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111. 发明公开

EP1756218A1 BLOCK COPOLYMERS USEFUL IN THERMOPLASTIC GEL COMPOSITIONS THAT CAN BE CONVERTED INTO THERMOSET GEL COMPOSITIONS BY EXPOSURE TO RADIATION 审中-公开
标题翻译： FOR USE IN热塑性凝胶组合物通过暴露于辐射中的硬质塑料的凝胶组合物嵌段共聚物转化为BE
公开(公告)号：EP1756218A1
公开(公告)日：2007-02-28
申请号：EP05730771.2
申请日：2005-03-25
申请人： KRATON Polymers Research B.V.
发明人： ST.CLAIR, David, J.
IPC分类号： C08L53/02 , C08F297/04
CPC分类号： C08L53/025 , C08F297/044 , C08F297/046
摘要： Disclosed is a thermoplastic gel composition that can be fabricated into an article, such as an air freshener or a gasket, and then be converted into a thermoset gel composition by exposure to radiation. The thermoset composition has better slump resistance at high temperatures compared to the thermoplastic composition. Prior to irradiation, the composition is a thermoplastic and so it can be easily mixed and formed into an article. Also disclosed are novel block copolymers.

112. 发明授权

EP1584654B1 Butyl rubber based sealant 有权
标题翻译：密封基于丁基橡胶
公开(公告)号：EP1584654B1
公开(公告)日：2006-12-20
申请号：EP04101425.9
申请日：2004-04-06
申请人： KRATON Polymers Research B.V.
发明人： Vermunicht, Geert E.A. KRATON Polymers Res. S.A. , Roumache, Olivier KRATON Polymers Res. S.A.
IPC分类号： C08L23/22 , C08L53/02
CPC分类号： C08L53/025 , C08F297/04 , C08F297/044 , C08L23/22 , C08L53/02 , C08L2205/02 , C08L2666/02 , C08L2666/04 , C08L2666/06 , C08L2666/24 , C09J123/22 , C09J153/025
摘要： A butyl rubber based sealant is provided comprising, calculated on the sealant, a) from 10 to 50% by weight (wt%) of butyl rubber, b) a hydrogenated styrenic block copolymer having at least two resinous endblocks of polymerized monovinyl arene and an elastomeric midblock of polymerized and subsequently hydrogenated conjugated diene or dienes, c) from 0 to 30 wt% of one or more polyolefins, d) from 0 to 60 wt% of one or more plasticizers and e) from 0 to 80 wt% of one or more fillers and filler deactivators, f) from 0 to 30 wt% of one or more tackifying resins, g) from 0 to 30 wt% of one or more other additives, characterized in that component b) is a linear hydrogenated styrenic block copolymer having an apparent molecular weight in the range of from 200,000 to 500,000 or a radial hydrogenated styrenic block copolymer having an apparent molecular weight in the range of from n times 100,000 to 250,000, n equals the number of polymer arms, and component (a) has a content of hydrogenated 1,2-polymerized conjugated dienes (vinyl content) of greater than 40% and a content of poly(monovinyl arene) in the range of from 20 to 50%, wherein said hydrogenated styrenic block copolymer comprises no more than 5% by weight of the sealant and wherein said hydrogenated styrenic block copolymer comprises no more than 10% by weight of the butyl rubber/hydrogenated styrenic block copolymer blend.

