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131. 发明公开

EP0481427A1 Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：EP0481427A1
公开(公告)日：1992-04-22
申请号：EP91117577.6
申请日：1991-10-15
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Shuto, Sadanobu, c/o Fuji Photo Film Co., Ltd. , Mitsui, Akio, c/o Fuji Photo Film Co., Ltd.
IPC分类号： G03C7/305
CPC分类号： G03C7/3029 , G03C7/30511 , Y10S430/158
摘要： A silver halide color photographic material comprises a support, a blue sensitive layer, a green sensitive layer and a red sensitive layer and at least one non-light-sensitive layer. The non-light-sensitive layer is an intermediate layer arranged between the silver halide emulsion layers. According to the present invention, the non-light-sensitive intermediate layer contains a compound represented by the formula (1a) or (1b):

in which R¹² is an aliphatic group, an aromatic group or a heterocyclic group; M is -CO-, -SO₂-, -N(R¹⁵)CO-, -OCO- or -N(R¹⁵)SO₂-; each of R¹⁴, R¹⁵ and R²⁴ independently is hydrogen, an alkyl group or an aryl group; L is a divalent linking group necessary for forming a 5, 6 or 7-membered ring; each of R¹¹, R¹³ and R²¹ independently is hydrogen or a substituent group of the hydroquinone nucleus; Time is a group which is released from the oxidation product of the hydroquinone nucleus to further release X; X is a development inhibitor; and t is 0 or 1. It is preferred that M is - SO₂-, -N(R¹⁵)CO-, -OCO- or -N(R¹⁵)SO₂-.
摘要翻译：卤化银彩色照相材料包括载体，蓝色敏感层，绿色敏感层和红色敏感层以及至少一个非光敏层。非感光层是布置在卤化银乳剂层之间的中间层。根据本发明，非感光中间层含有由式（1a）或（1b）表示的化合物：其中R 12是脂族基团，芳族基团或杂环基团; M是-CO-，-SO 2 - ， - N（R 15）CO-，-OCO-或-N（R 15）SO 2 - R 14，R 15和R 24中的每一个独立地为氢，烷基或芳基; L是形成5,6或7元环所必需的二价连接基团; R 11，R 13和R 21中的每一个独立地是氢或氢醌核的取代基; 时间是从氢醌核的氧化产物释放以进一步释放X的基团; X是一种发育抑制剂; t是0或1.M最好是-SO 2 - ， - N（R 15）CO-，-OCO-或-N（R 15）SO 2 - 。

132. 发明公开

EP0479156A1 Silver halide photographic materials 失效
标题翻译：卤化银照相材料
公开(公告)号：EP0479156A1
公开(公告)日：1992-04-08
申请号：EP91116543.9
申请日：1991-09-27
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Nii, Kazumi , Okamura, Hisashi , Katoh, Kazunobu
IPC分类号： G03C1/10
CPC分类号： G03C1/061 , Y10S430/158
摘要： Disclosed is a silver halide photographic material containing a compound of a general formula (1) or (2):
wherein ED represents a group that releases the moiety (Time) t -Y-L-Z by reaction with an oxidation product of a developing agent; Time represents a divalent linking group; t represents 0 or 1; Y represents a divalent group comprising a hetero atom through which Y bonds to the moiety ED-(Time) t ; L represents a divalent group which is capable of being cleaved by reaction with components in a developer; and Z represents a monovalent functional group that expresses a development inhibiting effect;
wherein Time, t, L and Z have the same meanings as above; Y represents a divalent group comprising a hetero atom through which Y bonds to the moiety
R 1 represents an aliphatic group or an aromatic group; G 1 represents is
G 2 represents a mere bond, -O-, -S- or
R 2 has the same meaning as R 1 or represents a hydrogen atom; when the compound has plural R 2 's, they may be same as or different from each other; and one of A 1 and A 2 represents a hydrogen atom, and the other represents a hydrogen atom, or an acyl group, an alkylsulfonyl group or an arylsulfonyl group.
The material may reproduce excellently a line original to form an ultra-hard image having a high background density. It also has a broad exposure latitude in halftone dot image-taking work and can form an ultra-hard halftone dot image with a high image quality. The material is useful in formation of ultra-hard negative images by photomechanical process.
摘要翻译：公开了含有通式（1）或（2）的化合物的卤化银照相材料：其中ED表示通过与显影剂的氧化产物反应释放部分（时间）t-Y-L-Z的基团; 时间代表二价连接基团; t代表0或1; Y表示包含杂原子的二价基团，通过该杂原子Y与部分ED-（时间）t键合; L表示能够通过与显影剂中的组分反应而被切割的二价基团; Z代表表现显影抑制效果的一价官能团; 其中Time，t，L和Z具有与上述相同的含义; Y表示包含杂原子的二价基团，通过该杂原子，与部分R 1键合的Y表示脂族基团或芳族基团; G 1表示G 2表示纯粹的键，-O - ， - S-或R 2具有与R 1相同的含义或表示氢原子; 当化合物具有多个R2时，它们可以彼此相同或不同; 并且A 1和A 2中的一个表示氢原子，另一个表示氢原子或酰基，烷基磺酰基或芳基磺酰基。该材料可以很好地再现原始线条以形成具有高背景密度的超硬图像。它在半色调点图像拍摄工作中具有广泛的曝光宽容度，并且可以形成具有高图像质量的超硬半色调点图像。该材料可用于通过光机械加工形成超硬的负片图像。

