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    • 2. 发明授权
    • Method for analyzing boron-containing alkaline pulping liquors
    • 分析含硼碱性制浆液的方法
    • US06635147B1
    • 2003-10-21
    • US09571297
    • 2000-05-14
    • Wu-hwa Wesley Hsu
    • Wu-hwa Wesley Hsu
    • D21C302
    • G01N33/343D21C7/12G01N31/164
    • Chemical species (e.g., metaborate, carbonate, hydroxide and sulfide) in a boron-containing alkaline wood pulping liquor sample are determined quantitatively by (i) subjecting a first aliquot portion of the sample to a primary acid titration analysis to derive multiple equivalence points at different respective pH values; (ii) subjecting a second aliquot portion of the sample to an analysis to determine the quantitative presence of boron or sulfide ions therein, and then (iii) determining the quantitative presence in the sample of at least one of the chemical species. Wood pulping parameters may thus be determined on the basis of the quantitative presence of the chemical species to assist in process and/or quality control of the wood pulping operation. For example, the sample may be analyzed for boron content using calorimeter or atomic spectroscopy and/or analyzed for sulfide ion content using a secondary silver sulfide precipitation titration analysis, each of which may be conducted substantially simultaneously with the primary acid titration analysis.
    • 通过以下步骤定量测定含硼碱性木材制浆液样品中的化学物质(例如偏硼酸盐,碳酸盐,氢氧化物和硫化物):(i)使样品的第一等分试样部分进行初级酸滴定分析,以得出多个等效点 不同的各自的pH值; (ii)使样品的第二等分试样部分进行分析以确定其中的硼或硫化物离子的定量存在,然后(iii)确定样品中至少一种化学物质的定量存在。 因此可以基于化学物质的定量存在来确定木材制浆参数,以辅助木材制浆操作的过程和/或质量控制。 例如,可以使用量热计或原子光谱分析样品的硼含量和/或使用二次硫化银沉淀滴定分析来分析硫化物离子含量,其中每一个可以与初级酸滴定分析基本上同时进行。
    • 4. 发明授权
    • Method of digesting wood with an alkaline liquor by adding an acidic agent to precipitate dissociated lignin
    • 通过添加酸性剂来沉淀离解的木质素,用碱性液体消化木材的方法
    • US06464827B1
    • 2002-10-15
    • US09722435
    • 2000-11-28
    • Jorge Luiz Colodette
    • Jorge Luiz Colodette
    • D21C302
    • D21C3/022D21C3/04
    • A method for producing pulp, comprising digesting lignocellulosic wood, containing one or more xylan derivatives selected from the group consisting of xylan bound with lignin, xylan bound with hexenuronic acid, and mixtures thereof, with an aqueous alkaline pulping solution containing sulfide and having an initial free hydroxyl ion concentration of at least 1 mole per liter, under conditions whereunder xylan is dissociated from said one or more xylan derivatives and the pH of the solution remains above 12.5; and then while the pH of said solution is above 12.5, adding a sufficient amount of an acidic agent to said pulping solution to precipitate dissociated xylan from said pulping solution while minimizing precipitation of lignin from said pulping solution. Carbon dioxide is a preferred acidic agent.
    • 一种用于生产纸浆的方法,包括消化木质纤维素木材,其含有一种或多种选自木质素结合的木聚糖,与己烯壬醛结合的木聚糖及其混合物的木聚糖衍生物与含硫化物的碱性制浆溶液并具有初始 游离羟基离子浓度至少为1摩尔/升,在木聚糖从所述一种或多种木聚糖衍生物解离的条件下,溶液的pH保持在12.5以上; 然后当所述溶液的pH高于12.5时,向所述制浆溶液中加入足够量的酸性试剂以从所述制浆液中沉淀离解的木聚糖,同时使来自所述制浆溶液的木质素沉淀最小化。 二氧化碳是优选的酸性剂。