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    • 103. 发明公开
    • Metallocene catalysts for olefin polymerization and methog of polymerizing olefins using the metallocene catalysts
    • 用于烯烃聚合的茂金属催化剂和使用茂金属催化剂聚合烯烃的方法
    • EP2174963A2
    • 2010-04-14
    • EP09016141.5
    • 1999-09-08
    • Samsung General Chemicals Co., Ltd.
    • Lyu, Yi-YeolChang, SeokYoon, Keun-ByoungJung, Won-Cheol
    • C08F210/00C08F4/642C07F17/00
    • C08F10/00C07F17/00C08F4/65908C08F4/65912C08F4/65916C08F4/6592C08F4/65925C08F4/65927C08F10/02C08F110/02C08F210/16C08F2410/03C08F2420/02Y10S526/943C08F210/14C08F4/65904
    • The new metallocene catalysts according to the present invention are prepared by reacting a metallocene compound with a compound having at least two functional groups. The metallocene compound is a transition metal compound, which is coordinated with a main ligand such as cyclopentadienyl group, and an ancillary ligand. The functional groups in the compound are selected from the group consisting of a hydroxyl group, an alkyl or aryl magnesium halide, a thiol group, a primary amine group, a secondary amine group, a primary phosphorous group, a secondary phosphorous group, etc. The metallocene catalysts according to the present invention have a structure in which an ancillary ligand of a metallocene compound is bonded to the functional groups of a compound having at least two functional groups. A structure of the metallocene catalysts can be varied with the type of a metallocene compound and a compound having at least two functional groups, and the molar ratio of each reactant. The metallocene catalysts are employed with a co-catalyst for olefin polymerization. The co-catalyst is an organometallic compound, or a mixture of non-coordinated Lewis acid and alkyl aluminium as it is well known in the art.
    • 根据本发明的新型茂金属催化剂通过使茂金属化合物与具有至少两个官能团的化合物反应来制备。 茂金属化合物是过渡金属化合物,其与主要配体如环戊二烯基和辅助配体配位。 化合物中的官能团选自羟基,烷基或芳基卤化镁,硫醇基,伯胺基,仲胺基,伯磷基,仲磷基等。 根据本发明的茂金属催化剂具有其中茂金属化合物的辅助配体与具有至少两个官能团的化合物的官能团键合的结构。 茂金属催化剂的结构可以随茂金属化合物和具有至少两个官能团的化合物的类型以及每种反应物的摩尔比而变化。 茂金属催化剂与用于烯烃聚合的助催化剂一起使用。 该助催化剂是一种有机金属化合物,或者是非配位路易斯酸和烷基铝的混合物,这在本领域中是众所周知的。
    • 109. 发明公开
    • TRANSITION METAL COMPLEX, PROCESS FOR PRODUCING THE SAME, AND USE
    • ÜBERGANGSMETALLKOMPLEX,VERFAHREN ZU DESSEN HERSTELLUNG,UND ANWENDUNG
    • EP2138503A1
    • 2009-12-30
    • EP08722361.6
    • 2008-03-18
    • Sumitomo Chemical Company, Limited
    • HANAOKA, HidenoriNABIKA, Masaaki
    • C07F17/00C08F4/6592C08F10/00
    • C07F17/00C08F10/00C08F210/16C08F2420/02C08F4/6592C08F210/14C08F2500/03C08F2500/10
    • A transition metal complex of the following formula (1):

      in which A represents an atom of Group 16 of the periodic table; B 1 represents an atom of Group 14 of the periodic table; M 1 represents a transition metal atom of Group 4 of the periodic table; Cp 1 represents a group having a cyclopentadiene anion backbone; R 1 , R 2 , R 3 , R 4 , R 5 and R 6 represent independently of one another a hydrogen atom, a halogen atom, a C 1-20 alkyl group optionally substituted with a halogen atom; R 7 , R 8 R 9 , R 10 , R 11 and R 12 represent independently of one another a hydrogen atom, a C 1-20 alkyl group optionally substituted with a halogen atom; and a 1,3-diene comprising R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and 4 carbon atoms coordinates on M 1 , and the 1,3-diene may be of either a cis or trans form, or a mixed form thereof, although the coordination form is not limited, and the double bonds may be delocalized. When this transition metal complex is used as a catalytic component, high molecular weight polyolefin is produced with high catalytic activity.