133. 发明公开

EP0464612A1 Silver halide photographic materials 失效
标题翻译：卤化银照相材料
公开(公告)号：EP0464612A1
公开(公告)日：1992-01-08
申请号：EP91110507.0
申请日：1991-06-25
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Motoki, Masuji, c/o Fuji Photo Film Co., Ltd. , Ohkawa, Atsuhiro, c/o Fuji Photo Film Co., Ltd. , Mihayashi, Keiji, c/o Fuji Photo Film Co., Ltd.
IPC分类号： G03C7/305
CPC分类号： G03C7/30576 , Y10S430/158
摘要： A silver halide photographic material having on a support, at least one photosensitive silver halide emulsion layer, which contains a coupler which releases at least two groups selected from the group consisting of a photographically useful group and a precursor thereof via a timing group upon undergoing a coupling reaction with an oxidized product of a developing agent, in which a plurality of photographically useful groups or precursors thereof are present on different atoms of the timing group, provided that when the plurality of photographically useful groups have a different function to each other, the timing group is not a group utilizing an intramolecular nucleophilic substitution reaction.
摘要翻译：一种卤化银照相材料，它在载体上具有至少一层感光卤化银乳剂层，该层含有一种偶合剂，该偶合剂在经历一个定时基时释放至少两个选自照相用基团及其前体的基团与显影剂的氧化产物偶联反应，其中多个照相用基团或其前体存在于该计时基团的不同原子上，条件是当多个照相用基团具有彼此不同的功能时，定时基团不是利用分子内亲核取代反应的基团。

134. 发明公开

EP0447921A2 Silver halide colour photographic material 失效
标题翻译：。。。。。。。。
公开(公告)号：EP0447921A2
公开(公告)日：1991-09-25
申请号：EP91103745.5
申请日：1991-03-12
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Mihayashi, Keiji, c/o Fuji Photo Film Co., Ltd. , Ichijima, Seiji, c/o Fuji Photo Film Co., Ltd. , Kawagishi, Toshio, c/o Fuji Photo Film Co., Ltd. , Saito, Naoki c/o Fuji Photo Co.,Ltd , Motoki, Masuji c/o Fuji Photo Film Co., Ltd
IPC分类号： G03C7/305
CPC分类号： C07D209/48 , C07D231/12 , C07D231/14 , C07D231/16 , C07D233/56 , C07D233/66 , C07D233/74 , C07D233/80 , C07D233/90 , C07D233/96 , C07D249/04 , C07D249/08 , C07D249/10 , C07D249/12 , C07D249/18 , C07D257/04 , C07D261/14 , C07D263/44 , C07D265/33 , C07D403/06 , C07D403/12 , C07D403/14 , C07D417/12 , C07D417/14 , G03C7/30511 , G03C7/30535 , G03C7/30558 , Y10S430/158
摘要： A silver halide color light-sensitive material including a support having thereon at least one hydrophilic colloidal layer is disclosed, wherein the hydrophilic colloidal layer contains a DIR coupler represented by formula (I):

