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    • 3. 发明授权
    • Method for processing chromium oxide-containing substances in large quantities, method for utilizing the processed substances, and products comprising the processed substances
    • 用于大量处理含铬氧化物的物质的方法,用于处理物质的方法以及包含处理物质的产品
    • US06336967B1
    • 2002-01-08
    • US09047411
    • 1998-03-25
    • Hisahiro MatsunagaMasato KumagaiHiroyuki ToboYasuo KishimotoToshikazu Sakuraya
    • Hisahiro MatsunagaMasato KumagaiHiroyuki ToboYasuo KishimotoToshikazu Sakuraya
    • C04B1814
    • C22B7/006C22B5/08C22B7/04C22B34/32Y02P10/234
    • A method of rapidly reducing chromium oxide-containing slag and the like in large quantities, in a simplified manner and without requiring high temperatures. Chromium oxides are reduced with at least one of elementary sulfur and compounds of sulfur having a valence less than 6. For an aqueous solution of the sulfur component, desirably, its sulfur content is more than 0.03% by weight. As the sulfur source, preferred is blast furnace slag (e.g., non-aged, gradually-cooled blast furnace slag) that is discharged in large quantities in the iron industry. Cr6+ in chromium oxides is reduced in one of the following ways: (a) Chromium oxide-containing substances are sprayed with or immersed in blast furnace slag-released water that has been used in cooling blast furnace slag. (b) Chromium oxide-containing substances are mixed with blast furnace slag, and then kept in an air atmosphere. Optionally, the mixture is sprayed with blast furnace slag-released water. (c) Chromium oxide-containing substances are mixed with blast furnace slag, and then steamed. (d) Prior to the reduction treatment, chromium oxide-containing substances are preferably steamed. 100 parts by weight of reduced chromium oxide-containing compounds are mixed with from 0.1 to 90 parts by weight of sulfur-containing slag, and used in various civil engineering works.
    • 以简化的方式大量快速还原含铬氧化物的炉渣等的方法,而不需要高温。 氧化铬与元素硫和价态小于6的硫化合物中的至少一种一起还原。对于硫成分的水溶液,理想的是其硫含量大于0.03重量%。 作为硫源,优选在铁工业中大量排放的高炉矿渣(例如,未老化,逐渐冷却的高炉渣)。 铬氧化物中的Cr6 +以下列方式之一进行还原:(a)将含氧化铬的物质喷洒或浸入已用于冷却高炉矿渣的高炉排渣水中。 (b)将含氧化铬的物质与高炉矿渣混合,然后保存在空气中。 任选地,混合物用高炉渣释放的水喷洒。 (c)将含氧化铬的物质与高炉矿渣混合,然后蒸。 (d)在还原处理之前,优选蒸去含氧化铬的物质。 将100重量份的含还原氧化铬的化合物与0.1至90重量份的含硫渣混合,并用于各种土木工程中。