    • 下式(1)的过渡金属络合物:其中A表示周期表第16族的原子; B 1表示周期表第14族的原子; M 1表示周期表第4族的过渡金属原子; Cp 1表示具有环戊二烯阴离子主链的基团; R 1,R 2,R 3,R 4,R 5和R 6彼此独立地表示氢原子,卤素原子,任选被卤素原子取代的C 1-20烷基; R 7,R 8 R 9,R 10,R 11和R 12彼此独立地表示氢原子,任选被卤素原子取代的C 1-20烷基; 和包含在M 1上配位的R 7,R 8,R 9,R 10,R 11,R 12和4碳原子的1,3-二烯,1,3-二烯可以是顺式或反式 ,或其混合形式,尽管配位形式没有限制,双键可以是离域的。 当该过渡金属络合物用作催化组分时,产生具有高催化活性的高分子量聚烯烃。
    • 110. 发明公开
    • PROCESS FOR PREPARING DIALKYL OXIDE METALLOCENES OR DIARYL OXIDE METALLOCENES
    • 制备二烷基氧化合物或二芳基氧化物金属化合物的方法
    • EP2125846A2
    • 2009-12-02
    • EP08707809.3
    • 2008-02-27
    • Chemtura Organometallics GmbH
    • WENDT, Ralf-AlexanderUNSLEBER, Hans-JoachimLIEDTKE, Nicole
    • C07F17/00
    • C07F17/00
    • Process for preparing bridged, stereorigid, stereomerically pure dialkoxide metallocenes, diaryl oxide metallocenes and preferably diphenoxide metallocenes of the general formula Q(Cp)(Cp')M(OR3)2 in which Cp = a cyclopentadienyl, an indenyl or a fluorenyl radical, Cp' = one of the Cp groups, Q = a single- or multimembered bridge (R1-Z-R2)b between Cp and Cp', in which R1 and R2 may be the same or different and are each a hydrogen atom, a C1-C10-alkyl group, a C6-C10-aryl group, and Z is carbon, silicon or germanium where b = 1, 2 or 3, M = a transition metal of group 4, especially Zr and Hf and Ti, O = oxygen, R3 = a C1-C10-alkyl group, a C6-C10-aryl group, where the alkyl group may be branched or unbranched and may be substituted by aryl groups, and the aryl group may contain further substituents, which is characterized in that, in the first stage, a bridged, stereorigid metallocene dihalide in the form of a rac/meso mixture, having the general formula Q(Cp)(Cp')M(X)2 is reacted with an alkylating reagent of the general formula R4-M-(X)n in which R4 = a C1-C10-alkyl group, a C6-C10-aryl group, M = an alkali metal or alkaline earth metal, preferably Mg, Na or Li, X = halogen, especially Cl and Br, n = the oxidation number of M reduced by 1, and then the resulting reaction mixture or the intermediately isolated dialkylmetallocene is reacted with an alcohol, an aryl alcohol or a phenol of the general formula HO-R3 in which HO = a hydroxyl group, R3 = a C1-C10-alkyl group, a C6-C10-aryl group, where the alkyl group may be branched or unbranched and may be substituted by aryl groups, and the aryl group may contain further substituents.
    • (Cp)(Cp')M(OR3)2其中Cp =环戊二烯基,茚基或芴基的桥连,立体刚性,立体异构纯二烷氧基金属茂,二芳基氧化物金属茂和优选二苯氧基金属茂的方法, Cp'= Cp基团之一,Q = Cp和Cp'之间的单或多桥(R1-Z-R2)b,其中R1和R2可以相同或不同,并且各自是氢原子, C1-C10-烷基,C6-C10-芳基,并且Z为碳,硅或锗,其中b = 1,2或3,M =第4族过渡金属,特别是Zr和Hf和Ti,O = 氧,R3 = C1-C10-烷基,C6-C10-芳基,其中烷基可以是支链或无支链的并且可以被芳基取代,并且芳基可以含有其它取代基,其特征在于 在第一阶段中,具有通式Q(Cp)(Cp')M(X)2的外消旋/内消旋混合物形式的桥连立体刚性金属茂二卤化物与 通式R 4 -M-(X)n的烷基化试剂,其中R 4 = C 1 -C 10烷基,C 6 -C 10芳基,M =碱金属或碱土金属,优选Mg,Na或 Li,X =卤素,特别是Cl和Br,n = M的氧化值减少1,然后将所得反应混合物或中间分离的二烷基茂金属与通式HO的醇,芳基醇或酚反应 -R3,其中HO =羟基,R3 = C1-C10-烷基,C6-C10-芳基,其中烷基可以是支链或非支链的并且可以被芳基取代,芳基可以是 含有其他取代基。