wherein R¹ represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; R² represents an organic group; X and Y each represent -N= or

wherein R³ represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, an amino group, an acyl group, an acylamino group, a carbamoyl group, a carbamoylamino group, a sulfonyl group, a sulfonylamino group, a sulfamoyl group, a sulfamoylamino group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, a hydroxyl group, a sulfenyl group, a sulfinyl group, an aliphatic group, an aromatic group, or a heterocyclic group; and Z represents a releasable group which is released on reacting with an oxidation product of an aromatic primary amine developing agent to become a development inhibitor or a precursor thereof and which diffuses into a color developing solution and then decomposes to a compound having no substantial influence on photographic properties.
摘要翻译：公开了一种卤化银色感光材料，其包括其上具有至少一个亲水胶体层的载体，其中亲水胶体层含有由式（I）表示的DIR成色剂：其中R 1表示氢原子脂肪族基，芳香族基或杂环基; R 2表示有机基团; X和Y各自表示-N =或，其中R 3表示氢原子，卤素原子，氰基，硝基，氨基，酰基，酰氨基，氨基甲酰基，氨基甲酰基氨基，磺酰基，磺酰基氨基，氨磺酰基，氨磺酰基氨基，烷氧基，芳氧基，烷氧基羰基，芳氧基羰基，羟基，亚磺酰基，亚磺酰基，脂肪族基，芳基或杂环基; Z表示与芳香族伯胺显影剂的氧化物反应而释放而成为显影抑制剂或其前体的可释放基团，并扩散到显色性溶液中，然后分解成不具有显着影响的化合物摄影属性。

135. 发明公开

EP0447920A1 Silver halide color photographic material 失效
标题翻译：远红外线材料。
公开(公告)号：EP0447920A1
公开(公告)日：1991-09-25
申请号：EP91103743.0
申请日：1991-03-12
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Mihayashi, Keiji, c/o Fuji Photo Film Co., Ltd. , Ichijima, Seiji, c/o Fuji Photo Film Co., Ltd. , Kawagishi, Toshio, c/o Fuji Photo Film Co., Ltd. , Saito, Naoki, c/o Fuji Photo Film Co., Ltd. , Motoki, Masuji, c/o Fuji Photo Film Co., Ltd.
IPC分类号： G03C7/36 , G03C7/305
CPC分类号： C07D209/48 , C07D231/12 , C07D231/14 , C07D231/16 , C07D233/56 , C07D233/66 , C07D233/74 , C07D233/80 , C07D233/90 , C07D233/96 , C07D249/04 , C07D249/08 , C07D249/10 , C07D249/12 , C07D249/18 , C07D257/04 , C07D261/14 , C07D263/44 , C07D265/33 , C07D403/06 , C07D403/12 , C07D403/14 , C07D417/12 , C07D417/14 , G03C7/30511 , G03C7/30535 , G03C7/30558 , Y10S430/158
摘要： A silver halide color light-sensitive material containing a coupler represented by formula (I):
wherein R 1 represents a substituted or unsubstituted alkyl group; R 2 and R 3 , same or different, each represent a group capable of substituting a benzene ring; Y represents a halogen atom, an alkoxy group, an alkoxycarbonyl group, a substituted or unsubstituted alkyl group, an alkylthio group, an aryloxy group, an alkylsulfonyl group, an arylthio group, or a carbamoyl group; X represents an organic residue necessary to form a substituted or unsubstituted 5- or 6-membered nitrogen-containing heterocyclic ring together with the nitrogen atom; t represents 0 or an integer of from 1 to 5; and m represents 0 or an integer of from 1 to 4.
The coupler of formula (I) is excellent in dye image stability.
摘要翻译：含有式（I）表示的成色剂的卤化银色感光材料：其中R1表示取代或未取代的烷基; R2和R3相同或不同，各自表示能够取代苯环的基团; Y表示卤素原子，烷氧基，烷氧基羰基，取代或未取代的烷基，烷硫基，芳氧基，烷基磺酰基，芳硫基或氨基甲酰基。 X表示与氮原子一起形成取代或未取代的5或6元含氮杂环所必需的有机残基; l表示0或1〜5的整数， m表示0或1〜4的整数。式（I）的成色剂的染料影像稳定性优异。

