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    • 2. 发明授权
    • Surface-active alkylurethanes of fructans
    • 果聚糖的表面活性烷基聚氨酯
    • US06534647B1
    • 2003-03-18
    • US09719321
    • 2000-12-11
    • Christian Victor StevensKarl BootenIsabelle M.-A. LaquiereLucien Daenekindt
    • Christian Victor StevensKarl BootenIsabelle M.-A. LaquiereLucien Daenekindt
    • C07H1100
    • C08B37/0051C07H3/00C11D1/10C11D1/50
    • The invention concerns the use as surface-active agent of a fructan N-alkylurethane (I) which is composed of saccharide units of general formula (II) A(O—CO—NH—R)s  (II) wherein A represents a fructosyl unit (F) or a terminal glucosyl unit (G) of said fructan, being a levan or an inulin, with a degree of polymerisation (DP) of minimum 3, (O—CO—NH—R) represents an N-alkylaminocarbonyloxy group replacing a hydroxyl group of the saccharide unit A, wherein R represents a linear or branched, saturated or unsaturated alkyl group containing from 3 to 22 carbon atoms and any mixture thereof, and s represents the number of N-alkylaminocarbonyloxy groups per saccharide unit which is expressed as degree of substitution (DS), and said DS has a value ranging from 0.10 to 2.0. The invention further relates to novel fructan N-alkylurethanes (I), in particular inulin N-alkylurethanes (I), and a method for their manufacture. The fructan N-alkylurethanes (I) have good to excellent surface-active properties in combination with good biodegradability and are suitable as surfactants for use in household and industrial applications, e.g. as detergents, emulsifiers, emulsion stabilizers, foaming agents, foam stabilisers, dispersants and wetting agents.
    • 本发明涉及由通式(II)的糖类单元构成的果聚糖N-烷基氨基甲酸酯(I)的表面活性剂的用途,其中A表示所述果聚糖的果糖基单元(F)或末端葡糖基单元(G) (DP)为3,(O-CO-NH-R)表示取代糖单元A的羟基的N-烷基氨基羰基氧基,其中R表示直链 或含有3至22个碳原子的支链,饱和或不饱和的烷基及其任何混合物,s表示以取代度(DS)表示的每个糖单元的N-烷基氨基羰基氧基的数目,并且所述DS具有值 范围从0.10到2.0。 本发明还涉及新型果聚糖N-烷基氨基甲酸酯(I),特别是菊糖N-烷基氨基甲酸酯(I)及其制备方法。 果聚糖N-烷基氨基甲酸酯(I)具有良好至优异的表面活性特性以及良好的生物降解性,并且适合用作家用和工业应用的表面活性剂,例如, 作为洗涤剂,乳化剂,乳液稳定剂,发泡剂,泡沫稳定剂,分散剂和润湿剂。
    • 4. 发明授权
    • &agr;-D-pentofuranosides, and a process for preparing the same
    • α-D-呋喃糖苷类及其制备方法
    • US06229008B1
    • 2001-05-08
    • US08793515
    • 1997-04-18
    • Jörn SaischekBerndt Stadelmann
    • Jörn SaischekBerndt Stadelmann
    • C07H1100
    • C07H15/18C07H19/04C07H19/16
    • &agr;-D-pentofuranoside derivatives have the general formula (D), in which R stands for (C1-C4)alkyl that is non-substituted or substituted one or several times by halogen, (C1-C4)alkyl, (C1-C4)alkoxy and/or phenyl, and R1 stands for [(C6-C20)aryl]k−[(C1-C4)alkyl or [(C6-C20)]aryl]k−[(C1-C12)alkyl)(3-k)Si in which k=0 to 3, that are non-substituted or substituted one or several times by halogen, (C1-C4)alkyl, (C1-C4)alkoxy and/or (C6-C20) aryl, or preferably a benzyl that is non-substituted or substituted one or several times by the above substituents. Also disclosed are starting and intermediary compounds, up to furanosides (D) having an analogous structure, processes for preparing said furanosides and their precursors, and their use.
    • α-D-呋喃糖苷衍生物具有通式(D),其中R代表被卤素,(C1-C4)烷基,(C1-C4)烷基取代或未取代一次或数次的(C1-C4)烷基 )烷氧基和/或苯基,R1代表[(C6-C20)芳基] k - [(C1-C4)烷基或[(C6-C20)]芳基] k - [(C1-C12)烷基) -k)其中k = 0至3的Si,其被未取代或被卤素,(C1-C4)烷基,(C1-C4)烷氧基和/或(C6-C20)芳基取代或取代一次或数次,或 优选通过上述取代基未取代或取代一次或数次的苄基。 还公开了具有类似结构的呋喃糖苷(D)的起始和中间化合物,制备所述呋喃糖苷及其前体的方法及其用途。