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    • 98. 发明授权
    • SEPARATOR FOR FUEL CELLS OF SOLID POLYELECTROLYTE TYPE AND PROCESSES OF THE PRODUCTION THEREOF
    • 用于固体聚电解质型燃料电池的分离器及其生产过程
    • EP0784352B1
    • 2001-02-14
    • EP96922230.6
    • 1996-07-04
    • NISSHINBO INDUSTRIES, INC.
    • SAITO, Kazuo, Nisshinbo Industries, Inc.HAGIWARA, Atsuchi, Nisshinbo Industries, Inc.TANNO, Fumio, Nisshinbo Industries, Inc.
    • H01M8/02
    • C04B35/536H01M8/0213H01M8/0226H01M2300/0082Y02P70/56
    • A separator for fuel cells of solid polyelectrolyte type which overcomes the disadvantages of the prior art, is lightweight, can be slotted easily, and exhibits high gas barrier properties; and processes for the production thereof. The separator is of the type to be sandwiched between gas diffusion electrodes of the fuel cell and characterized by being made of the carbonaceous composite material comprising expanded graphite particles which have a mean particle diameter of 5 to 12 mu m and at least 80 % of which have diameters falling within the range of 0.1 to 20 mu m and a thermoplastic or thermosetting resin or a sinter thereof, wherein the graphite particles are dispersed in the resin of sinter thereof, and having slots for feeding oxidant gas or fuel gas on one or both surfaces thereof. The separator can be produced by mixing a thermoplastic or thermosetting resin with the above-specified expanded graphite particles, pressure-molding the obtained mixture at ordinary temperature to 400 DEG C and forming slots of feeding oxidant gas or fuel gas on one or both surfaces of the resulting carbonaceous composite material, or by mixing a thermosetting resin with the above graphite particles, pressure-molding the obtained mixture at ordinary temperature to 400 DEG C, firing the resulting molding in a nonoxidizing atmosphere at 700 to 3000 DEG C to form a carbonaceous composite material, and forming slots for feeding oxidant gas or fuel gas on one or both surfaces of the material, or by mixing a thermosetting resin with the above graphite particles, pressure-molding the obtained mixture at ordinary temperature to 400 DEG C, forming slots for feeding oxidant gas or fuel gas on one or both surfaces of the obtained molding, and firing the resulting slotted molding in a nonoxidizing atmosphere at 700 to 3000 DEG C.
    • 克服了现有技术的缺点的用于固体聚电解质型燃料电池的隔板重量轻,可以容易地开槽,并显示出高气体阻隔性; 和它们的生产过程。 隔板是夹在燃料电池的气体扩散电极之间的类型,其特征在于由含有平均粒径为5至12μm的膨胀石墨颗粒的碳质复合材料制成,并且其至少80% 直径在0.1-20μm范围内的热塑性或热固性树脂或其烧结物,其中石墨颗粒分散在其烧结物的树脂中,并且具有用于将氧化剂气体或燃料气体供入一个或两个 表面。 隔板可以通过将热塑性树脂或热固性树脂与上述膨胀石墨颗粒混合,将所得混合物在常温下加压成型至400℃,并在其一个或两个表面上形成供应氧化剂气体或燃料气体的槽 或者将热固性树脂与上述石墨颗粒混合,将所得混合物在常温下加压成型至400℃,在700-3000℃的非氧化性气氛中煅烧所得到的成型体,形成含碳的复合材料 复合材料,以及在材料的一个或两个表面上供给氧化剂气体或燃料气体,或者通过将热固性树脂与上述石墨颗粒混合,在常温下将所得混合物加压成型至400℃,形成狭缝 用于将氧化剂气体或燃料气体供给到所获得的模制品的一个或两个表面上,并且将所得到的开槽模制品在非氧化自由基 在700-3000℃