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    • 7. 发明公开
    • Improved performance of high speed emulsions for color film
    • Verbesserte Leistung hochempfindlicher EmulsionenfürFarbfilme
    • EP1111449A2
    • 2001-06-27
    • EP00204391.7
    • 2000-12-08
    • EASTMAN TECHNOLOGY, INC.
    • Eikenberry, Jon Nathan, c/o Eastman Kodak CompanySouthby, David Thomas, c/o Eastman Kodak Company
    • G03C1/10G03C7/392G03C7/305G03C1/035
    • G03C1/10G03C1/035G03C1/12G03C7/3003G03C7/3022G03C7/30547G03C7/39208G03C2001/0055G03C2001/03541G03C2001/03547G03C2001/03558G03C2001/03594G03C2007/325G03C2200/11G03C2200/24Y10S430/156
    • A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises

      a) an emulsion with 3D, core/shell grains of at least 0.40 µm average diameter having a high iodide content in the core of the grain with a shell containing a lesser amount of iodide,
      b) a one-equivalent image-dye forming coupler, and
      c) a fragmentable electron donating compound of the formula: X-Y' or a compound which contains a moiety of the formula -X-Y';
      wherein
         X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, β - , is covalently linked directly or indirectly to X, and wherein:

      1) X-Y' has an oxidation potential between 0 and about 1.4 V; and
      2) the oxidized form of X-Y' undergoes a bond cleavage reaction to give the radical X • and the leaving fragment Y; and, optionally,
      3) the radical X • has an oxidation potential ≤-0.7V (that is, equal to or more negative than about -0.7V).
    • 照相材料包括载体,其载有青色染料影像形成单元,其包括至少一种与其相关联的至少一种形成青色染料的成色剂的感红卤化银乳剂层,品红色染料影像形成单元包括至少一种绿色染料成像单元, 感光卤化银乳剂层,其具有与其相关的至少一种品红色染料形成成色剂,黄色染料成像单元,其包含至少一种感蓝卤化银乳剂层,其具有至少一种形成黄色染料的成色剂,其中至少 所述乳剂层中的一个包括a)具有三维,具有至少0.40μm平均直径的芯/壳颗粒的乳液,其颗粒核中具有高碘含量,壳含有较少量的碘化物,b)一个 - 等同的图像 - 染料形成成色剂,和c)下式的可裂解供电子化合物:XY'或含有式-X-Y'部分的化合物; 其中X是电子给体部分,Y'是离开质子H或离去基团Y,条件是如果Y'是质子,则基团β - 直接或间接地共价连接到X和 其中:1)XY'具有介于0和约1.4V之间的氧化电位; 和2)X-Y'的氧化形式经历键断裂反应,得到基团X 1和离去的片段Y; 和任选地,3)基团X 1具有≤-0.7V的氧化电位(即,等于或大于约-0.7V的负值)。