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    • 5. 发明专利
    • POLYAMIDES
    • GB1374767A
    • 1974-11-20
    • GB347371
    • 1971-01-29
    • ICI LTD
    • C08G69/00C08G69/36C09J177/00D06M17/00D06M17/08C08G20/02B32B5/28C08G41/02C08G51/02C08G51/22C08G53/02
    • 1374767 Laminates IMPERIAL CHEMICAL INDUSTRIES Ltd 17 Jan 1972 [29 Jan 1971] 3473/71 Heading B5N [Also in Division C3] A fabric is coated with a copolyamide and contacted with a second fabric surface, and heat is applied to soften the copolyamide, thus bonding the fabrics. The copolyamide contains, randomly distributed, by weight: 10-80% -[-CO (CH 2 ) 5 NH-]-; 10-80% -[-NH(CH 2 ) 6 - NHCO(CH 2 ) x CO-]- or -[-NH(CH 2 ) 6 NH-COAr-CO-]-, where x is 2, 3, 5, 6, 7, 9 or 10, and Ar is a monocyclic aromatic nucleus; 1-70% -[-CO(CH 2 ) 11 NH-]-, and 0-10% other amide monomer units. The "other units" may be derived from salts of hexamethylene diamine with adipic or sebacic acids, or salts of ethylenediamine or tri-, tetra-, penta-, deca-, or dodecamethylenediamine with HOOC(CH 2 ) x COOH or with a monocyclic aromatic dicarboxylic acid. The polymer may contain: glass fibres, mica, carbon, or chalk, pigments, or plasticizers or flow improvers, e.g. stearates or silicates of Mg, Al, Ca, or Zn, or tallow amines, and may be made into films, fibres, filaments or shaped articles. Or the copolyamide may be a powder having number-average particle-size
    • 6. 发明专利
    • FOAM STABILIZERS
    • GB1359024A
    • 1974-07-03
    • GB5412071
    • 1971-11-22
    • ICI LTD
    • C08G77/06C08J9/00C08G31/09C08G53/08C08G47/10C08G51/22
    • 1359024 Polysiloxane foam stabilizers IMPERIAL CHEMICAL INDUSTRIES Ltd 9 Nov 1972 [22 Nov 1971] 54120/71 Headings C3T and C3C A foam stabilizer suitable for use in the production of foams from plastisols comprises at least one copolymer consisting of (A) R 3 SiO 0À5 , (B) RSiO 1À5 and (C) SiO 2 units wherein R is an alkyl, monocyclic aryl hydrocarbon, alkaryl or aralkyl radical the ratio of A to B + C units being 0À6 : 1 to 1À5 : 1 and of B : C units 0À05 : 1 to 1 : 1. The copolymers can be prepared by cohydrolysing a mixture of R 3 SiX, RSiX 3 and SiX 4 where X is a halogen, or by the addition of a blend of R 3 SiX and RSiX 3 in a solvent to a stabilized silica hydrosol, or by the addition of a solution of R 3 SiX to a stabilized hydrosol of silica and methylsiliconic acid. In the production of a solid thermoplastic foam, a plastisol or a thermoplastic resin, preferably a vinyl chloride polymer, having at least one of the above polysiloxane copolymers dispersed therein is foamed with a gas or vapour introduced mechanically, and the foam so produced is heated to cause gelation and fusion thereof and then cooled. Preferred resins are vinyl chloride/ vinyl acetate copolymers containing up to 20% wt. polymerized vinyl acetate. In the examples various polysiloxane copolymers in which R is methyl are prepared by the above methods and are used as stabilizers in the preparation of foams from plastisols comprising (1) vinyl chloride polymer and as plasticizer dialkyl phthalate, butyl benzyl phthalate and mixtures thereof, and (2) vinyl chloride/vinyl acetate copolymer and as plasticizer a mixture of dialkyl phthalate, butylbenzyl phthalate and chlorinated paraffin in varying proportions, and the foam densities are determined.
