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1. 发明专利

BG16850A1 未知
公开(公告)号：BG16850A1
公开(公告)日：1973-04-25
申请号：BG1640270
申请日：1970-12-24
IPC分类号： C08D1/18

2. 发明专利

PH15236A CATALYST COMPLEXES FOR THE POLYMERIZATION OF ALPHA OLEFINS 未知
公开(公告)号：PH15236A
公开(公告)日：1982-10-07
申请号：PH15527
申请日：1974-02-19
申请人： SOLVAY
发明人： HERMANS JEAN P , HENRIOULLE PAUL
IPC分类号： C08D1/12 , C08D1/14 , C08D1/18

3. 发明专利

DE2359586A1 未知
公开(公告)号：DE2359586A1
公开(公告)日：1974-06-20
申请号：DE2359586
申请日：1973-11-29
申请人： SNAM PROGETTI
发明人： LUGLI GABRIELE , MAZZEI ALESSANDRO , BRANDI GABRIELLA
IPC分类号： C08F4/00 , C08F2/00 , C08F2/48 , C08F4/40 , C08F4/44 , C08F4/60 , C08F4/72 , C08F10/00 , C08F36/04 , C08D1/18 , C08F1/46 , C08D3/02
摘要： An olefin or diolefin is polymerized, and mixtures thereof are copolymerized, in the presence of a catalyst system consisting of:

4. 发明专利

NL7109181A 未知
公开(公告)号：NL7109181A
公开(公告)日：1972-01-04
申请号：NL7109181
申请日：1971-07-02
IPC分类号： C07F3/00 , C08F2/00 , C08F4/12 , C08F36/04 , C08F1/74 , C08D1/18
摘要： Novel bisorganoalkaline earth metal compounds are prepared by reacting bisorganomercurials with calcium, strontium or barium. The novel process is conducted in a solvent. As an example, dibenzylcalcium is prepared by reacting dibenzylmercury with calcium in tetrahydrofuran. The bisorganoalkaline earth metal compounds are useful as metallating reagents in organic synthesis and as initiators in the polymerization of vinyl monomers, such as styrene and butadiene.

5. 发明授权

US3935175A Process for the polymerization of unsaturated compounds 失效
标题翻译：不饱和化合物聚合方法
公开(公告)号：US3935175A
公开(公告)日：1976-01-27
申请号：US417077
申请日：1973-11-19
申请人： Gabriele Lugli , Alessandro Mazzei , Gabriella Brandi
发明人： Gabriele Lugli , Alessandro Mazzei , Gabriella Brandi
IPC分类号： C08F4/00 , C08F2/00 , C08F2/48 , C08F4/40 , C08F4/44 , C08F4/60 , C08F4/72 , C08F10/00 , C08F36/04 , C08D1/14 , C08D1/18 , C08D1/20
CPC分类号： C08F10/00 , C08F36/04
摘要： An olefin or diolefin is polymerized, and mixtures thereof are copolymerized, in the presence of a catalyst system consisting of:A. a uranium compound consisting of U(OCH.sub.3).sub.4, U(OCH.sub.3).sub.3 Cl, U(OC.sub.4 H.sub.9).sub.4, U(OC.sub.8 H.sub.17).sub.4, U [N(C.sub.2 H.sub.5).sub.2 ].sub.4, U [N(C.sub.2 H.sub.5).sub.2 ].sub.3 Br, U(OCH.sub.3).sub.5, U(O-i-C.sub.4 H.sub.9).sub.5 ;b. a reducing compound of a metal belonging to the 2nd or 3rd group of the periodic system, selected from the hydrides, mixed hydrides and alkyl derivatives thereof;C. a Lewis acid selected from AlBr.sub.3, AlI.sub.3, AlCl.sub.3, AlCl.sub.3.OEt.sub.2, Al R Cl.sub.2, B Cl.sub.3 and TiCl.sub.4, wherein R is a hydrocarbon radical.
摘要翻译：在由以下组成的催化剂体系的存在下，将烯烃或二烯烃聚合，并将其混合物共聚合：