113. 发明公开

EP1699869A1 ADHESIVE FORMULATIONS FROM RADIAL (S-I/B)X POLYMERS 有权转让
标题翻译： KLEBSTOFFFORMULIERUNGEN AUS RADIALEN（S-I / B）X-POLYMEREN
公开(公告)号：EP1699869A1
公开(公告)日：2006-09-13
申请号：EP04813955.4
申请日：2004-12-13
申请人： KRATON Polymers Research B.V.
发明人： DUBOIS, Donn, A.
IPC分类号： C08L53/02 , C09J153/02 , C08F297/04
CPC分类号： C09J153/02 , C08F297/04 , C08F297/044 , C08L53/00 , C08L53/02 , C08L53/025 , C08L2666/24 , C09J153/025
摘要： The invention relates to an adhesive composition comprising (i) one or more styrenic block copolymer compositions, (ii) a tackifier resin, and (iii) one or more plasticizers, wherein said styrenic block copolymer composition comprises: a. a tetra-branched block copolymer (IV) represented by the general formula (A-B)4X; b. a tri-branched block copolymer (III) represented by the general formula (A-B)3X; c. a di-branched block copolymer (II) represented by the general formula (A-B)2X; and d. a linear diblock copolymer (I) represented by the general formula A-B; where: i. A represents a polymer block of a mono alkenyl arene; ii. B represents a polymer block of a mixture of isoprene and 1,3-butadiene in a weight ratio of isoprene to butadiene from about 70:30 to about 40:60; iii. X represents the residue of a multi-functional coupling agent; iv. the weight percent of A blocks is from about 14% to about 22%; v. the relative amounts of copolymers IV, III, II, and I are from 0 to 20 weight percent IV, from 50 to 80 weight percent III, from 0 to 20 weight percent II and from 20 to 50 weight percent I, where the total of I, II, III and IV equals 100 weight percent; and vi. the melt flow rate of the polymer composition is at least 2.0 g/10 minutes at 200° C./5 kg as measured by ASTM D1238 (D condition).
摘要翻译：本发明涉及一种粘合剂组合物，其包含（i）一种或多种苯乙烯类嵌段共聚物组合物，（ii）增粘剂树脂和（iii）一种或多种增塑剂，其中所述苯乙烯嵌段共聚物组合物包含：a。由通式（A-B）4X表示的四支链嵌段共聚物（IV）湾由通式（A-B）3X表示的三支链嵌段共聚物（III）; C。由通式（A-B）2X表示的二支链嵌段共聚物（II）; 和d。由通式A-B表示的直链二嵌段共聚物（I）; 其中：i。 A表示单烯基芳烃的聚合物嵌段; II。 B表示异戊二烯与丁二烯的重量比为约70:30至约40:60的异戊二烯和1,3-丁二烯的混合物的聚合物嵌段; III。 X表示多官能偶联剂的残基; IV。 A块的重量百分比为约14％至约22％; v。共聚物IV，III，II和I的相对量为IV为0至20重量％，IV为50至80重量％，II为0至20重量％，I为20至50重量％，其中 I，II，III和IV的总和等于100重量％; 和vi。根据ASTM D1238（D条件）测量，聚合物组合物的熔体流动速率在200℃下为至少2.0g / 10分钟。

114. 发明授权

EP1474495B1 SOLVENT-FREE, HOT MELT ADHESIVE COMPOSITION COMPRISING A CONTROLLED DISTRIBUTION BLOCK COPOLYMER 有权
标题翻译：无溶剂热熔粘合剂组合物，与控制分布的嵌段共聚物CONTAINS
公开(公告)号：EP1474495B1
公开(公告)日：2006-06-28
申请号：EP03707250.1
申请日：2003-02-07
申请人： KRATON Polymers Research B.V.
发明人： HANDLIN, Dale, L., Jr. , WILLIS, Carl, L. , MAES, Caroline, R., N.
IPC分类号： C09J153/00 , B32B9/02 , B32B25/00
CPC分类号： C09J153/02 , C08F287/00 , C08F297/04 , C08L23/10 , C08L23/12 , C08L25/06 , C08L53/02 , C08L53/025 , C08L77/00 , C08L91/00 , C08L95/00 , C08L101/00 , C08L2666/02 , C08L2666/24 , C09D153/02 , C09D153/025 , C09J153/025 , Y10T428/13 , Y10T428/249921 , Y10T428/31931 , C08L2666/04 , C08L53/00
摘要： The present invention relates to elastomeric articles prepared from novel anionic block copolymers of mono alkenyl arenes and conjugated dienes, and to blends of such block copolymers with other polymers. The block copolymers are selectively hydrogenated and have mono alkenyl arene end blocks and controlled distribution blocks of mono alkenyl arenes and conjugated dienes. The block copolymer may be blended with at least one other polymer selected from the group consisting of olefin polymers, styrene polymers, amorphous resins, and engineering thermoplastic resins.

