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    • 4. 发明申请
    • Process for producing aromatic polyethers with high molecular weights
    • 制备高分子量芳香族聚醚的方法
    • US20030114639A1
    • 2003-06-19
    • US10237887
    • 2002-09-10
    • SUMITOMO CHEMICAL COMPANY, LIMITED
    • Kazushige OkamotoKunihisa Satoh
    • C08G065/34
    • C08G75/23
    • A process for producing an aromatic polyether having a high molecular weight, small dispersion of the molecular weight, excellent in the heat resistance as well as the impact resistance and represented by the formula (1): 1 wherein each of x1 and x2 independently represents a halogen, and n represents an integer of 1 or above is provided, which comprises polymerizing 4,4null-biphenol with a 4,4null-dihalogenodiphenyl sulfone represented by the formula (2): 2 wherein x1 and x2 have the same meaning as above, in an amount exceeding 1 time by mole and not exceeding 1.05 time by mole based on said 4,4null-biphenol in diphenyl sulfone and in the presence of an alkali metal carbonate and/or an alkali metal bicarbonate at a temperature which is not lower than 240null C. and not higher than 270null C.
    • 一种具有高分子量,分子量分散小,耐热性以及耐冲击性优异并由式(1)表示的芳族聚醚的方法:其中x1和x2各自独立地表示卤素 ,并且n表示1以上的整数,其包括使4,4'-联苯酚与由式(2)表示的4,4'-二卤代二苯基砜聚合:其中x1和x2具有与上述相同的含义, 其量相对于二苯砜中的4,4'-联苯并且在碱金属碳酸盐和/或碱金属碳酸氢盐存在下,温度不低于1倍摩尔,不超过1.05倍摩尔 超过240℃,不高于270℃
    • 5. 发明申请
    • Method for preparing polyether polyol copolymer
    • 聚醚多元醇共聚物的制备方法
    • US20030069390A1
    • 2003-04-10
    • US10223564
    • 2002-08-19
    • Hodogaya Chemical Co., Ltd.
    • Hiroshi SatohHideyuki Ishii
    • C08G065/34
    • C08G65/16C08G18/4854C08G18/4858C08G65/20C08G65/2609C08G65/2666
    • A method for preparing a polyether polyol copolymer includes the step of copolymerizing (1) a cyclic ether represented by the following formula (I): 1 wherein x is an integer ranging from 2 to 10; (2) a diol represented by the following formula (II): HOnull(CH2)xnullOHnullnull(II)wherein x is the same as that specified above; and (3) other polyols, in the presence of an acid catalyst. The method permits the arbitrary modification of the content of the O(CH2)x units present in the main chain of a polyether polyol copolymer so that the copolymer may have an appropriate crystallinity suitable for use as an elastomer by controlling the ratio of the diol represented by Formula (II) used in the copolymerization and simultaneously permits the change of the molecular weight of the resulting polyether polyol copolymer.
    • 制备聚醚多元醇共聚物的方法包括:(1)由下式(I)表示的环状醚共聚合的步骤:其中x为2至10的整数; (2)由下式(II)表示的二醇:HO-(CH 2)x -OH(II)其中x与上述相同; 和(3)其它多元醇,在酸催化剂存在下。 该方法允许任意改变存在于聚醚多元醇共聚物主链中的O(CH 2)x单元的含量,使得共聚物可具有适合用作弹性体的适当结晶度,通过控制二醇的比例 通过共聚中使用的式(II),同时允许所得聚醚多元醇共聚物的分子量的改变。
    • 10. 发明申请
    • Polymer having unique optical property and polymerizable monomer therefor
    • 具有独特光学性质的聚合物和可聚合单体
    • US20040132963A1
    • 2004-07-08
    • US10475981
    • 2003-10-27
    • Tamaki Nakano
    • C08G065/34
    • C08F12/32C08K5/00
    • A polymer compound having a functional group containing a cyclic part with aromatic properties comprising C, H and/or C, H, X (X is a hetero atom) in the side-chain, and a number average molecular weight of 250-1,000,000. The molar optical absorption due to the cyclic part with aromatic properties of the polymer compound is lower 30% or more than the molar optical absorption due to the cyclic part with aromatic properties in a polymerizing monomer used to introduce the cyclic part with aromatic properties. As this cyclic part has an overlapping stack structure, the compound has a hypochromic effect, and if an electron donor compound or electron-accepting compound is added, a charge transfer complex is formed.
    • 具有包含侧链中C,H和/或C,H,X(X为杂原子),芳族性质的环状部分的官能团的高分子化合物,数均分子量为250〜1,000,000。 由于具有芳族性质的环状部分的高分子化合物引起的摩尔光学吸收由于在用于引入具有芳香性质的环状部分的聚合单体中具有芳族性质的环状部分而导致的摩尔光学吸收降低30%或更多。 由于该环状部分具有重叠的堆叠结构,所以化合物具有低色素效应,并且如果加入电子给体化合物或受电子化合物,则形成电荷转移络合物。