Pigmentes der Formeln (III) oder (IV) oder eines Derivaten davon,

              A(D 3 )(D 4 ) x    (III)


      und
      (b) partielle oder vollständige Überführung des latenten Pigmentes in dessen unlösliche Pigmentform durch Abspaltung der Gruppen D 3 , D 4 , durch Abspaltung der Gruppen L 1 und L 2 .

      Die Erfindung betrifft auch ein derartig hergestelltes, strukturiertes Material, dessen Verwendung als Farbfilter oder zur permanenten Speicherung von digitaler Information, sowie ein Verfahren zum Ablesen darauf gespeicherter digitaler Information durch Bestrahlen mit einer Lichtquelle und Messung der Intensität des reflektierten oder des transmittierten Lichtstrahles.
    • 制备方法。 的材料 具有式(A)(D 2)x(I)的颜料涂层的基材; 或Pc(II)或其衍生物。 在表面上包括:(a)用溶胶涂覆基材。 或熔融式A(D3)(D4)x(III)的潜在颜料; 或衍生。 的这种或潜在的颜料(IV)或位置异构体或衍生物。 这个的; 及(b)部分或完全将(II)或(IV)转换为无理机构。 通过消除D3和D4 gps的颜料形式。 用H取代或除去L1和L2 gps:A =喹吖啶酮,蒽醌,苝,靛蓝,偶氮,喹酞酮,异吲哚啉酮,异吲哚啉,二恶嗪,酞菁或二酮吡咯并吡咯发色团gp。 其D1和x D2或D3和x D4连接到N原子,并且与A中的每个N原子连接的0,1或2个D1,D2,D3或D4; D1,D2 = H; x = 0 - 4; Pc =酞菁发色团; D3,D4 = -CO-O-(X)m-(Y)n-(CO)p-C6H3R1R2,-CO-O-(X)m-(Z)n-Q或-CO-O-NR3R4; X = 1〜14 C亚烷基,2〜14 C亚烯基,2〜14 C亚炔基或4〜12 C环烯(en) Y = -V-(CH 2)q; Z = -V-(CH 2)r; V = 3〜6 C亚环烷基; q = 1〜16; r = 0-1; R1,R2 = H,1-6C烷基,1-4C烷氧基,卤素,CN,NO2或苯基或苯氧基, substd。 1-4烷基,1-4C烷氧基或卤素; Q = H,CN,Si(R 1)3,-C(R 5)(R 6)(R 7),-SO 2 -C 6 H 3 R 1 R 2,-SO 2 R 8,SR 8,-CH(R 9)2,吡啶基,嘧啶-4-基,噻吩基 ,呋喃基,芴-9-基,萘-1-基,2,7-二叔丁基-10,10-二氧代 - 噻吨-9-基或菲-9-基; R8 = 1-4C烷基; R9 =苯基,选择。 substd。 1-4烷基,1-4C烷氧基或卤素; R3,R4 = H,1〜18C烷基或 - (X)m-(Y)n-C6H3R1R2,或NR3R4-吡咯烷基,哌啶基或吗啉基; L 1,L 2 =卤素,1〜18 C烷氧基,2〜18 C二烷基氨基,1〜18 C环烷基氨基,1-6 C烷基哌啶子基或吗啉代; M = H 2或至少二价金属原子。 还要求的是在pt上具有均匀颜料涂层的材料。 的表面,没有其余的。
    • 19. 发明公开
    • Thermal dye bleach construction
    • Konstruktion zum thermischen Farbbleichen。
    • EP0571906A2
    • 1993-12-01
    • EP93108295.2
    • 1993-05-21
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • Helland, Randall H., c/o Minnesota Mining andTiers, George V. D., c/o Minnesota Mining andStevenson, Dian E., c/o Minnesota Mining and
    • G03C1/498G03C7/02B41M5/28
    • G03C1/49845B41M5/286G03C1/49854Y10S430/156Y10S430/165
    • A thermal-dye-bleach construction comprising a thermal nucleophile-generating agent in association with a styryl dye having a nucleus of general formula (I):

      representing the nucleus of a styryl dye in which

      R = methyl or ethyl group
      Y = alkoxy of 1 to 20 carbon atoms
      m = 1 or 2,
      n = 1, 2, or 3, and
      x e = an anion

      The aromatic fused benzene portion of the indolenine ring may be further substituted with commonly acceptable dye substituents such as alkyl and substituted alkyl (of 1 to 10 carbon atoms) groups, alkoxy groups (preferably of 1 to 10 carbon atoms), fused aromatic rings (as to make the benzene ring a fused naphthalene ring), halogen (including fluoro), cyano, nitro, carboxamido, amido, etc. One or two substituents chosen variously from said group may also be present on the phenyl ring to which the alkoxy group is attached. These substituents and their combinations should not be chosen so as to alter the absorption characteristics of the dye greatly enough to remove the maximum absorption from between 300 and 490 nm.
      X e may be any anion, but certain classes of anions and certain particular anions are preferred. Aromatic and perfluorinated anions and, in particular dodecylbenzenesulfonate and especially perfluoro(ethylcyclohexane sulfonate) are preferred on account of their solubilizing power, but simpler anions such as iodide, chloride, bromide, methylsulfate, perchlorate and the like may also be used.
    • 一种热染料漂白结构,其包含与具有通式(I)的核的苯乙烯基染料相结合的热亲核试剂:代表苯乙烯基染料的核的CHEM,其中R =甲基或乙基Y = 1至20个碳原子的烷氧基m = 1或2,n = 1,2或3,x <( - )> =阴离子吲哚宁环的芳族稠合苯部分可以进一步被通常可接受的染料取代基取代 例如烷基和取代的烷基(1-10个碳原子)基团,烷氧基(优选1-10个碳原子),稠合芳环(使苯环为稠合萘环),卤素(包括氟), 氰基,硝基,甲酰氨基,酰氨基等。从所述基团不同地选择的一个或两个取代基也可以存在于与烷氧基连接的苯环上。 不应选择这些取代基及其组合,以便大大改变染料的吸收特性,以去除300至490nm之间的最大吸收。 X <( - )>可以是任何阴离子,但是某些类型的阴离子和某些特定的阴离子是优选的。 芳族和全氟化阴离子,特别是十二烷基苯磺酸盐,特别是全氟(乙基环己烷磺酸盐)是优选的,因为其增溶作用,但也可以使用更简单的阴离子如碘化物,氯化物,溴化物,甲基硫酸盐,高氯酸盐等。