115. 发明公开

EP1633795A1 ARTICLES PREPARED FROM HYDROGENATED BLOCK COPOLYMERS 审中-公开
标题翻译：的氢化嵌段共聚物生产的OBJECTS
公开(公告)号：EP1633795A1
公开(公告)日：2006-03-15
申请号：EP04754037.2
申请日：2004-06-03
申请人： KRATON Polymers Research B.V. , Handlin, Dale L. , Willis, Carl L. , De Groot, Hendrik , Clawson, Margaret A. B. , Joly, Gert J. , Maris, Catherine A. L. , Djiauw, Lie
发明人： HANDLIN, Dale, L. , WILLIS, Carl, L. , DE GROOT, Hendrik , CLAWSON, Margaret, A., B. , JOLY, Gert, J. , MARIS, Catherine, A., L. , DJIAUW, Lie
IPC分类号： C08F297/04 , C08L53/02 , C08F8/04
CPC分类号： C08F8/42 , C08F8/04 , C08F297/04 , C08F297/044 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L23/10 , C08L25/04 , C08L25/06 , C08L53/025 , C08L57/02 , C08L2205/03 , C08L2205/035 , Y10S525/901 , Y10S526/938 , C08L2666/24 , C08L2666/02 , C08L55/02 , C08L2666/06 , C08L53/00
摘要： The present invention relates to articles prepared from novel anionic block copolymers of mono alkenyl arenes and conjugated dienes, and to blends of such block copolymers with other polymers. The block copolymers are selectively hydrogenated and have mono alkenyl arene end blocks and conjugated diene mid blocks. The block copolymer may be blended with at least one other polymer selected from the group consisting of olefin polymers, styrene polymers, amorphous resins and engineering thermoplastic resins.

116. 发明授权

EP1325042B1 A METHOD FOR MAKING SELECTIVELY HYDROGENATED BLOCK COPOLYMERS OF VINYL AROMATIC HYDROCARBONS AND CONJUGATED DIENES 有权
标题翻译：用于生产乙烯基芳香族烃和共轭二烯的选择性氢化嵌段共聚物
公开(公告)号：EP1325042B1
公开(公告)日：2006-03-15
申请号：EP01966220.4
申请日：2001-08-24
申请人： KRATON Polymers Research B.V.
发明人： JOHNSON, Kimberly, Ann , DE JONG, Wouter , SCHISLA, David, K.
IPC分类号： C08F8/04
CPC分类号： C08F297/04 , C08F8/04
摘要： Disclosed is a method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes comprising: a) anionically polymerizing vinyl aromatic hydrocarbons and conjugated dienes to produce block copolymers with living chain ends; b) terminating the living chain ends, to produce a terminated block copolymer, with a member from the group consisting of an alcohol, hydrogen, and mixtures thereof, to prepare a terminated block copolymer; and c) contacting the terminated block copolymers with hydrogen at a temperature of from 20 to 175° C in the presence of a catalyst prepared by combining a cobalt carboxylate with an aluminum alkyl, wherein: (i) if the polymer is terminated with an alcohol and the alcohol is a linear alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the alcohol: living chain end molar ratio is from 0.05 to 1.2; (ii) if the polymer is terminated with an alcohol and the alcohol is a branched alcohol, the branched alcohol is used to terminate the living chain ends in an amount such that the alcohol: living chain end molar ration is from 0.05 to about 3.0; an (iii) if the polymer is terminated with an alcohol and the alcohol is a mixture of a linear alcohol and a branched alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the linear alcohol: living chain end molar ration is from 0.05 to 1.2.