6. 发明授权

US3892722A Method for preparing stereoregular 1,4-transpolymers of 2-alkyl- butadienes-1,3 or stereoregular 1,4-transcopolymers of 2-alkylbutadienes-1,3 with butadiene-1,3 失效
标题翻译： 2-烷基丁二烯-1,3与2,3-丁二烯-1,3-的2-烷基 - 丁二烯-1,3或立构规整的1,4-转化聚合物的立体规定的1,4-交联聚合物的方法
公开(公告)号：US3892722A
公开(公告)日：1975-07-01
申请号：US37047273
申请日：1973-06-15
申请人： BABITSKY BORIS DAVIDOVICH , BERESNEV VADIM NIKOLAEVICH , BOLSHAKOVA TATYANA GEORGIEVNA , BUZINA NATALYA ANATOLIEVNA , VASILIEV VALENTIN ALEXANDROVIC , KALINICHEVA NADEZHDA ANDREEVNA , KORMER VITALY A , ZOBACH MARK IOSIFOVICH , RADCHENKO IVAN IGNATIEVICH , KHRUSTALEVA TAISIYA DANILOVNA
发明人： BABITSKY BORIS DAVIDOVICH , BERESNEV VADIM NIKOLAEVICH , BOLSHAKOVA TATYANA GEORGIEVNA , BUZINA NATALYA ANATOLIEVNA , VASILIEV VALENTIN ALEXANDROVIC , KALINICHEVA NADEZHDA ANDREEVNA , KORMER VITALY ABRAMOVICH , ZOBACH MARK IOSIFOVICH , RADCHENKO IVAN IGNATIEVICH , KHRUSTALEVA TAISIYA DANILOVNA
IPC分类号： C08F4/00 , C08F4/42 , C08F36/04 , C08D1/18 , C08D3/08
CPC分类号： C08F36/04 , C08F4/82
摘要： A method for preparing stereoregular 1,4-transpolymers of 2alkylbutadienes-1,3 or stereoregular 1,4-transcopolymers of 2alkylbutadienes-1,3 with butadiene-1,3 consisting in that 2alkylbutadienes-1,3 are polymerized or 2-alkylbutadienes-1,3 are copolymerized with butadiene-1,3 in an aqueous medium in the presence of pi -allyl complexes of nickel having the general formula

WHERE R1, R2, R3, R4 and R5 are hydrogen, alkyl, aryl, halide, or various combinations thereof, and X is a monovalent anion, with subsequent isolation of the main products from the reaction mixture. The proposed method ensures the preparation of the above named polymers and coopolymers of 1,4-trans-stereoregular structure, which is responsible for their high elasticity and strength. The method is simple and efficient, since the polymerization and copolymerization processes are effected in an aqueous medium.
摘要翻译：制备2-烷基丁二烯-1,3或2-烷基丁二烯-1,3的立构规整的1,4-转移聚合物与丁二烯-1,3的2-偶氮二烯-1,3或1,3-丁二烯-1,3-的方法，在具有通式为R 1，R 2，R 3，R 4和R 5为氢的烷基，烷基，环烷基，环烷基，环烷基，环烷基，芳基，卤化物或其各种组合，X是一价阴离子，随后从反应混合物中分离出主要产物。

7. 发明授权

US3846388A Copolymer of a conjugated diolefin and vinyl chloride and manufacturing process therefor 失效
标题翻译：共轭二烯和氯乙烯的共聚物及其制备方法
公开(公告)号：US3846388A
公开(公告)日：1974-11-05
申请号：US35880773
申请日：1973-05-09
申请人： BRIDGESTONE TIRE CO LTD
发明人： OHASHI T , SAKATA R
IPC分类号： C08F214/06 , C08F236/04 , C08D3/04 , C08D1/18
CPC分类号： C08F214/06 , C08F236/04
摘要： A high molecular weight copolymer of a conjugated diolefin and vinyl chloride in which the vinyl chloride content is from 5 mol up to 50 mol percent relative to the total monomers and the vinyl chloride unit is distributed at random in the molecule chain, and a manufacturing process for such copolymer by carrying out the copolymerization by adding a particular catalyst in the presence of at least the vinyl chloride monomer, in a halogenated hydrocarbon as solvent, at a temperature of -100* to 80*C so that the molar ratio of said catalyst to the total amount of the monomers as charged is 0.05 to 0.0001. The catalyst is any acidic Friedel-Crafts metal halide compound wherein the metal belongs to Group II to VIII of the Periodic Table or alkylaluminum halide compound of the general formula, A1 Rn X3 n wherein R represents an alkyl group, X represents a halogen atom and n represents 1 or 1.5.
摘要翻译：共轭二烯烃和氯乙烯的高分子量共聚物，其中相对于总单体和氯乙烯单元的氯乙烯含量为5摩尔至50摩尔％，在分子链中随机分布，制造过程对于这种共聚物，通过在至少氯乙烯单体的存在下，在卤代烃作为溶剂中，在-100〜80℃的温度下，通过加入特定的催化剂进行共聚，使得所述催化剂的摩尔比相对于所加入的单体的总量为0.05〜0.0001。该催化剂是任何酸性Friedel-Crafts金属卤化物，其中金属属于元素周期表第Ⅱ至VIII族或通式为Al Rn X3-n的烷基铝卤化物，其中R表示烷基，X表示卤素原子 n表示1或1.5。

