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    • 100. 发明公开
    • A process for the provision of a plant extract containing condensed tannins, with astringent characteristics, modified by copolymerization, for use in tanning and retanning of skins, a plant extract with astringent characteristics, modified by copolymerization, and use of a modified plant extract containing tannins
    • 提供包含植物提取物和植物提取物缩合单宁的方法具有修饰的通过聚合涩特征
    • EP1437419A1
    • 2004-07-14
    • EP03253595.7
    • 2003-06-06
    • Tanac S.A.
    • LAMB, Luiz HenriqueDecusati, Otavio
    • C14C3/12C08H5/02
    • C14C3/12
    • The present invention refers to a process for obtaining a plant extract containing condensed tannins, with astringent characteristics, modified by copolymerization, to be used for tanning and retanning of skins; it also refers to the plant extract thus obtained; and it also refers to the use thereof for treating hides.
      The process according to the present invention comprises the following steps:

      (a) adding water to a reactor at a ratio between 2.0 and 5.8%, by weight, to the total desired weight of the load;
      (b) adding to the reactor an amount between 1.2 and 2.5%, by weight, of a copolymerization agent, selected from acrylic acid, metacrylic acid, mixtures of acrylic acid and metacrylic acid or esters thereof; all the while stirring the mixture;
      (c) adding thioglycolic acid at a ratio between 0.1 and 1.7%, by weight, while cooling the mixture, allowing the same to react whereupon there occurs the exothermal reaction and the temperature reaches 95° C, and after the said reaction the product obtained from the reaction being left to cool;
      (d) adjusting the pH to values in the range between 3.5 and 7.0, by adding an alkali to the mixture;
      (e) mixing a powdered extract of a plant with water at a ratio of about 0.5 to 2.0 kg per liter of water; or
         alternatively, mixing a solution of tannin in liquid form in a concentration of 25% to 60%;
      (f) raising the temperature of the mixture to a range between 67 and 98° C, to carry out the reaction, for a period of 2 to 7 hours, preferably for 5 hours;
      (g) adding the sodium bisulphite at a ratio of 0.5 to 4.0%, by weight, over the amount of tannin;
      (h) raising the temperature of the mixture, keeping the reaction system heated at a temperature between 45 and 127° C, the pressure being comprised between 0.2 and 7 kgf/cm 2 ; and
      (i) allowing a reaction time of about 4 hours.
    • 获得的植物提取物包括将2-5.8重量%的水。 添加1.2-2.5重量%的共聚合剂包含丙烯酸,甲基丙烯酸,和/或它们的酯。 添加0.1-1.7重量%的巯基乙酸。 混合每升水0.5-2千克植物的粉状提取物; 混合25-60%的单宁; 将温度升高到67至98℃; 加入0.5-4重量%的亚硫酸氢钠。 提高温度; 允许和4小时的反应时间。 获得含缩合单宁,具有收敛特性,通过共聚改性的植物提取物,在鞣革和皮的复鞣中使用,包括加入2-5.8重量%的水至反应器中。 添加1.2-2.5重量%的共聚剂,其包含丙烯酸,甲基丙烯酸,和/或它们的酯,同时搅拌该混合物。 添加0.1-1.7重量%的巯基乙酸,同时冷却该混合物使之反应,其中那里发生放热反应,并在温度达到95 [℃,并在反应后留在反应中得到的产品冷却。 将pH调节至3.5-7,通过向碱的混合物; 混合每升水0.5-2千克植物的粉状提取物; 或替代地,混合在液体形式25-60%单宁的溶液; 升高混合物的温度到67-98 [℃,进行反应,2-7小时,优选5小时; 加入0.5-4%(重量)亚硫酸氢钠,过单宁的量。 升高混合物的温度,保持在45加热到127 [度] C中的反应体系中,在0.2-7千克力/厘米的压力2> 允许和4小时的反应时间。