117. 发明公开

EP1612243A1 Bituminous roofing composition 审中-公开
标题翻译： Bitumenhaltige Dachabdeckungsmasse
公开(公告)号：EP1612243A1
公开(公告)日：2006-01-04
申请号：EP04103061.0
申请日：2004-06-30
申请人： KRATON Polymers Research B.V.
发明人： Trommelen, Erik A.T. , Bodt, Duco , Vonk, Willem C. , Van Dijk, Cornelis Martinus
IPC分类号： C08L95/00 , C08L53/02
CPC分类号： C08L95/00 , C08L53/02 , C08L53/00 , C08L2666/24
摘要： The present invention provides a bituminous roofing composition which comprises from 2 to 20 percent by weight, based on block copolymer plus bitumen, of a styrenic block copolymer composition, the balance being a bituminous material, wherein the styrenic block copolymer composition comprises:

a. from 5 to 70% by weight of a first block copolymer selected from linear styrenic block copolymers (SBC1), radial styrenic block copolymers (SBC2) and mixtures thereof, wherein:

i. said linear block copolymer comprises at least two polymer blocks each substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound and having an apparent molecular weight greater than 250,000 and;
ii. said radial styrenic block copolymer has three or more polymer arms attached to the residue of a cross-linking agent or multifunctional compound, and comprises at least two polymer blocks each substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound and wherein the polymer arms have an average apparent molecular weight greater than 125,000 and

b. from 95 to 30% by weight of an elastomer (EI) having an apparent molecular weight of 120,000 to 250,000.

The present invention also comprises a easy welding roll roofing membrane which comprises a reinforcing mat and the above described bituminous composition which saturates and/or coats the reinforcing mat.
摘要翻译：本发明提供了一种沥青屋面组合物，其包含基于嵌段共聚物加沥青的2至20重量％的苯乙烯嵌段共聚物组合物，余量为沥青材料，其中所述苯乙烯嵌段共聚物组合物包含：a。 5至70重量％的选自线性苯乙烯嵌段共聚物（SBC1），径向苯乙烯系嵌段共聚物（SBC2）及其混合物的第一嵌段共聚物，其中：所述线性嵌段共聚物包含至少两个聚合物嵌段，每个聚合物嵌段基本上由芳族乙烯基化合物制成，至少一个聚合物嵌段基本上由共轭二烯化合物制成并具有大于25万的表观分子量; II。所述径向苯乙烯嵌段共聚物具有连接到交联剂或多官能化合物的残基上的三个或更多个聚合物臂，并且包含至少两个基本上由芳族乙烯基化合物制成的聚合物嵌段和至少一个基本上由共轭二烯化合物，其中聚合物臂的平均表观分子量大于125,000，b。 95〜30重量％的表观分子量为12万〜25万的弹性体（EI）。本发明还包括容易的焊接辊屋面膜，其包括增强垫和上述沥青组合物，其使增强垫饱和和/或涂覆。

118. 发明公开

EP1586606A1 An asphalt binder based on polymer modified bitumen, hot mix asphalts made thereof, and pavements made therefrom 审中-公开
标题翻译：沥青混合料沥青混合沥青沥青沥青沥青沥青沥青
公开(公告)号：EP1586606A1
公开(公告)日：2005-10-19
申请号：EP04101527.2
申请日：2004-04-14
申请人： KRATON Polymers Research B.V.
发明人： Korenstra, Jan , Vonk, Willem C. , van Dijk, Cornelis Martinus
IPC分类号： C08L95/00 , C08L53/02
CPC分类号： C08F297/04 , C08F297/044 , C08L95/00 , C08L2666/02 , C08L2666/24 , C09J153/02 , Y10T428/31917 , Y10T428/3192 , C08L53/00
摘要： An asphalt binder comprising 85 to 98.5 parts by weight of a bitumen and 15-1.5 parts by weight of a polymer composition, wherein the polymer composition comprises:

