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    • 1. 发明授权
    • Rosin-fatty acid vinylic emulsion compositions
    • 松香脂肪酸乙烯基乳液组合物
    • US06429247B1
    • 2002-08-06
    • US09738335
    • 2000-12-15
    • Rajnikant ShahWarunee S. SissonThomas M. Sisson
    • Rajnikant ShahWarunee S. SissonThomas M. Sisson
    • C08L9304
    • C09D151/08C08F257/02C08F285/00C08F289/00C09D11/10
    • A rosin fatty acid vinylic emulsion composition produced by (A) polymerizing a mixture of vinylic monomers in the presence of a fatty acid rosin mixture comprising a mixture of fatty acids and rosin, at temperature in the range of about 135° C. to about 175° C., to produce a rosin-fatty acid vinylic polymer having a weight average molecular weight in the range of 4,000 to about 12,000; and (B) subsequently emulsion polymerizing another mixture of vinylic monomers in the presence of the rosin-fatty acid vinylic polymer of step A at temperature in the range of about 20° C. to about 100° C., to produce a rosin-fatty acid vinylic emulsion composition with polymers having a weight average molecular weight in the range of about 40,000 to about 200,000.
    • 一种松香脂肪酸乙烯基乳液组合物,其通过(A)在包含脂肪酸和松香的混合物的脂肪酸松香混合物存在下聚合乙烯基单体的混合物,温度范围为约135℃至约175℃ 以产生重均分子量在4,000至约12,000范围内的松香脂肪酸乙烯基聚合物; 和(B)随后在步骤A的松香脂肪酸乙烯基聚合物的存在下在约20℃至约100℃的温度范围内将乙烯基单体的另一混合物乳化聚合,以产生松香脂肪 酸性乙烯基乳液组合物,其重均分子量在约40,000至约200,000范围内。
    • 2. 发明授权
    • Polyolefin based hot melt adhesive composition
    • 聚烯烃基热熔胶组合物
    • US06486246B1
    • 2002-11-26
    • US09402381
    • 1999-10-04
    • Jean Marc Vion
    • Jean Marc Vion
    • C08L9304
    • C09J123/10C08L2207/02C08L2666/02C08L2666/04C09J123/16
    • A hot melt adhesive polyolefin composition having a viscosity from 7,000 to less than 500,000 mPa·sec, at 190° C. including (by weight): I) 5-85% of a crystalline propylene polymer selected from a propylene homopolymer and a copolymer of propylene and ethylene or a C4-C10 &agr;-olefin or blends thereof, having an isotactic index from 80 to 98%; II) 5-85% of an heterophasic polyolefin composition including: (i) a crystalline propylene polymer and (ii) and an amorphous copolymer of ethylene and propylene or a C4-C10 &agr;-olefin or blends thereof, containing less than 40% of ethylene; III) 10-75% of a material selected from aliphatic hydrocarbon resins, terpene/phenolic resin, polyterpenes, rosin, rosin esters and blends thereof; and optionally IV) a mineral paraffinic or naphthalenic oil, an amorphous poly(&agr;-olefin) having low molecular weight or a mixture thereof.
    • 一种熔融粘合性聚烯烃组合物,其在190℃下的粘度为7000至小于500,000mPa.sec,包括(重量):I)5-85%的结晶丙烯聚合物,其选自丙烯均聚物和共聚物 丙烯和乙烯或C 4 -C 10α-烯烃或其共混物,具有80至98%的全同立构指数; II)5-85%的异相聚烯烃组合物,其包括:(i)结晶丙烯聚合物和(ii)和乙烯和丙烯或C 4 -C 10α-烯烃或其共混物的无定形共聚物,其含量小于40% 乙烯; III)10-75%选自脂族烃树脂,萜烯/酚醛树脂,多萜烯,松香,松香酯及其共混物的材料; 和任选的IV)无机石蜡或萘油,具有低分子量的无定形聚(α-烯烃)或其混合物。
    • 6. 发明授权
    • Flooring adhesives
    • 地板胶
    • US06169132A
    • 2001-01-02
    • US09325044
    • 1999-06-03
    • Peter FickeisenEckehardt Wistuba
    • Peter FickeisenEckehardt Wistuba
    • C08L9304
    • C09J193/00C08L25/00C08L27/00C08L33/00C08L2666/04C08L2666/08Y10S524/915
    • Aqueous composition comprising from 10 to 35% by weight of a water-dispersed polymer A) having a glass transition temperature Tg of below −10° C. from 5 to 22% by weight of a resin B) which is liquid at 23° C. and 1 bar, has a glass transition temperature of below −10° C. and in which abietic acid is soluble at 23° C. and 1 bar such that it is possible to obtain solutions of resin B and abietic acid having a weight content of up to 50% by weight of abietic acid from 5 to 22% by weight of a resin C) which is based on abietic acid or on modified abietic acid and has a glass transition temperature of from 0 to 90° C. and from 21 to 80% by weight of a filler D), the percentages by weight being based on the sum of the constituents of the aqueous composition with the exception of water.