8. 发明授权

US3515656A Photopolymerization process for hydroxy alkyl acrylates 失效
标题翻译：羟丙基丙烯酸酯的光聚合方法
公开(公告)号：US3515656A
公开(公告)日：1970-06-02
申请号：US3515656D
申请日：1966-07-15
申请人： MITSUBISHI GAS CHEMICAL CO
发明人： HUANG CHING YUN , SATO KATSUO , IKEGAMI MASUYA
IPC分类号： C08F2/46 , C08F20/22 , C08F20/28 , C08D1/16 , C08D1/18
CPC分类号： C08F20/22 , C08F20/28

9. 发明授权

US3864319A Method for preparing alternating copolymers using a friedel-crafts catalyst and a free radical initiator in an aqueous medium 失效
标题翻译：在水介质中使用Friedel-Crafts催化剂和自由基引发剂制备交替共聚物的方法
公开(公告)号：US3864319A
公开(公告)日：1975-02-04
申请号：US30296472
申请日：1972-11-01
申请人： GAYLORD RESEARCH INST INC
发明人： GAYLORD NORMAN G
IPC分类号： C08F4/28 , C08F236/04 , C08D1/09 , C08D1/18 , C08D1/22
CPC分类号： C08F4/28 , C08F236/04
摘要： An improved method for preparing 1:1 alternating copolymers by reacting an electron donor monomer and an electron acceptor monomer in an aqueous medium in the presence of a Friedel-Crafts halide and a water-soluble free radical initiator.
摘要翻译：在Friedel-Crafts卤化物和水溶性自由基引发剂存在下，通过使电子供体单体和电子受体单体在水性介质中反应制备1：1交替共聚物的改进方法。

10. 发明授权

US3845030A Preparation of organometal terminated polymers 失效
标题翻译：有机终止聚合物的制备
公开(公告)号：US3845030A
公开(公告)日：1974-10-29
申请号：US30777372
申请日：1972-11-20
申请人： PHILLIPS PETROLEUM CO
发明人： URANECK C , SMITH R
IPC分类号： C08C19/44 , C08D1/18 , C08D5/02 , C08D5/04
CPC分类号： C08C19/44
摘要： 1. A POLYMERIZATION PROCESS WHICH COMPRISES POLYMERIZING MONOMERS SELECTED FROM THE GROUP CONSISTING OF CONJUGATED DIENES AND CONJUGATED DIENES IN ADMIXTURE WITH VINYL-SUBSTITUTED AROMATIC COMPOUNDS, WITH AN ALKALI METAL, ORGANOALKALI METAL, OR ORGANOALKALINE EARTH METAL INITIATOR, THEREBY PRODUCING POLYMER CONTAINING TERMINAL REACTIVE ALKALI OR ALKALINE EARTH METAL GROUPS, WHEREIN THE IMPROVEMENT COMPRISES MODIFYING SIAD POLYMER TO INCREASE THE FILLER-POLYMER INTERACTION IN FILLER-LOADED STOCKS BY TREATING SAID POLYMER CONTAINING TERMINAL REACTIVE ALKALI OR ALKALONE EARTH METAL GROUPS WITH A MODIFYING AGENT CONSISTING ESSENTIALLY OF AT LEAST ONE R(Z-1)MX WHEREIN R IS A HYDROCARBON RADICAL CONTAINING UP TO 12 CARBON ATOMS, M IS A METAL SELECTED FROM GROUPS 2B, 4A, AND 5A, X IS A RADICAL SELECTED FROM THE GROUP CONSISTING OF HALOGEN, -OR, -SR, AND -N(R)2 AND Z IS AN INTEGER EQUAL TO THE VALANCE OF M.

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