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    • 3. 发明申请
    • COLOR STABLE ROSIN ESTERS AND PREPARATION THEREOF
    • 颜色稳定的ROSIN ESTERS及其制备
    • WO1998026020A1
    • 1998-06-18
    • PCT/US1997022828
    • 1997-12-11
    • UNION CAMP CORPORATION
    • UNION CAMP CORPORATIONWHALEN, David, Mayo
    • C09F01/00
    • C09F1/04
    • Rosin esters that are both light colored and color stable are produced by reacting polyhydric alcohol with an equivalent excess of rosin, in the presence of calcium bis(monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate. As used herein, "reacting" means to contact the reactants under conditions of time, temperature, pressure, etc., effective to achieve the desired reaction, e.g., an esterification reaction. When phosphinic acid is added to the reaction mixture, light colored and color stable rosin esters are produced regardless of whether the rosin or polyol are in equivalent excess, although preferably the rosin is in equivalent excess. It is preferred to include a phenol sulphide compound, such as Vultac3 2, with the calcium bis(monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphanate, and to add the phosphinic acid incrementally after the acid number of the rosin and polyhydric alcohol reaction mixture has dropped to about 100. Excess rosin is preferably stripped from the product mixture at about 275 DEG C.
    • 在双(1-(3,5-二 - 叔丁基-4-羟基苄基)膦酸二乙酯存在下,通过多元醇与等量过量的松香反应,生成浅色和稳定的松香酯。 在这里,“反应”是指在时间,温度,压力等条件下接触反应物,以有效地实现所需的反应,例如酯化反应,当将次膦酸加入到反应混合物中时,浅色和稳定 无论松香或多元醇是否相当于过量产生松香酯,尽管优选松香相当于过量,但优选包括酚硫化物化合物如Vultac3 2与双((乙基) - 二叔丁基-4-羟基苄基)磷酸酯,并且在酸值的松香和多元醇反应混合物已经降至约100之后,增量地加入次膦酸。优选从产物中剥离松香 t混合物在约275℃