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1. 发明授权

US06225414B1 Propylene block copolymer 失效
标题翻译：丙烯嵌段共聚物
公开(公告)号：US06225414B1
公开(公告)日：2001-05-01
申请号：US08868539
申请日：1997-06-04
申请人： Takanori Kume , Kazuki Wakamatsu , Eisuke Shiratani
发明人： Takanori Kume , Kazuki Wakamatsu , Eisuke Shiratani
IPC分类号： C08F29708
CPC分类号： C08F297/083 , C08F210/16 , C08F2/001 , C08F2/34
摘要： A polypropylene block copolymer obtained by producing an ethylene-propylene copolymer moiety as a component A having an ethylene content of 1.5 to 6.0% by weight in an amount of 40 to 85% by weight based on the total weight of components A and B in the absence of an inert solvent, substantially, in a first step, with a Ziegler-Natta catalyst, and then producing an ethylene-propylene copolymer moiety as a component B having an ethylene content of 7 to 17% by weight in an amount of 15 to 60% by weight based on an amount of the whole polymer in a gas phase in a second step, wherein an intrinsic viscosity ([&eegr;]B) of the component B is from 2.0 to 5.0 dl/g and the ratio of the intrinsic viscosity ([&eegr;]B) of the component B to an intrinsic viscosity ([&eegr;]A) of the component A is within the range of 0.5 to 1.8.
摘要翻译：一种聚丙烯嵌段共聚物，它通过以乙烯 - 丙烯共聚物部分作为组分A生产乙烯含量为基于A组分和B组分总重量的40至85重量％的重量百分数为1.5至6.0重量％基本上不用惰性溶剂，在第一步中，用齐格勒 - 纳塔催化剂，然后制备乙烯 - 丙烯共聚物部分作为组分B，其乙烯含量为7至17重量％，用量为15至 60重量％，基于第二工序中的气相中的全部聚合物的量，其中，成分B的特性粘度（ηB）为2.0〜5.0dl / g，特性粘度组分B的（ηB）与组分A的特性粘度（ηA）在0.5至1.8的范围内。

2. 发明授权

US06812292B2 Propylene/ethylene block copolymer, blushing-resistant transparent polypropylene resin for molding, elastomer for molding, and molded article obtained therefrom 失效
标题翻译：丙烯/乙烯嵌段共聚物，用于成型的抗白色透明聚丙烯树脂，用于成型的弹性体和由其获得的模塑制品
公开(公告)号：US06812292B2
公开(公告)日：2004-11-02
申请号：US10668198
申请日：2003-09-24
申请人： Minoru Terano , Tetsuya Matsukawa , Hideshi Satake , Masato Takahashi
发明人： Minoru Terano , Tetsuya Matsukawa , Hideshi Satake , Masato Takahashi
IPC分类号： C08F29708
CPC分类号： C08F297/083 , C08F210/06 , C08L53/00 , C08F210/16 , C08F2500/12 , C08F2500/04 , C08F2500/11
摘要： A polypropylene/ethylene block copolymer, which has a poly(ethylene-co-propylene) segment content of 5 to 100 wt. %, excluding 100 wt. %, and a total ethylene content of 2 to 95 wt. %. (a) The block polymer comprises polypropylene segments and poly(ethylene-co-propylene) segments chemically bonded thereto, and (b) the polypropylene segments and the poly(ethylene-co-propylene) segments have been synthesized in the presence of an olefin polymerization catalyst comprising an organometallic compound and a solid catalyst component comprising either titanium and a halogen, or titanium, magnesium, and a halogen. The block copolymer has a weight-average molecular weight of 100,000 or higher, is suitable for producing general-purpose molded articles, and has an excellent balance among mechanical properties, impact resistance, thermal properties, transparency, moldability, and other properties.

