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    • 17. 发明公开
    • HAIR CARE COMPOSITION
    • 头发护理组合物
    • EP2925287A1
    • 2015-10-07
    • EP13791981.7
    • 2013-11-12
    • Unilever PLCUnilever N.V.
    • HENTRICH, DoreenJARVIS, Adam, PeterKITA-TOKARCZYK, Katarzyna, ElzbietaLIMER, Adam, JohnROBSON, Scott
    • A61K8/49A61Q5/00A61K8/81A61K8/23A61Q5/02A61Q5/12A61K8/891A61K8/892
    • A61K8/463A61K8/8164A61K8/892A61K2800/548A61Q5/02A61Q5/12C08L2201/54C08L2312/00C09D133/10C09D135/02
    • An aqueous composition comprising: i) at least 0.5 wt.% of the total composition of a cleansing surfactant, ii) at least 0.01 wt.% of the total composition of a silicone conditioning agent; iii) at least 0.05 wt.% of the addition polymerization product of: a. from 0.1 to 5 wt.% of a first unsaturated monomer A of a ethylenically unsaturated diacid of formula (I): HOOC-CR
      5 =CR
      6 -COOH, or an unsaturated cyclic anhydride precursor of such an ethylenically unsaturated cis diacid, the anhydride having formula (II), where R
      5 and R
      6 are individually selected from H, C
      1 -C
      3 alkyl, phenyl, chlorine and bromine; b. from 1 to 60 wt.% of a second ethylenically unsaturated monomer B selected from acrylic acid, methacrylic acid and combinations thereof, c. from 30 to 75 wt.% a (meth)acrylate monomer C selected from C
      1 to C
      8 alkyl esters of (meth)acrylic acid and C
      1 to C
      8 alkyl estersof methacrylic acid and combinations thereof, d. from 1 to 25 wt.% of an associative monomer D of the formula (III), where R
      1 and R
      2 are each independently selected from H, and C
      1-3 alkyl; R
      3 is C
      2 -C
      4 and mixtures thereof, preferably C
      2 ; m, the average number of alkoxy units R
      3 O, is from 6 to 40; R
      4 is alkyl or alkylaryl where the alkyl part is linear or branched; and the total number of carbons is from 6 to 40; e. from 0 to 1.0 wt.% of a cross linking monomer E for introducing branching and controlling molecular weight, the cross linking monomer comprising polyfunctional units carrying multiple reactive functionalization groups selected from the group consisting of vinyl, allylic and functional mixtures thereof.
    • 一种含水组合物,其包含:i)占全部组合物至少0.5重量%的清洁表面活性剂,ii)至少0.01重量%的硅氧烷调理剂总组合物; iii)至少0.05重量%的以下加成聚合产物:a。 0.1至5重量%的式(I)的烯属不饱和二酸的第一不饱和单体A:HOOC-CR 5 = CR 6 -COOH或这种烯属不饱和顺式二酸的不饱和环酸酐前体,酸酐 具有式(II),其中R 5和R 6分别选自H,C 1 -C 3烷基,苯基,氯和溴; 湾 1至60重量%的选自丙烯酸,甲基丙烯酸及其组合的第二烯键式不饱和单体B,c。 (甲基)丙烯酸的C 1 -C 8烷基酯和甲基丙烯酸的C 1 -C 8烷基酯及其组合的(甲基)丙烯酸酯单体C,30-75重量%,d。 1至25重量%的式(III)的缔合单体D,其中R 1和R 2各自独立地选自H和C 1-3烷基; R 3是C 2 -C 4及其混合物,优选C 2; m,烷氧基单元R 3 O的平均数目为6至40; R 4是其中烷基部分是直链或支链的烷基或烷基芳基; 总碳数为6至40; 即 0-1.0重量%的用于引入支化和控制分子量的交联单体E,所述交联单体包含带有多个选自乙烯基,烯丙基和其官能混合物的反应性官能化基团的多官能单元。