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    • 119. 发明公开
    • Silver halide photographic material
    • 卤化银照相材料
    • EP0615159A1
    • 1994-09-14
    • EP94103296.3
    • 1994-03-04
    • FUJI PHOTO FILM CO., LTD.
    • Asami, Masahiro, c/o FUJI PHOTO FILM CO., LTD.Kawata, Ken, c/o FUJI PHOTO FILM CO., LTD.
    • G03C1/26G03C1/37G03C1/047
    • C09B23/0066C09B23/0075G03C1/035G03C1/047G03C1/127G03C1/28G03C2001/03517G03C2001/03535G03C2001/0818
    • Disclosed is a silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the silver halide emulsion layer contains a silver halide emulsion sensitized by a methine dye represented by following formula (I) and the total content of calcium in the photographic constituting layers on the support is not more than 10 mg/m², wherein the silver halide emulsion layer contains a silver halide emulsion sensitized by a methine dye represented by following formula (I) and any one of the photographic constituting layers of the photographic material contains at least one compound represented by one of following formulae (II) to (X) and wherein the silver halide emulsion layer contains a silver halide emulsion sensitized by following formula (XI) or (XII);

      wherein Q represents a non-metallic atomic group necessary for forming a 5-membered or 6-membered ring; R₁ to R₁₁ each represents a hydrogen atom or a substituent, however, at least one of R₁ to R₃ represents a group containing an aromatic group and R₄ and R₅ are not a hydrogen atom; L₁ to L₃ each represents a methine group; n represents an integer of from 0 to 6; M represents a counter ion neutralizing an electrostatic charge; and m represents 0 or 1;


         wherein R² to R¹⁹, Y, Z¹, Z², n and m each represents that disclosed in the Detailed Description of the Invention;

      wherein R₂₁ represents a phenyl group or a 1-naphthyl group, R₂₂ and R₂₃ each represents a methyl group or an ethyl group, X⁻ represents I⁻, Br⁻ or an arylsulfonate ion, R₃₂ represents a 2-phenoxyethyl group, a 2-(1-naphthoxy)ethyl group, a 2-(2-naphthoxy)ethyl group or a 2-(4-phenylphenoxy)ethyl group and R₃₃ represents a methyl group or an ethyl group. The material provides an excellent stability showing less deviation of the performance at the production thereof and provides an excellent processing stability and less depositions in processing liquids and thus forms less streaks even in continuous processing.
    • 本发明公开了一种卤化银彩色照相材料,该材料包括在其上具有至少一层感光卤化银乳剂层的载体,其中卤化银乳剂层含有由下式(I)表示的次甲基染料敏化的卤化银乳剂, 载体上照相构成层中的钙含量不超过10mg / m 2,其中卤化银乳剂层含有由下式(Ⅰ)表示的次甲基染料敏化的卤化银乳剂和任何一种照相组分 (Ⅺ)或(II)敏化的卤化银乳剂层;以及(XI)卤化银乳剂层含有至少一种由下式(Ⅱ)至 其中Q表示形成5元或6元环所必需的非金属原子团; R 1至R 11各自代表氢原子或取代基,然而,R 1至R 3中的至少一个代表含有芳基的基团,而R 4和R 5不是氢原子; L 1至L 3各自代表次甲基; n表示0至6的整数; M代表中和静电荷的抗衡离子; 并且m代表0或1; 其中R 2至R 16,Y,Z 1,Z 2,n和m各自代表本发明详述中公开的那些; 其中R 21代表苯基或1-萘基,R 22和R 23各代表甲基或乙基,X - 代表I - ,Br - 或芳基磺酸根离子,R 32代表2-苯氧基乙基, (1-萘氧基)乙基,2-(2-萘氧基)乙基或2-(4-苯基苯氧基)乙基,R 33表示甲基或乙基。 该材料提供了极好的稳定性,在生产时表现出较小的性能偏差,并且提供了优异的加工稳定性和较少的加工液体沉积,因此即使在连续加工中也形成较少的条纹。
    • 120. 发明公开
    • Silver halide emulsion and method of preparing the same
    • Silberhalogenidemulsion und Verfahren zu ihrer Herstellung。
    • EP0610796A1
    • 1994-08-17
    • EP94101558.8
    • 1994-02-02
    • FUJI PHOTO FILM CO., LTD.
    • Okutsu, Tetsuo, c/o FUJI PHOTO FILM CO., LTD.
    • G03C1/005G03C1/047
    • G03C1/0051
    • A silver halide emulsion comprising 50% to 100% of projected area of all silver halide grains are occupied by hexagonal tabular silver halide grains which have an aspect ratio of 8 to 40, which have a ratio of the longest side to the shortest side of 1 to 2, and which have an average silver iodide content of 2 mol% to 10 mol%, and all silver halide grains have a grain size of variation coefficient of 8% to 20%. A method of preparing the emulsion described above, comprising a nucleation step and a grain-growing step and in which a dispersant used in the nucleation step is low-molecular gelatin having a molecular weight of 5,000 to 25,000, and nucleation time t (seconds) in the nucleation step satisfies the relationship of 1
    • 包含所有卤化银颗粒的投影面积的50%至100%的卤化银乳剂由具有8至40的纵横比的六角形片状卤化银颗粒占据,其中最长边与最短边之比为1 至2,平均碘化银含量为2mol%至10mol%,并且所有卤化银颗粒的变化系数的晶粒尺寸为8%至20%。 一种制备上述乳液的方法,包括成核步骤和晶粒生长步骤,并且其中在成核步骤中使用的分散剂是分子量为5,000至25,000的低分子明胶和成核时间t(秒) 在成核步骤满足1