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1. 发明公开

CN112811831A 一种增强聚甲醛的玻璃纤维浸润剂及其应用有权
公开(公告)号：CN112811831A
公开(公告)日：2021-05-18
申请号：CN202110038619.1
申请日：2021-01-12
申请人：巨石集团有限公司
发明人：章建忠 , 钱权洲 , 樊家澍 , 黄建 , 张志坚
IPC分类号： C03C25/465 , C03C25/32 , C03C25/323 , C03C25/325
摘要：本发明公开了一种增强聚甲醛的玻璃纤维浸润剂，由固体组分和水组成；固体组分包含偶联剂、成膜剂、交联剂和相容剂，余量为水；浸润剂中各固体组分占浸润剂的质量百分比为：偶联剂0.2～1.2％，成膜剂3～20％，交联剂0.2～1.4％，相容剂0.2～1.5％；其中，硅烷偶联剂为氨基硅烷偶联剂。采用该浸润剂处理后的玻璃纤维，其增强聚甲醛树脂复合材料适用性较强，挤出使用顺畅，复合材料外观优良，无明显浮纤现象，满足市场及应用需求。

2. 发明公开

CN108501476A 一种防寒服用保温材料的加工工艺无效
公开(公告)号：CN108501476A
公开(公告)日：2018-09-07
申请号：CN201810207322.1
申请日：2018-03-14
申请人：合肥远科服装设计有限公司
发明人：张力
IPC分类号： B32B17/02 , B32B17/06 , B32B33/00 , B32B7/12 , B32B5/06 , C03C25/40 , C03C25/285 , C03C25/325 , C03C25/32 , D04H1/02 , D04H1/4382 , D04H1/4218 , D04H1/54
CPC分类号： B32B5/02 , B32B5/06 , B32B7/12 , B32B33/00 , B32B2255/02 , B32B2255/26 , B32B2262/101 , B32B2307/714 , B32B2437/00 , C03C25/285 , C03C25/32 , C03C25/325 , C03C25/40 , D04H1/02 , D04H1/4218 , D04H1/4382 , D04H1/54
摘要：本发明属于服装面料加工技术领域，提供了一种防寒服用保温材料的加工工艺，本发明以聚碳酸酯二元醇和聚甲基丙烯酸十八烷基酯为原料，将原料经过加热得到的混合物再加入由脱乙酰甲壳质和凝胶剂，将上述两种混合物进行混合后加热再固化，固化产物用石油醚洗涤，洗涤后的下层液，用火焰喷吹工艺，喷洒在玻璃纤维上，加热成型，制备得到超细玻璃棉，超细玻璃棉表面粘结布料固定即可。本发明制备的防寒服用保温材料保温隔热性能优异，兼具阻燃性能，值得推广应用。

3. 发明公开

CN116239317A 一种聚乙烯醇修饰的玻璃微管的制备方法审中-实审
公开(公告)号：CN116239317A
公开(公告)日：2023-06-09
申请号：CN202211716553.8
申请日：2022-12-29
申请人：深圳市鑫明光建筑科技有限公司
发明人：徐飙 , 徐凯 , 王明明 , 陈峰
IPC分类号： C03C25/16 , C03C25/465 , C03C25/305 , C03C25/30 , C03C25/325 , C03C25/323 , C03C25/328 , C03C25/32 , C01B3/00
摘要：本发明公开了一种聚乙烯醇修饰的玻璃微管的制备方法，属于氢气存储技术领域，包括如下步骤：称取交联剂溶解至有机溶液中，充分搅拌；称取聚乙烯醇加入到上述溶液中，并进行充分搅拌；将玻璃微管完全浸泡在上述混合溶液中，浸泡时间在5‑120s。在使用玻璃微管进行氢气的制备、运输和储氢过程中，容易在玻璃微管中出现瑕疵或破损，会导致整体储氢材料的性能下降，并造成安全隐患，因此，我们设计了一种通过聚乙烯醇修饰的玻璃微管，通过交联剂将聚乙烯醇包裹在玻璃微管表面，制备了聚乙烯醇修饰的玻璃微管，合成方法简便，操作方便，有利于进一步实现规模化生产，且在实验过程中玻璃微管中空结构保持良好，提高结构稳定性的同时不会影响储氢性能。

4. 发明授权

CN112811831B 一种增强聚甲醛的玻璃纤维浸润剂及其应用有权
公开(公告)号：CN112811831B
公开(公告)日：2022-08-09
申请号：CN202110038619.1
申请日：2021-01-12
申请人：巨石集团有限公司
发明人：章建忠 , 钱权洲 , 樊家澍 , 黄建 , 张志坚
IPC分类号： C03C25/465 , C03C25/32 , C03C25/323 , C03C25/325
摘要：本发明公开了一种增强聚甲醛的玻璃纤维浸润剂，由固体组分和水组成；固体组分包含偶联剂、成膜剂、交联剂和相容剂，余量为水；浸润剂中各固体组分占浸润剂的质量百分比为：偶联剂0.2～1.2％，成膜剂3～20％，交联剂0.2～1.4％，相容剂0.2～1.5％；其中，硅烷偶联剂为氨基硅烷偶联剂。采用该浸润剂处理后的玻璃纤维，其增强聚甲醛树脂复合材料适用性较强，挤出使用顺畅，复合材料外观优良，无明显浮纤现象，满足市场及应用需求。

