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    • 13. 发明公开
    • MICROPOROUS FILM
    • MIKROPORÖSER电影
    • EP1063256A1
    • 2000-12-27
    • EP99907942.9
    • 1999-03-16
    • Asahi Kasei Kogyo Kabushiki Kaisha
    • MATSUDA, ShigenobuNAGOYA, FujiharuKOIZUMI, Toshinori
    • C08J9/28C08J9/00B01D71/34
    • B01D67/0086B01D67/0011B01D67/0016B01D67/0027B01D67/003B01D69/02B01D71/34B01D2323/12B01D2323/34C08J9/28C08J2201/052C08J2327/16
    • A microporous membrane is produced by cooling a solution comprising a vinylidene fluoride homopolymer or copolymer having a weight average molecular weight of 1 x 10 5 or more and a solvent therefor, to form a two-phase gel, said microporous membrane comprising a polymer phase comprising said vinylidene fluoride homopolymer or copolymer, and intercommunicating voids which have an average pore size measured by the half-dry method of 0.005 to 5 µm and range from one side of the membrane to the other side, and said microporous membrane having as its internal structure a percolation structure in which the polymer phase forms an isotropic network structure by three-dimensional branching in arbitrary directions, the voids are formed by surrounding by said polymer phase of the network structure and intercommunicate with one another, and the ratio of the maximum pore size measured by the bubble point method to the average pore size measured by the half-dry method is 2.0 or less.
    • 通过将包含重均分子量为1×10 5以上的偏二氟乙烯均聚物或共聚物的溶液及其溶剂冷却来形成微孔膜,形成两相凝胶,所述微孔膜包含聚合物 包含所述偏二氟乙烯均聚物或共聚物的相,以及通过半干法测定的平均孔径为0.005〜5μm并且从膜的一侧到另一侧的范围的相互连通的空隙,并且所述微孔膜具有 其内部结构是其中聚合物相通过三维分支在任意方向上形成各向同性网络结构的渗透结构,通过网状结构的所述聚合物相包围并相互连通而形成空隙, 通过泡点法测定的通过半干法测量的平均孔径的最大孔径为2.0以下。