3. 发明授权

US06355731B1 Process for the production of heterophasic polymer compositions, and compositions thus obtained 失效
标题翻译：用于生产多相聚合物组合物的方法和由此获得的组合物
公开(公告)号：US06355731B1
公开(公告)日：2002-03-12
申请号：US09509659
申请日：2000-03-30
申请人： Gabriele Govoni , Massimo Covezzi , Jean News
发明人： Gabriele Govoni , Massimo Covezzi , Jean News
IPC分类号： C08F29708
CPC分类号： C08F297/083 , C08F4/65912 , C08F10/00 , C08F10/06 , C08F210/06 , C08F297/08 , C08L23/0815 , C08L23/14 , C08L2207/02 , C08L2308/00 , C08F4/65927 , C08F2/001 , C08F2/42 , C08L2666/04 , C08F210/16 , C08F2500/12 , C08F2500/17
摘要： A process for the preparation of heterophasic polyolefin compositions by (i) polymerizing to form (a) a crystalline propylene or ethylene polymer, and (b) an elastomeric copolymer of ethylene and a C3-C10 &agr;-olefin, wherein the polymerizations are carried out in the presence of a Ziegler-Natta catalyst, (ii) contacting the polymer obtained in (i) with: (a) a compound capable of deactivating the catalyst present in (i), and (b) a catalyst (2) obtained by contacting (I) a compound containing a transition metal M, and at least one ligand coordinated with the metal M by a &pgr; bond, and (II) a cocatalyst, and (iii) copolymerizing ethylene and a C3-C10 &agr;-olefin in the presence of the polymer treated as in (ii), and the catalyst (2).
摘要翻译：通过（i）聚合以形成（a）结晶丙烯或乙烯聚合物和（b）乙烯和C 3 -C 10α-烯烃的弹性共聚物来制备多相聚烯烃组合物的方法，其中进行聚合在齐格勒 - 纳塔催化剂存在下，使（ⅰ）中得到的聚合物与（ⅰ）使（ⅰ）中存在的催化剂失活的化合物和（b）由（ⅰ）中得到的催化剂使（I）含有过渡金属M的化合物和至少一种通过π键与金属M配位的配体，和（II）助催化剂，和（iii）使乙烯和C 3 -C 10α-烯烃在（ii）中处理的聚合物的存在和催化剂（2）。

4. 发明授权

US06730744B1 Method for copolymerization and resulting copolymers 失效
标题翻译：共聚方法和所得共聚物
公开(公告)号：US06730744B1
公开(公告)日：2004-05-04
申请号：US09937090
申请日：2002-07-15
申请人： Guillaume Desurmont , Hajime Yasuda , Jean Malinge
发明人： Guillaume Desurmont , Hajime Yasuda , Jean Malinge
IPC分类号： C08F29708
CPC分类号： C08F297/08 , C08F110/14 , C08F210/06 , C08F210/14 , C08F2500/15 , C08F210/16 , C08F220/06
摘要： The invention concerns a method for preparing block copolymers comprising steps which consist in: polymerising a first monomer using an organolanthanide catalyst wherein said catalyst in the form of a hydride complex of a trivalent metal from the group of rare earths; then in polymerising at least a second monomer. The invention also concerns block copolymers whereof the blocks are polyolefins.
摘要翻译：本发明涉及一种制备嵌段共聚物的方法，其包括以下步骤：使用有机镧系元素催化剂聚合第一单体，其中所述催化剂为来自稀土族的三价金属的氢化物络合物; 然后聚合至少一种第二单体。本发明还涉及嵌段共聚物，其中嵌段是聚烯烃。

