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1. 发明专利

MX9710520A COMPOSICIONES NOVEDOSAS DE PEROXIDO DE ACIDO OXALICO Y USOS. 未知
公开(公告)号：MX9710520A
公开(公告)日：1998-12-31
申请号：MX9710520
申请日：1997-12-19
申请人： ATOCHEM NORTH AMERICA ELF
发明人： SANCHEZ JOSE , STEIN DARYL L
IPC分类号： C07C409/00 , C07C409/16 , C07C409/18 , C07C409/20 , C07C409/22 , C07C409/38 , C07C409/40 , C08F4/32 , C08F4/34 , C08K5/14 , C08F04/38
摘要： Se describe una composicion novedosa de peroxidos de la Estructura A, y uso de la composicion novedosa de peroxido de ácido oxálico de la Estructura A como un iniciador; a) para curar resinas de poliester insaturadas, b) para polimerizar monomeros etilénicamente insaturados, c) para entrelazar poliolefinas, d) para curar elastomeros, e) para modificar poliolefinas, f) para injertar monomeros de vinilo en estructuras de la base de polímeros y g) para compatibilizar mezclas de dos o más polímeros incompatibles.

2. 发明专利

MX9706842A PEROXIDOS DE CETONA CICLICOS COMO INICIADORES DE POLIMERO. 未知
公开(公告)号：MX9706842A
公开(公告)日：1997-11-29
申请号：MX9706842
申请日：1996-03-06
申请人： AKZO NOBEL NV
发明人： STIGTER LEONIE ARINA , MEIJER JOHN , SWIETEN ANDREAS PETRUS VAN
IPC分类号： C07D323/00 , C07D323/04 , C08F4/00 , C08F4/36 , C08F4/38 , C08F10/00 , C08F12/00 , C08F12/08 , C08F04/00 , C08F04/38
摘要： Un procedimiento para la preparacion de (co)polímeros que emplean una composicion de peroxido que comprende por lo menos un peroxido orgánico en donde por lo menos 20% del contenido de oxígeno activo total de dicho peroxido orgánico se atribuye a uno o más peroxidos de cetona cíclicos representados por las formulas (I-III); estos peroxidos de cetona cíclicos son altamente eficientes como iniciadores de la polimerizacion; se proveen también peroxidos de cetona cíclicos nuevos y composiciones que comprenden dichos compuestos.

3. 发明专利

MX9700535A FORMULACIONES DE PEROXIDO DE CETONA CICLICO. 未知
公开(公告)号：MX9700535A
公开(公告)日：1997-04-30
申请号：MX9700535
申请日：1995-07-14
申请人： AKZO NOBEL NV
发明人： TORENBEEK REINDER , MEIJER JOHN , HOGT ANDREAS HERMAN , BEKENDAM GERRIT
IPC分类号： C07D323/00 , C07D323/04 , C08F4/36 , C08F4/38 , C08F8/06 , C08F8/50 , C08K5/14 , C08K5/15 , C08F04/38 , C08K05/14 , C08K05/15
摘要： Se describe una composicion de peroxido de cetona cíclico transportable y estable en almacenamiento que consta de 1.0-90% en peso de uno o más peroxidos de cetona cíclicos y 10-99% en peso de uno o más diluyentes seleccionados del grupo que consta de flemetizadores líquidos para los peroxidos de cetona cíclicos, plastificadores, vehículos poliméricos solidos, soportes inorgánicos, peroxidos orgánicos y mezclas de los mismos; también se describe el uso de estas formulaciones de peroxido de cetona cíclico en la modificacion de copolímeros; estas formulaciones proveen un grado sorprendente de modificacion de los polímeros en comparacion con sus contrapartes, los peroxidos de cetona no cíclicos.

4. 发明公开

EP0080338A3 Polymerization of polyol (allyl carbonate) using polymerization initiators of short and long half lives 有权转让
标题翻译：使用短期和长期半衰期的聚合引发剂聚合多元醇（全氟代碳酸酯）
公开(公告)号：EP0080338A3
公开(公告)日：1983-07-20
申请号：EP82306166
申请日：1982-11-19
申请人： PPG INDUSTRIES, INC.
发明人： Leatherman, Ivan Roger
IPC分类号： C08F18/24 , C08F04/38
CPC分类号： C08F18/24
摘要： A liquid composition comprising a polyol(allyl carbonate), a photochromic agent, and a first peroxide polymerization initiator characterized in that a second peroxide polymerization initiator is present, the second initiator having a half life at least five times greater than the first, measured atthe same temperature, in polyol(allyl carbonate) and a method of polymerizing a polyol(allyl carbonate) having a photochromic agent incorporated therein by adding a first peroxide polymerization initiator to the polyol(allyl carbonate) monomer and curing the polyol(allyl carbonate), characterised in that a second peroxide polymerization initiator is added to the polyol(allyl carbonate), the second initiator having a half life at least five times greaterthan the first, measured at the same temperature, in polyol(allyl carbonate).

5. 发明公开

EP0090627A3 Method for producing a plastic lens 失效
标题翻译：生产塑料镜片的方法
公开(公告)号：EP0090627A3
公开(公告)日：1984-07-25
申请号：EP83301713
申请日：1983-03-28
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Moriya, Yasuo , Fukushi, Kyosuke , Nakayama, Masaharu
IPC分类号： C08F18/16 , C08F04/38 , B29D11/02
CPC分类号： C08F18/24 , G02B1/041 , C08L31/00
摘要： A plastic lens which has high hardness and excellent scratch resistance and can form a transparent and uniform reflection preventing film through vacuum deposition, is produced by mixing
(a) diethylene glycol bis(allyl carbonate) with (b) at least one of organic peroxides having a decomposition temperature at selected half-life value for ten hours of not higher than 80°C and (c) at least one of organic peroxides having a decomposition temperature at selected half-life value for ten hours of 90-110°C, which have no copolymerizability to the diethylene glycol bis(allyl carbonate) (a), as a polymerization initiator, and polymerizing and casting the resulting mixture in a desired lens-forming mold.

