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    • 6. 发明申请
    • Catalyst and process for preparing low-viscosity and color-reduced polyisocyanates containing isocyanurate groups
    • 用于制备含有异氰脲酸酯基团的低粘度和减色多异氰酸酯的催化剂和方法
    • US20030187178A1
    • 2003-10-02
    • US10396475
    • 2003-03-26
    • DEGUSSA AG
    • Stephan KohlstrukIngo BockhoffMichael EwaldRainer Lomoelder
    • C08G018/08
    • C08G18/791B01J31/0278B01J31/0279B01J31/0298B01J31/04B01J2231/341C07C211/63C07C217/58C08G18/092C08G18/1875
    • A low-viscosity polyisocyanates and polyisocyanates of reduced color containing isocyanurate groups is prepared by a process comprising, partially trimerizing aliphatic and/or cycloaliphatic diisocyanates in the presence of 0.02 to 2% by weight, based on the weight of the diisocyanate starting material, of at least one trimerization catalyst of formula (I) 1 wherein and wherein substituents A, B, C, D, and E simultaneously or independently of one another are hydrogen, chloro, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxycarbonyl, hydroxyl, (R5)3SiOnull, (R5)2 Nnull, nullCOOH, (R5)2NnullCH2null or phenyl, it being 5 possible for any two adjacent radicals selected from the group A, B, C, D and E to form a conjoint 5- or 6-membered saturated or unsaturated ring which may also include nitrogen, sulfur or oxygen heteroatoms; F is hydrogen, methyl or fluoro; G is hydrogen, methyl or fluoro; R2 and R3 simultaneously or independently of one another are C1-C18-alkyl or R1; R4 is hydrogen, methyl, C2-C18-alkyl, C3-C8-cycloalkyl or C2-C12-alkoxy; R5 is C1-C18-alkyl; Ynull is R6COOnull; R6 is hydrogen or a branched or unbranched aliphatic or araliphatic C1-C12-alkyl radical, and then removing excess diisocyanate from the reaction medium.
    • 通过一种方法制备低粘度多异氰酸酯和含有异氰脲酸酯基团的多色异氰酸酯,该方法包括在0.02至2重量%的二异氰酸酯原料重量的存在下将脂族和/或脂环族二异氰酸酯部分三聚, 至少一种式(I)的三聚催化剂,其中取代基A,B,C,D和E彼此同时或独立地为氢,氯,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷氧基羰基,羟基,(R 5)3 SiO - ,(R 5)2 N-,-COOH,(R 5)2 N-CH 2 - 或苯基,对于任选的两个相邻基团 由A,B,C,D和E组合形成一个5或6元饱和或不饱和的环,其也可包括氮,硫或氧杂原子; F是氢,甲基或氟; G是氢,甲基或氟; R 2和R 3彼此同时或独立地是C 1 -C 18 - 烷基或R 1; R 4是氢,甲基,C 2 -C 18 - 烷基,C 3 -C 8 - 环烷基或C 2 -C 12 - 烷氧基; R 5是C 1 -C 18 - 烷基; Y - 为R 6 COO - ; R 6是氢或支链或非支链脂族或芳脂族C 1 -C 12 - 烷基,然后从反应介质中除去过量的二异氰酸酯。
    • 7. 发明申请
    • Self-emulsifiable polyisocyanate with high functionality and process for producing the same
    • 具有高功能性的自乳化多异氰酸酯及其制造方法
    • US20030105267A1
    • 2003-06-05
    • US10208034
    • 2002-07-31
    • NIPPON POLYURETHANE INDUSTRY CO., LTD
    • Motomu KitaMitsushige IkemotoToshiaki Sasahara
    • C08G018/08
    • C08G18/222C08G18/283C08G18/706C08G18/7837
    • A self-emulsifiable polyisocyanate with high functionality, having the average number of functional groups in 4.3 or more and a viscosity of 8,000 mPa.s (at 25null C.) or less, which is obtained by subjecting a modified polyisocyanate containing allophanate bonds and a poly(oxyalkylene)glycol monoalkyl ether (e) having oxyethylene bonds in a total amount of 30 mole % or more in its molecule to a urethanization reaction, said modified polyisocyanate being obtained by reacting a polyol (a) having the average number of functional groups in an amount of 2 or more with an organic polyisocyanate (b) in the presence of an allophanate-forming catalyst (c) comprising a zirconium carboxylate; and a process for producing the same. As compared with a conventional self-emulsifiable polyisocyanate, a self-emulsifiable polyisocyanate with high functionality of the present invention is equivalent or similar in water-dispersibility, lower in viscosity, more excellent in performance such as stain resistance, whereby it can be used as a base material or a curing agent for: a water-based paint, an aqueous adhesive, a sealing material, ink, an agent for treating fibers or glass fibers, a sizing agent, a stopping material, a primer, a consolidating agent, an anchor coating agent, various binders, or the like.
    • 具有高官能度的自乳化多异氰酸酯,其官能团的平均数为4.3以上,粘度为8,000mPa.s(25℃)以下,其通过使含有脲基甲酸酯键的改性多异氰酸酯和 所述改性多异氰酸酯通过使具有平均数量的官能团的多元醇(a)反应获得,所述聚(异氰酸酯)是分子内具有30摩尔%以上氧化乙烯键的聚(氧化烯)二醇单烷基醚(e) 在含有羧酸锆的脲基甲酸酯形成催化剂(c)的存在下,使用有机多异氰酸酯(b)的量为2以上的基团; 及其制造方法。 与常规的可自乳化的多异氰酸酯相比,本发明的具有高官能度的自乳化多异氰酸酯在水分散性,粘度较低,耐污性等性能更优异的情况下是相同或相似的,因此其可以用作 用于以下的基材或固化剂:水性涂料,水性粘合剂,密封材料,油墨,纤维或玻璃纤维的处理剂,上浆剂,止挡材料,底漆,固结剂, 锚涂剂,各种粘合剂等。