5. 发明授权

US06646044B1 Continuous production method of propylene-based block copolymer 失效
标题翻译：丙烯基嵌段共聚物的连续制备方法
公开(公告)号：US06646044B1
公开(公告)日：2003-11-11
申请号：US09805769
申请日：2001-03-16
申请人： Fuminao Watanabe , Eiji Tanaka , Jun Hosoi
发明人： Fuminao Watanabe , Eiji Tanaka , Jun Hosoi
IPC分类号： C08F29708
CPC分类号： C08F297/08 , Y10S526/902 , Y10S526/905
摘要： A stable continuous production of a propylene-based block copolymer can proceed for a long time without causing accumulation of particles having a small diameter by a process having the following steps: (1) polymerizing an &agr;-olefin containing liquid propylene as a main component in the presence of hydrogen and a stereoregular polymerization catalyst in one or more polymerization reactors to obtain a polymer slurry; (2) feeding the polymer slurry to a copolymerization reactor; and (3) copolymerizing propylene and an &agr;-olefin other than propylene substantially in a gaseous phase in the presence of the stereoregular polymerization catalyst, the polymer slurry and a deactivating compound in the copolymerization reactor to obtain a propylene-block copolymer powder. The polymer slurry, discharged from one of said one or more polymerization reactors and is classified using a classification system to obtain a) a classified polymer slurry containing a large amount of particles having a small particle diameter and b) a classified polymer slurry containing a large amount of particles having a large particle diameter. A main part of the classified polymer slurry containing a large amount of particles having a small particle diameter is recycled to a final polymerization reactor of the one or more polymerization reactors.
摘要翻译：丙烯类嵌段共聚物的稳定连续生产可以进行很长时间，而不会通过具有以下步骤的方法积累具有小直径的颗粒：（1）将含有α-烯烃的液体丙烯作为主要成分聚合在一个或多个聚合反应器中存在氢和立体规则聚合催化剂以获得聚合物浆料; （2）将聚合物浆料进料到共聚反应器中; 和（3）在立体规则聚合催化剂，聚合物浆料和失活化合物存在下，在共聚反应器中共聚丙烯和丙烯以外的基本上气相的α-烯烃，得到丙烯 - 嵌段共聚物粉末。从所述一个或多个聚合反应器之一排出的聚合物浆料，并使用分级体系进行分级，以获得a）含有大量具有小粒径的颗粒的分级聚合物浆料和b）含有大量颗粒的分级聚合物浆料具有大粒径的粒子的量。含有大量具有小粒径的颗粒的分级聚合物浆料的主要部分被循环到一个或多个聚合反应器的最终聚合反应器中。

6. 发明授权

US06214939B1 Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer 失效
标题翻译：烯烃聚合催化剂和制备聚丙烯和丙烯嵌段共聚物的方法
公开(公告)号：US06214939B1
公开(公告)日：2001-04-10
申请号：US09089116
申请日：1998-06-03
申请人： Tetsunori Shinozaki , Mamoru Kioka
发明人： Tetsunori Shinozaki , Mamoru Kioka
IPC分类号： C08F29708
CPC分类号： C08F297/083 , C08F10/06 , C08F110/06 , C08F210/06 , Y02P20/52 , Y10S526/904 , C08F4/6492 , C08F4/6494 , C08F4/6465 , C08F2500/17 , C08F2500/12 , C08F2500/15 , C08F2500/18 , C08F210/16
摘要： The present invention provides olefin polymerization catalysts and processes for preparing a polypropylene and a propylene block copolymer using the olefin polymerization catalysts. The olefin polymerization catalyst (1) of the invention is formed from: (I-1) a contact product obtained by contacting: (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (C) a specific organosilicon compound; (II-1) (D) a specific polyether compound; and optionally, (III) an organometallic compound catalyst component. The olefin polymerization catalyst (2) of the invention is formed from: (I-2) a contact product obtained by contacting: (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (D) a specific polyether compound; (II-2) (C) a specific organosilicon compound; and optionally, (III) an organometallic compound catalyst component. The propylene is polymerized in the presence of the above-mentioned olefin polymerization catalysts to prepare highly isotactic polypropylene. The propylene block copolymer is prepared by the steps of polymerizing propylene to form a polypropylene component and copolymerizing ethylene and an &agr;-olefin of 3 to 20 carbon atoms to form an ethylene/&agr;-olefin copolymer component in the presence of the polymerization catalysts.
摘要翻译：本发明提供烯烃聚合催化剂和使用烯烃聚合催化剂制备聚丙烯和丙烯嵌段共聚物的方法。本发明的烯烃聚合催化剂（1）由以下物质形成：（I-1）通过使（A）固体钛催化剂成分，（B）有机金属化合物催化剂成分和（C）有机硅化合物; （II-1）（D）特定的聚醚化合物; 和（III）有机金属化合物催化剂组分。本发明的烯烃聚合催化剂（2）由以下物质形成：（I-2）通过使（A）固体钛催化剂成分（B）有机金属化合物催化剂成分与（D）聚醚化合物; （II-2）（C）特定的有机硅化合物; 和（III）有机金属化合物催化剂组分。丙烯在上述烯烃聚合催化剂的存在下聚合以制备高度全同立构的聚丙烯。丙烯嵌段共聚物通过聚合丙烯以形成聚丙烯组分并使乙烯和3-20个碳原子的α-烯烃共聚以在聚合催化剂存在下形成乙烯/α-烯烃共聚物组分的步骤来制备。

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