6. 发明公开

EP0189930A3 Process for preparing acrylic polymers using a dual peroxide initiator system 失效
标题翻译：使用双过氧化物引发剂体系制备丙烯酸聚合物的方法
公开(公告)号：EP0189930A3
公开(公告)日：1988-12-07
申请号：EP86101273
申请日：1986-01-31
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Heitner, Barry Jordan
IPC分类号： C08F265/06 , C08F04/38 , C08F20/14
CPC分类号： C08F265/06 , C08F2/02
摘要： A process for producing acrylic polymers which have high thermal stability, are free of defects and have a low level of unreacted monomer. The process includes the polymerization at a high production rate of a methyl methacrylate syrup in the presence of a mixture of two peroxide initiators. The first initiator has a 5-minute half-life at temperatures between about 75°C to 100°C and emits a maximum of 1 mole of carbon dioxide per 2 moles of free radicals. The second initiator has a one minutes half-life at temperature of between about 105°C to about 125°C and emits a maximum of 1 mole of carbon dioxide per 1 mole of free radicals.

7. 发明申请

WO1995017438A1 STYRENE POLYMERIZATION PROCESS 审中-公开
标题翻译：苯乙烯聚合方法
公开(公告)号：WO1995017438A1
公开(公告)日：1995-06-29
申请号：PCT/US1993012491
申请日：1993-12-21
申请人： KELLEY, Joseph, M.
IPC分类号： C08F04/38
CPC分类号： C08F279/04 , C08F12/08 , C08F279/02 , C08F212/08
摘要： An improved process for the polymerization of the styrene is provided. The process comprises feeding styrene monomer (1) and a mixture of peroxides (3), which decompose at progressively higher temperatures, into a prepolymerization vessel (1) maintained at 200-270 DEG F. About 20-40 % of the styrene in this vessel is converted to polymer (depending on temperature and residence time) and then fed to an extruder (5) where the polymer is raised in temperature by passage throught a heat exchanger (4) or through the heated throat of the extruder (5). During this heating, the polymerization is completed in seconds to minutes in an extruder (5) as the peroxides decompose in sequence as the temperature rises. A final devolatilization zone (6) is provided to remove the final traces of monomer. The molten polymer is then passed through a die (7) and stranded or hot die face cut. In like manner, this process can be used to produce styrene-acrylonitrile copolymers by the addition, prior to prepolymerization, of acrylonitrile to the prepolymerization vessel (1), impact polystyrene by the addition of rubber to the styrene in a dissolver (12) and ABS by the addition of rubber and acrylonitrile to the styrene in a dissolver (12) prior to prepolymerization.
摘要翻译：提供了改进的苯乙烯聚合方法。该方法包括将苯乙烯单体（1）和在逐渐升高的温度下分解的过氧化物（3）的混合物加入到保持在200-270°F的预聚合容器（1）中。该方法中约20-40％的苯乙烯将容器转化成聚合物（取决于温度和停留时间），然后进料到挤出机（5）中，其中聚合物通过热交换器（4）或通过挤出机（5）的加热喉道在温度下升高。在这种加热过程中，当挤出机（5）中的过氧化物随着温度升高而依次分解时，聚合在几分钟内完成。提供最终的脱挥发区（6）以除去最终痕量的单体。然后将熔融的聚合物通过模具（7）并且被切割或绞合或热模切面。以类似方式，该方法可用于通过在预聚合之前将丙烯腈加入到预聚合容器（1）中，通过在溶解器（12）中向苯乙烯中加入橡胶来冲击聚苯乙烯来生产苯乙烯 - 丙烯腈共聚物，以及 ABS通过在预聚合之前在溶解器（12）中向苯乙烯中加入橡胶和丙烯腈。

8. 发明公开

EP0206289A3 Preparation of acrylic polymers using a ternary peroxide initiator system 有权转让
标题翻译：使用过氧化氢初始化系统制备丙烯酸聚合物
公开(公告)号：EP0206289A3
公开(公告)日：1988-12-07
申请号：EP86108467
申请日：1986-06-20
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Heitner, Barry Jordan
IPC分类号： C08F265/06 , C08F220/14 , C08F04/38
CPC分类号： C08F265/06 , C08F2/02
摘要： A process for producing acrylic polymers at a high rate which have high thermal stability, are free of defects and have a low level of unreacted monomer by polymerization of a methyl methacrylate syrup in the presence of a mixture of three peroxide initiators.

9. 发明公开

EP0109532A3 Olefin polymers and a process for preparing them 失效
标题翻译： OLEFIN聚合物及其制备方法
公开(公告)号：EP0109532A3
公开(公告)日：1985-12-18
申请号：EP83110192
申请日：1983-10-12
申请人： Montedison S.p.A.
发明人： Clementini, Luciano , Spagnoli, Leonardo
IPC分类号： C08F255/02 , C08F04/38 , C08F220/06
CPC分类号： C08F255/02 , C08F222/02 , C08F220/06
摘要： The invention relates to olefinic polymers characterized by the presence of free carboxylic groups arranged along the polymeric chain, obtained by radicalic grafting of unsaturated carboxylic acids onto the chain of the olefinic polymer. The products so obtained exhibit in particular a high adhesion to metals. The manufacturing process is based on the use of at least two different organic peroxides, having different reactivities.

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