(i) from 5 to 70% by weight of a linear styrenic block copolymer (SBC1) comprising at least two polymer blocks each substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound and having an apparent molecular weight greater than 250,000 and/or a radial styrenic block copolymer (SBC2) having three or more polymer arms attached to the residue of a cross-linking agent or multifunctional compound, comprising at least two polymer blocks each substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound and wherein the polymer arms have an average apparent molecular weight greater than 125,000 and
(ii) from 95 to 30% by weight of an elastomer (EI) having an apparent molecular weight in the range of 120,000 to 250,000, preferably a styrenic diblock copolymer having one polymer block substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound.
摘要翻译：一种沥青粘合剂，其包含85至98.5重量份的沥青和15-1.5重量份的聚合物组合物，其中所述聚合物组合物包含：（i）5-70重量％的线性苯乙烯系嵌段共聚物（SBC1）包括至少两个聚合物嵌段，每个聚合物嵌段基本上由芳香族乙烯基化合物制成，至少一个聚合物嵌段基本上由共轭二烯化合物制成，表观分子量大于25万，和/或具有三个或更多个分子量的径向苯乙烯嵌段共聚物（SBC2）连接到交联剂或多官能化合物的残基上的更多聚合物臂包含至少两个基本上由芳族乙烯基化合物制成的聚合物嵌段和至少一个基本上由共轭二烯化合物制成的聚合物嵌段，并且其中聚合物臂具有大于125,000的平均表观分子量和（ii）95至30重量％的具有表观分子量的弹性体（EI） e为120,000至250,000，优选苯乙烯二嵌段共聚物，其具有基本上由芳族乙烯基化合物制成的一个聚合物嵌段和至少一个基本上由共轭二烯化合物制成的聚合物嵌段。

119. 发明公开

EP1581571A1 CONJUGATED DIENE BLOCK (CO) POLYMERS AND PROCESS FOR PREPARING SAME 失效转让
标题翻译：用于生产共轭DIEN BLOCK（共）聚合物
公开(公告)号：EP1581571A1
公开(公告)日：2005-10-05
申请号：EP03799606.3
申请日：2003-12-30
申请人： KRATON Polymers Research B.V.
发明人： WILLIS, Carl, Lesley
IPC分类号： C08F297/02
CPC分类号： C08F297/02 , C08F36/04 , C08F4/48
摘要： Disclosed is a process for preparing polymers and copolymer blocks of conjugated dienes with varying amounts of branching comprising the use of a microstructure control agent and a microstructure control agent deactivant. The polymerization can be started with or without a microstructure control agent. At some point in the polymerization prior to the completion of the addition of the conjugated diene to the polymer, the microstructure control agent can be deactivated, either partially or completely, resulting in a polymer or copolymer block having a region of less branching adjacent to a region of more branching. Preferred microstructure control agent deactivants are metal alkyls such as triethyl aluminum.

120. 发明公开

EP2785883A1 AGING (WEATHERING) INHIBITION METHOD OF IRON ORE PELLETS DURING STOCKPILING 审中-公开
标题翻译：一种抑制铁矿石PELLETES的衰老过程中储存
公开(公告)号：EP2785883A1
公开(公告)日：2014-10-08
申请号：EP12772705.5
申请日：2012-09-04
申请人： Vale S.A.
发明人： VIEIRA, Maria Beatriz Harmendani , BOTELHO, Marcus Eduardo Emrich
IPC分类号： C22B1/24
CPC分类号： C22B1/2406 , C22B1/16 , C22B1/2413
摘要： The present invention refers to an effective method for minimizing the problems of iron ore pellet degradation by weathering during their stockpiling, i.e., by providing an appropriate method for improving the state of the art with regard to iron ore pellet resistance related just to the hydration process of the slag phase. Thus, in order to minimize hydration in the slag phase, stabilizers are introduced into the mixture used to produce iron ore pellets prior to being heat-treated.
摘要翻译：本发明涉及在有效的方法用于通过其储存期间，即在风化减少铁矿石球团退化的问题，通过在适当的方法相对于只与水合过程铁矿石球团性改进现有技术的状态提供的渣相。因此，为了最大限度地减少在渣相水合，稳定剂被引入到用于生产之前被加热处理铁矿石球团的混合物。

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