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    • 1. 发明授权
    • N-sulphonyl and N-sulphinyl amino acid derivatives as microbicides
    • N-磺酰基和N-亚磺酰氨基酸衍生物作为杀微生物剂
    • US06194611B1
    • 2001-02-27
    • US09051688
    • 1998-04-16
    • Martin Zeller
    • Martin Zeller
    • C07C33100
    • C07C311/06A01N41/06C07C307/06
    • &agr;-Amino acid amides of formula (I) wherein the substituents are defined as follows: n is the number zero or one; R1 to R7 are as herein defined; R8 is C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl; R9 is C3-C8cycloalkyl; a C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl group substituted by one or more halogen atoms; or a group (a) wherein p and q are identical or different and are each independently of the other the number zero or one; and R13, R14, R15 and R16 are identical or different and are each independently of the others hydrogen or C1-C4alkyl; and X is hydrogen, in which case p and q must have the value zero; phenyl unsubstituted or mono- or poly-substituted by halogen, nitro, cyano, carboxy, C2-C6alkenyl, C2-C6alkynyl, C1-C6haloalkyl, C3-C6alkenyloxy, C3-C6alkynyloxy, C3-C7cycloalkyl, C1-C6haloalcoxy, C1-C6alkylthio, C1-C6alcoxycarbonyl, C3-C6alkenyloxycarbonyl, C3-C6alkynyloxycarbonyl, C1-C6alkyl or by C1-C6alkoxy; cyano; —COOR17; —COR18 or a group (b) wherein R17 and R21 are each independently of the other hydrogen, C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl, and R18 is hydrogen; C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl or phenyl, unsubstituted or substituted by halogen, nitro, cyano, C1-C4alkyl or by C1-C4alkoxy, and R19 and R20 are identical or different and are each independently of the other hydrogen or C1-C4alkyl, are valuable microbicides. They can be used in plant protection in the form of suitable compositions, for example in the control of fungal diseases.
    • 式(I)的α-氨基酸酰胺,其中取代基定义如下:n是数字0或1; R1至R7如本文所定义; R8是C1-C6烷基,C3-C6链烯基或C3-C6炔基; R9为C3-C8环烷基; 被一个或多个卤素原子取代的C 1 -C 6烷基,C 3 -C 6烯基或C 3 -C 6炔基; 或其中p和q相同或不同并且各自独立于数字零或一个的基团(a); R 13,R 14,R 15和R 16相同或不同,各自独立地为氢或C 1 -C 4烷基; 并且X是氢,在这种情况下,p和q必须具有零值; 未被取代或被卤素,硝基,氰基,羧基,C 2 -C 6烯基,C 2 -C 6炔基,C 1 -C 6卤代烷基,C 3 -C 6烯氧基,C 3 -C 6炔氧基,C 3 -C 7环烷基,C 1 -C 6卤代烷氧基,C 1 -C 6烷硫基, C 1 -C 6烷氧基羰基,C 3 -C 6烯氧基羰基,C 3 -C 6炔氧基羰基,C 1 -C 6烷基或C 1 -C 6烷氧基; 氰基; -COOR17; -COR 18或其中R 17和R 21各自独立地为其它氢,C 1 -C 6烷基,C 3 -C 6烯基或C 3 -C 6炔基的基团(b),R 18为氢; C 1 -C 6烷基,C 2 -C