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    • 10. 发明授权
    • Ligand and complex for catalytically bleaching a substrate
    • 用于催化漂白底物的配体和配合物
    • US06432900B1
    • 2002-08-13
    • US09650148
    • 2000-08-29
    • Adrianus Cornelis AppelRonald HageDavid TetardRobin Stefan Twisker
    • Adrianus Cornelis AppelRonald HageDavid TetardRobin Stefan Twisker
    • C11D726
    • C07D401/14C07D213/38C07D213/55C11D3/28C11D3/3932
    • The invention relates to ligands or complexes useful as catalysts for catalytically bleaching substrates with atmospheric oxygen, and as catalysts in the of treatment of textiles such as laundry fabrics whereby bleaching by atmospheric oxygen is catalysed after the treatment. The ligand is of the general formula: wherein R1, R2, and R3 independently represent a group selected from hydrogen, hydroxyl, halogen, —NH—C(NH)NH2, —R and —OR, wherein R=alkyl, alkenyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl or a carbonyl derivative group, R being optionally substituted by one or more functional groups, and provided that two of R1, R2 and R3 are coordinating groups and one of R1, R2 and R3 is a non-coordinating group; Q independently represents a group selected from C2-3-alkylene optionally substituted by H, benzyl or C1-8-alkyl; and Q1, Q2 and Q3 independently represent specified linking groups.
    • 本发明涉及可用作催化漂洗底物与大气氧的催化剂的配体或配合物,以及作为处理纺织品如洗涤织物的催化剂,由此在处理后催化大气中的漂白。 配位体具有以下通式:其中R1,R2和R3独立地表示选自氢,羟基,卤素,-NH-C(NH)NH2,-R和-OR的基团,其中R =烷基,烯基,环烷基, 杂环烷基,芳基,杂芳基或羰基衍生物基团,R任选被一个或多个官能团取代,并且条件是R 1,R 2和R 3中的两个为配位基团,R 1,R 2和R 3中的一个为非配位基团。 Q独立地表示选自任选被H,苄基或C 1-8 - 烷基取代的C 2-3 - 亚烷基的基团; 而Q1,Q2和Q3独立地表示指定的连接基团。