    • 水性组合物,其包含10至35重量%的玻璃化转变温度Tg低于-10℃的水分散聚合物A),其重量比为5至22重量%的在23℃下为液体的树脂B) 和1巴,玻璃化转变温度低于-10℃,其中松香酸在23℃和1巴下溶解,使得可以获得重量含量为的树脂B和松香酸​​的溶液 至多50重量%的松香酸,其为5至22重量%的基于松香酸或改性松香酸的树脂C),并且具有0至90℃的玻璃化转变温度和21至80% 的填料D),重量百分比是基于除了水以外的水性组合物的组分的总和。
    • 9. 发明授权
    • Emulsion for pressure-sensitive adhesive
    • 压敏胶乳液
    • US06518342B1
    • 2003-02-11
    • US09429108
    • 1999-10-28
    • Yasumasa TanakaNaoki TsunemineOsamu Konosu
    • Yasumasa TanakaNaoki TsunemineOsamu Konosu
    • C08L9304
    • C09J201/06C08L2666/26
    • The present invention provides an emulsion for pressure-sensitive adhesive, and a pressure-sensitive adhesive product which exhibits high water resistance and high adhesion properties. The emulsion for pressure-sensitive adhesive includes as essential components: a pressure-sensitive adhesive polymer (A) having a glass-transition temperature of −80 to −20° C., a weight-average molecular weight of 150,000 or larger, and a carboxylic acid value of 30 or smaller; a rosin derivative (B) having a weight-average molecular weight of 100,000 or smaller, and containing at least part of the carboxyl groups being alkali salt with a carboxylic acid value of 190 or larger before alkalization; and a compound (C) having a weight-average molecular weight of 100,000 or smaller, and having no carboxyl group but having at least one functional group reactive with a carboxyl group in its molecule. The amount of the rosin derivative (B) is 2 to 30 mass percent when the total amount of the pressure-sensitive adhesive polymer (A) and the rosin derivative (B) in the emulsion is defined as 100 mass percent, and the compound (C) is contained in the emulsion so that the functional group of the compound (C) is in an amount of 0.05 to 10 equivalent with respect to one equivalent of the carboxyl groups of the rosin derivative (B) before alkalization.
    • 本发明提供了一种用于压敏粘合剂的乳液和显示出高耐水性和高附着性的压敏粘合剂产品。 用于压敏粘合剂的乳液包括作为必要组分的一种:玻璃化转变温度为-80至-20℃,重均分子量为15万或更大的压敏粘合剂聚合物(A)和 羧酸值为30以下; 松香衍生物(B),其重均分子量为100,000以下,并且在碱化之前,至少部分羧基为碱金属盐,羧酸值为190以上的碱金属盐; 和重均分子量为100,000以下,不具有羧基但具有至少一个与其分子中的羧基反应的官能团的化合物(C)。 当乳液中的粘合剂聚合物(A)和松香衍生物(B)的总量定为100质量%时,松香衍生物(B)的量为2〜30质量%,化合物 C)包含在乳液中,使得化合物(C)的官能团相对于碱化前的松香衍生物(B)的一当量的羧基为0.05〜10当量。