136. 发明公开

EP0444501A2 Photographic material and process comprising a compound capable of forming a wash-out dye 失效
标题翻译：一种照相材料和方法，包括的化合物，能够形成色偏的。
公开(公告)号：EP0444501A2
公开(公告)日：1991-09-04
申请号：EP91102366.1
申请日：1991-02-19
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Chen, Teh-Hsuan, c/o EASTMAN KODAK COMPANY , Kilminster, Kenneth Norman, c/o EASTMAN KODAK CO. , Poslusny, Jerrold Neal, c/o EASTMAN KODAK COMPANY , Slusarek, Wojciech, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： C07D257/04 , G03C7/30576 , Y10S430/156 , Y10S430/158 , Y10S430/16
摘要： Photographic compound (A) capable of releasing a photographically useful group is represented by the formula: SOL-CAR-LINK-PUG wherein SOL is a water-solubilizing group; CAR is a carrier moiety that, upon reaction with oxidized developing agent, is capable of releasing LINK-PUG and capable of forming a compound that is washed out of the photographic element during photographic processing; LINK-PUG is in turn capable of releasing a photographically useful group (PUG) during photographic processing and LINK-PUG is represented by the formula:

wherein X, R₁, R₂, R₃, R₄ and PUG are as defined in the application. The photographic compound (A) enables formation of easily removable compounds in photographic elements and processes that provide images having improved acutance.
摘要翻译：照相化合物（A）能够释放照相用基团是由下式表示：SOL-CAR-LINK-PUG worin SOL是水溶性基团; CAR是载体部份，即，在与氧化的显影剂反应，能够释放LINK-PUG和能够形成化合物并洗出照相冲洗加工过程中的照相元件的组成; LINK-PUG进而能够在照相冲洗加工和LINK-PUG是由下式表示释放照相用基团（PUG）的： worin X，R1，R2，R3，R4和PUG如本申请中定义的，照相化合物（A），能够形成易于拆卸的化合物在照相元件和过程并提供具有改进的锐度的图像。

137. 发明公开

EP0438150A3 Silver halide colour photographic material 失效
标题翻译：银色彩色摄影材料
公开(公告)号：EP0438150A3
公开(公告)日：1991-08-21
申请号：EP91100514.8
申请日：1991-01-17
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Ohkawa, Atsuhiro, c/o Fuji Photo Film Co., Ltd. , Motoki, Masuji, c/o Fuji Photo Film Co., Ltd. , Mihayashi, Keiji, c/o Fuji Photo Film Co., Ltd.
IPC分类号： G03C7/305
CPC分类号： G03C7/30529 , G03C7/30541 , G03C7/30576 , Y10S430/158
摘要： A silver halide color photographic material comprising on a support at least a silver halide emulsion layer, comprising a compound represented by general formula (I):
as described in the specification.

