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    • 3. 发明授权
    • Flameproof styrene containing graft resin compositions substantially free of phenolic resins and containing styrene/acrylonitrile resin compatabilizer
    • 含防火苯乙烯的接枝树脂组合物基本上不含酚醛树脂,并含有苯乙烯/丙烯腈树脂复合材料
    • US06716900B2
    • 2004-04-06
    • US10052205
    • 2002-01-16
    • Bok-Nam JangSe-Jong KimYoung-Kil ChangGyu-Cheol Lee
    • Bok-Nam JangSe-Jong KimYoung-Kil ChangGyu-Cheol Lee
    • C08K5521
    • C08L55/02C08F279/02C08K5/521C08K5/523C08L51/04C08L71/123C08L81/02C08L71/12C08L2666/02C08L2666/14C08L2666/24C08L85/00
    • A flameproof thermoplastic resin composition is substantially free of phenolic resin, red phosphorous and silicone resin and comprises (A) about 40-95 parts by weight of a rubber modified styrene-containing resin comprising (a1) about 20-95% by weight of a styrene-containing graft copolymer resin containing about 19-50% by weight of acrylonitrile in the copolymer excluding rubber and (a2) about 5-80% by weight of a styrene-containing copolymer containing about 19-50% by weight of acrylonitrile; (B) about 5-60 parts by weight of a polyphenylene ether resin; (C) about 2-40 parts by weight of a compatabilizer comprising (c1) a styrene-containing copolymer containing about 5-18% by weight of acrylonitrile in the copolymer per 100 parts by weight of the sum of (A) and (B) or (c2) a styrene-containing graft copolymer having up to about 60% by weight of rubber wherein the compatabilizer contains about 5-18% by weight of acrylonitrile in the copolymer excluding rubber, per 100 parts by weight of the sum of (A) and (B); and (D) about 5-30 parts by weight of an aromatic phosphoric acid ester per 100 parts by weight of the sum of (A) and (B). The physical properties and flame retardance of the resin compositions according to the present invention are adversely affected by the presence of 3% or more by weight of polycarbonate based on the total weight of the composition.
    • 防火热塑性树脂组合物基本上不含酚醛树脂,红磷和有机硅树脂,并且包含(A)约40-95重量份的含橡胶改性苯乙烯的树脂,其包含(a1)约20-95重量%的 在包含橡胶的共聚物中含有约19-50重量%丙烯腈的含苯乙烯接枝共聚物树脂和(a2)约5-80重量%含有约19-50重量%丙烯腈的含苯乙烯共聚物; (B)约5-60重量份聚苯醚树脂; (C)约2-40重量份的组合物,其包含(c1)含有共聚物中约5-18重量%丙烯腈的含苯乙烯共聚物,每100重量份(A)和(B )或(c2)含有至多约60重量%的橡胶的含苯乙烯的接枝共聚物,其中所述组合物在除橡胶之外的共聚物中含有约5-18重量%的丙烯腈,每100重量份的( A)和(B); 和(D)每100重量份(A)和(B)之和约5-30重量份的芳族磷酸酯。 根据本发明的树脂组合物的物理性能和阻燃性受到基于组合物总重量的3重量%或更多重量的聚碳酸酯的不利影响。
    • 8. 发明授权
    • Polyphenylene ether resin composition
    • 聚苯醚树脂组合物
    • US06469077B1
    • 2002-10-22
    • US09416892
    • 1999-10-13
    • Satoru MoritomiYasuo Tatsumi
    • Satoru MoritomiYasuo Tatsumi
    • C08K5521
    • C08K5/523C08L71/12
    • There is provided a polyphenylene ether resin composition, comprising: a component (A) containing a polyphenylene ether resin; a component (B) containing a phosphate compound represented by the following formula (I); and a component (C) containing a condensed phosphate compound represented by the following formula (II), wherein R1, R2 and R3 are independently of one another an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms or a hydroxyl group; R4, R5, R6 and R7 are independently of one another a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 6 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms or a hydroxyl group, provided that a case of R4=R5=R6=R=H is excluded; n is an integer of not less than 1; Z is an organic group having 1 to 10 carbon atoms; and q is an integer of from 0 to 4; and wherein said composition contains a content of phosphorus therein of from about 1.8 to 5% by weight based on the total weight of the polyphenylene ether resin composition.
    • 提供聚苯醚树脂组合物,其包含:含有聚苯醚树脂的组分(A);含有下式(I)表示的磷酸酯化合物的组分(B); 和含有下式(II)表示的缩合磷酸酯化合物的组分(C),其中R 1,R 2和R 3彼此独立地为具有1至20个碳原子的烷基,具有3至20个碳原子的环烷基, 碳原子数6〜20的芳基,碳原子数1〜20的烷氧基或羟基; R4,R5,R6和R7彼此独立地为氢原子,碳原子数1〜20的烷基,碳原子数为6〜20的环烷基,碳原子数为6〜20的芳基,烷氧基为 1〜20个碳原子或羟基,条件是R4 = R5 = R6 = R = H的情况除外; n为不小于1的整数; Z为碳原子数1〜10的有机基团。 q为0〜4的整数, 并且其中所述组合物含有基于聚苯醚树脂组合物总重量的约1.8至5重量%的磷含量。