    • 7. 发明专利
    • PROCESS FOR PREPARING A BLENDED SOLUTION OF DIFFERENT TYPES OF HIGH MOLECULAR COMPOUNDS
    • GB1339139A
    • 1973-11-28
    • GB6151170
    • 1970-12-29
    • AJINOMOTO KK
    • C08G69/10C08L21/00C08L77/00C08G41/04C08G20/08C08G51/22B32B27/06
    • 1339139 Poly(γ-alkylglutamate-N-carboxy anhydride) compositions AJINOMOTO CO Inc 29 Dec 1970 [30 Dec 1969] 61511/70 Headings C3P and C3R [Also in Divisions B2 and B5] An optically-active γ-alkyl glutamate-N- carboxy anhydride (A) is polymerized in a solution of an elastic high-molecular compound (E) to yield a clear homogeneous blended solution. In (A), the alkyl group may be a C 1-4 alkyl; mixtures of different anhydrides (A) may be used. (E) may have glass transition or softening point 200%. (E) may be polyurethane, natural rubber, synthetic rubber, e.g. polychloroprene, isoprene/isobutylene copolymer, acrylonitrile/ butadiene copolymer, butyl rubber, polybutene, chlorosulphonated polyethylene, butadiene / styrene copolymer, polybutadiene, polyisoprene, chlorinated polyethylene, ethylene/propylene copolymer, polyalkyl acrylate, intramolecularly plasticized polyester, organopolysiloxanes, polyethers, or polyamides. (A)/(E) weight ratio may be from 1 to 9. The solvent may be a chlorinated aliphatic hydrocarbon, an aromatic hydrocarbon, an ester, a ketone, dimethyl formamide, N-methylpyrrolidone, and/or dimethyl sulphoxide. Also present may be a non-solvent for (A), e.g. dimethyl ether, acetonitrile, tetrahydrofuran, chlorinated aliphatic hydrocarbons, or ligroin. As polymerization initiator may be used an amine, or NaOH or KOH. The polymerization temperature may be -20‹ to + 30‹ C. Also present may be cross-linking agents or accelerators for (E); further solvent; fillers, e.g. CaCO 3 , TiO 2 , and C black; plasticizers, e.g. dioctyl phthalate, tricresyl phosphate, or chlorinated diphenyl, triphenyl, naphthalene, or paraffin; surfactants; colourants, dyes; blowing agents; non-elastic polymers, e.g. polymers or copolymers of vinyl chloride, styrene, methacrylate, polycarbonate. Use.-Films; fibres; in artificial leather; coating glass, fabrics, woven, knitted or unwoven textiles, paper, wood, natural or artificial leather, book-cloth, release paper; or metal plates; as fibre-treating agents or paints.
    • 8. 发明专利
    • ADHESIVE SEMI-CURED SEALING STRIP FOR AUTOMOBILE WINDSHIELD
    • GB1332701A
    • 1973-10-03
    • GB5425170
    • 1970-11-13
    • THIOKOL CHEMICAL CORP
    • C08L81/00B60J10/02C03C27/04C08K13/02C08L7/00C08L21/00C08L33/00C08L33/02C08L67/00C08L77/00C08L81/04C09J159/00C09K3/10C08G43/00C08G51/08C08G51/10C08G51/16C08G51/22E06B3/56
    • 1332701 Polythiol-terminated polymer compositions THIOKOL CHEMICAL CORP 13 Nov 1970 [17 March 1970] 54251/70 Heading C3R [Also in Division El] A composition curable on exposure to moisture comprises the following ingredients in parts by weight: liquid polythiol terminated polymer(s) or polymer blend: 100; extender and/or plasticizer: 0-300; alkaline earth metal carbonates: 0-300; fibrous filler: 2-65; carbon black: 2-75; curing agent for semicuring any uncured polymer: 0-7; moistureactivatable curing agent for final curing of polymer(s): 2-20; adhesive additive: 0-20; desiccant: 1-25À5; U/V stabilizer: 0-5, the polymer if uncured being curable to the semicured product, or being already a semi-cured or blended product, having a viscosity at 25‹ C. of at least 6000 poises and a M.wt. of at least 13,000. Suitable polymers include polythiopolymercaptans of formula HS(RSS) n RSH where R is a hydrocarbon, oxa- or thiahydrocarbon radical, and n = 2-70, or -SSH terminated polysulphides, or -SH terminated polyethers, e.g. polypropylene glycol, or hydrocarbon polymers, polyurethanes or polyalkylene sulphides. The polymer is preferably the polysulphide LP31 or LP32 of the formula where n = 42 and 23 respectively and must be partially cured e.g. with an organic peroxide to a polymer of the above viscosity or it may be blended with a high M.wt. organic ST polysulphide rubber of the formula where n = 500, R is a random mixture 98% of which has the structure -CH 2 CH 2 OCH 2 OCH 2 CH 2 - and 2% the structure which is prepared from bis(2-chloroethyl) formal and sodium polysulphide with trichloropropane as a branch inducing agent. Included with or substituted for the ST-rubber may be chlorinated rubbers, acrylic resins, polyisobutylene, reclaimed natural and synthetic rubbers, epoxy resins, chlorinated biphenyls, coumarone-indene resins and polyamides. Curing agents include inorganic and organic peroxides, chromate salts, manganates, plumbates, permanganates and molybdates. Plasticizers-extenders which may also serve as desiccating and hygroscopic accelerating agents include chlorinated hydrocarbons e.g. biphenyls, phthalates, polyalkylene glycol benzoates. Fibrous fillers include synthetic fibres, nylon, rayon, polyester, asbestos, glass fibres. Non-fibrous fillers include clays, slate flour, asbestine, Al 2 O 3 , TiO 2 , ZnS, SiO 2 , iron oxide. Adhesive additives include polyurethane resins, chlorinated terphenyls, phenolic resins, epoxy resins, organosilicon compounds, acrylic resins, polyester resins, polyamides, liquid polysulphide polymers. U.V. light stabilizers include organic silicon-containing compounds substituted with at least one alkoxy, acyloxy, vinyl or amino group, benzophenones, benzotriazoles, aryl esters and substituted acrylonitriles. Other additives include pigments, fatty acid cure inhibitors such as stearic acid, thixotropic agents such as calcium silicate and anti-oxidants such as butylated hydroxy toluene. Uses.-For making a moisture curable sealing strip for adhesively fastening and sealing a windscreen to an automobile body.