138. 发明公开

EP0440195A2 Silver halide color photographic material 失效
标题翻译：远红外线材料。
公开(公告)号：EP0440195A2
公开(公告)日：1991-08-07
申请号：EP91101209.4
申请日：1991-01-30
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Ono, Michio, c/o Fuji Photo Film Co., Ltd. , Hanaki, Kouichi, c/o Fuji Photo Film Co., Ltd. , Sakanoue, Kei, c/o Fuji Photo Film Co., Ltd. , Hirano, Shigeo, c/o Fuji Photo Film Co., Ltd. , Yamamoto, Mitsuru, c/o Fuji Photo Film Co., Ltd.
IPC分类号： G03C7/305
CPC分类号： G03C7/30511 , Y10S430/156 , Y10S430/158
摘要： A novel silver halide color photographic material is provided comprising on a support at least one silver halide emulsion layer containing at least one of the compounds represented by formulae (I) to (III):
wherein R 11 represents
or
in which R 13 represents an alkyl, aryl or heterocyclic group, and R 14 and R 15 each represents hydrogen, alkyl group or aryl group; R 12 represents a substituent having a Hammett's substituent constant ap of 0.3 or less; n represents an integer 0 to 2, and when n is 2, the two R 12 's may be the same or different; B represents a group which releases PUG after being separated from a hydroquinone nucleus; PUG represents a development inhibitor; t represents an integer; and A and A' each represents hydrogen or a group capable of being removed by an alkali; R 11 and R 12 , R 11 and A or A', R 12 and A or A', and two R 12 's may together form a ring;
wherein Q 1 represents an atomic group containing at least one hetero atom and is required for the formation of a heterocyclic group containing 5 or more members together with carbon atoms connected thereto; R 21 represents a group capable of substituting on the hydroquinone nucleus; and B, PUG, ℓ, A and A' are as defined above;
wherein R 31 represents an alkyl group containing two or more carbon atoms in which the carbon atom adjacent to the carbonyl group is not substituted by a hetero atom, a cycloalkyl group, an aryl group or a heterocyclic group; R 32 and R 33 each represents hydrogen or a substituent having a Hammett's substituent constant σp of 0.3 or less; and B, PUG, ℓ, A and A' are as defined above. In a preferred embodiment, the compound represented by the general formula (III) is one represented by the general formula (IIIA):
wherein R 34 represents a substituent; PUG, A, A', B and ℓ have the same meanings as defined in the general formula (III); and n' represents an integer 2 or more. The compound represented by the general formula (III) is also one represented by the general formula (IIIB):
wherein R 35 represents a substituent; A, A', B, PUG, and t have the same meanings as defined in formula (III); and m represents an integer 1 to 5, and when m is 2 ormore, the plurality of R 35 's may be the same or different.
摘要翻译：提供了一种新颖的卤化银彩色照相材料，其在载体上包含至少一种含有至少一种式（I）至（III）表示的化合物的卤化银乳剂层：其中R11表示或CHEM >其中R 13表示烷基，芳基或杂环基，R 14和R 15各自表示氢，烷基或芳基; R12表示哈米特取代基常数σp为0.3以下的取代基; n表示0〜2的整数，n为2时，两个R 12可以相同也可以不同， B表示在与氢醌核分离后释放PUG的基团; PUG代表发育抑制剂; l表示整数; A和A'各自表示氢或能够被碱除去的基团; R11和R12，R11和A或A'，R12和A或A'，两个R12可以一起形成环; 其中Q 1表示含有至少一个杂原子的原子团，并且是形成含有5个或更多个成员以及与其连接的碳原子的杂环基所必需的; R 2表示能够在氢醌核上取代的基团; 和B，PUG，l，A和A'如上所定义; 其中R31表示含有两个或更多个碳原子的烷基，其中与羰基相邻的碳原子未被杂原子，环烷基，芳基或杂环基取代; R32和R33各自表示氢或Hammett取代基常数σp为0.3以下的取代基; 和B，PUG，l，A和A'如上所定义。在优选的实施方案中，由通式（III）表示的化合物是由通式（IIIA）表示的化合物：其中R 34表示取代基; PUG，A，A'，B和I与通式（III）中定义相同; n'表示2以上的整数。由通式（III）表示的化合物也是由通式（IIIB）表示的化合物：其中R 35表示取代基; A，A'，B，PUG和l具有与式（III）中定义的相同的含义; m表示1〜5的整数，当m为2以上时，多个R 35可以相同也可以不同。

139. 发明公开

EP0401612A3 Farbfotografisches Aufzeichnungsmaterial mit einem DIR-Kuppler 失效
标题翻译：彩色摄影记录材料与DIR COUPLER
公开(公告)号：EP0401612A3
公开(公告)日：1991-06-05
申请号：EP90109914.3
申请日：1990-05-24
申请人： Agfa-Gevaert AG
发明人： Vetter, Hans, Dr. , Odenwälder, Heinrich, Dr. , Bergthaller, Peter, Dr. , Krüger, Thomas, Dr.
IPC分类号： G03C7/305
CPC分类号： G03C7/305 , Y10S430/158
摘要： Aus DIR-Kupplern der Formel I werden bei Farbentwicklung hochwirksame Silberhalogenidentwicklungsinhibitoren freigesezt. Bei Verwendung solcher DIR-Kuppler in farbfotografischen Silberhalogenidmaterialien werden hohe Kanteneffekte und hohe Interimageeffekte erhielt.
A-(TIME) n -Z I
In Formel I bedeuten
A den Rest eines Kupplers, der unter den Bedingungen der fotografischen Entwicklung mit dem Oxidationsprodukt eines Silberhalogenidentwicklungsmittels kuppelt und dabei den Rest der Formel
-(TIME) n- Z
freisetzt; TIME ein Bindeglied, das bei Reaktion des Kupplers mit dem Oxidationsprodukt eines Silberhalogenidentwicklungsmittels zusammen mit dem daran gebundenen Rest Z (einem Triazolring) freigesetzt wird und seinerseits unter den Entwicklungsbedingungen den Rest Z verzögert freisetzt;
n 0 oder 1;
Z einen Triazolrest einer der Formeln
R¹ Alkylthio;
R² H, Alkyl, Alkylthio, Aryl oder eine heterocyclische Gruppe, wobei mindestens einer der Reste R¹ und R² im Abstand von 2 bis 4 Atomen vom Triazolring eine in wäßrigem Alkali verseifbare Gruppe -CO-OR³, -O-CO-OR³ oder -O-CO-R³ enthält;
R³ Alkyl, Cycloalkyl oder Aryl.

140. 发明公开

EP0362870A3 Silver halide color photographic material 失效
标题翻译：银色彩色摄影材料
公开(公告)号：EP0362870A3
公开(公告)日：1991-05-29
申请号：EP89118591.0
申请日：1989-10-06
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Ichijima, Seiji, c/o Fuji Photo Film Co., Ltd. , Shimada, Yasuhiro, c/o Fuji Photo Film Co., Ltd.
IPC分类号： G03C7/305
CPC分类号： C07D403/12 , C07D403/14 , G03C7/30576 , Y10S430/158
摘要： A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide color photographic material contains a compound represented by the following general formula (I):
wherein A represents a group whose bond to (L)t-B is capable of being cleaved upon reaction with an oxidation product of a developing agent; L represents a group whose bond to B is capable of being cleaved after being cleaved from A; B represents a 5-membered, 6-membered or 7-membered. nitrogen-containing unsaturated heterocyclic group which has 2 to 6 carbon atoms, which is connected to A-(L) at the nitrogen atom, and which has a sulfonamido group and a development inhibitor group or a precursor thereof on the ring carbon atoms; t represents an integer of 0 to 2, and when ℓ represents 2, the two L's may be the same or different. The silver halide color photographic material has excellent sharpness and color reproducibility.
摘要翻译：一种卤化银彩色照相材料，包括其上具有至少一个卤化银乳剂层的载体，其中所述卤化银彩色照相材料含有由以下通式（I）表示的化合物：A-（L）-B（I）其中A表示与（L）-B键的键与显影剂的氧化产物反应时能够裂解的基团; L表示与B键合后能够断裂的基团， B代表5元，6元或7元。具有2〜6个碳原子的含氮不饱和杂环基，其在氮原子上与A-（L）1连接，并且在环碳原子上具有亚磺酰氨基和显影抑制基团或其前体; l表示0〜2的整数，当l表示2时，两个L可以相同或不同。卤化银彩色照相材料具有优异的清晰度和色彩再现性。

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