5. 发明专利

DE1494868B2 未知
公开(公告)号：DE1494868B2
公开(公告)日：1970-09-10
申请号：DE1494868
申请日：1963-08-03
IPC分类号： C03C25/32 , C03C25/325
摘要： Glass fibres are sized by applying thereto a linear polycarbonate having a molecular weight above 10,000. The polycarbonate is preferably one prepared from an aromatic dihydroxy compound preferably a bisphenylol-alkane, -cycloalkene, - ether, -sulphide, -sulphane or sulphide or a mixture of aromatic and aliphatic or cycloaliphatic dihydroxy compounds. Polycarbonates or mixed polycarbonates produced wholly or partially from B-alkenyl-substituted aromatic dihydroxy compounds, e.g. mono-and diallyl-and-methallyl-hydroquinone 3-mono-and 3, 31-diallyl-and-methallyl-4, 41-di-hydroxy diphenyl and the 3-mono-and 3, 31-diallyl-and-methallyl compounds of bio-(4-diphenylol)-methane, -ethane, -propane, -butene, cyclohexane, ether, sulphide, sulphoxide or sulphane, may be used. 0.5-5% by weight solutions or emulsions of the polycarbonates in benzene, toluene, xylene, methylene chloride, ethylene chloride, chloroform or carbon tetrachloride possibly with the addition of mono-or dichloro-benzene or aniode, or aqueous dispersions of the polycarbonates may be applied to the fibres during their production, after burning off a chromium complex size or after coating with a butadiene-styrene copolymer size.

6. 发明专利

GB1027324A Sized glass fibre material 未知
公开(公告)号：GB1027324A
公开(公告)日：1966-04-27
申请号：GB3129564
申请日：1964-08-04
申请人： BAYER AG
IPC分类号： C03C25/32 , C03C25/325
摘要： Glass fibres are sized by applying thereto a linear polycarbonate having a molecular weight above 10,000. The polycarbonate is preferably one prepared from an aromatic dihydroxy compound preferably a bisphenylol-alkane, -cycloalkene, - ether, -sulphide, -sulphane or sulphide or a mixture of aromatic and aliphatic or cycloaliphatic dihydroxy compounds. Polycarbonates or mixed polycarbonates produced wholly or partially from B-alkenyl-substituted aromatic dihydroxy compounds, e.g. mono-and diallyl-and-methallyl-hydroquinone 3-mono-and 3, 31-diallyl-and-methallyl-4, 41-di-hydroxy diphenyl and the 3-mono-and 3, 31-diallyl-and-methallyl compounds of bio-(4-diphenylol)-methane, -ethane, -propane, -butene, cyclohexane, ether, sulphide, sulphoxide or sulphane, may be used. 0.5-5% by weight solutions or emulsions of the polycarbonates in benzene, toluene, xylene, methylene chloride, ethylene chloride, chloroform or carbon tetrachloride possibly with the addition of mono-or dichloro-benzene or aniode, or aqueous dispersions of the polycarbonates may be applied to the fibres during their production, after burning off a chromium complex size or after coating with a butadiene-styrene copolymer size.

7. 发明专利

FR1418417A 未知
公开(公告)号：FR1418417A
公开(公告)日：1965-11-19
申请号：FR996188
申请日：1964-11-25
申请人： BAYER AG
发明人： HECHELHAMMER WILHELM , STREIB HUGO
IPC分类号： C03C25/28 , C03C25/285 , C03C25/32 , C03C25/325 , C08G64/04 , C08K7/14 , C08K9/08 , C08L69/00

8. 发明专利

DE1494869A1 未知
公开(公告)号：DE1494869A1
公开(公告)日：1969-02-20
申请号：DE1494869
申请日：1963-11-29
申请人： BAYER AG
发明人： HUGO STREIB DR , WILHELM HECHELHAMMER DR
IPC分类号： C03C25/32 , C03C25/325
摘要： Glass fibres are sized by applying thereto a linear polycarbonate having a molecular weight above 10,000. The polycarbonate is preferably one prepared from an aromatic dihydroxy compound preferably a bisphenylol-alkane, -cycloalkene, - ether, -sulphide, -sulphane or sulphide or a mixture of aromatic and aliphatic or cycloaliphatic dihydroxy compounds. Polycarbonates or mixed polycarbonates produced wholly or partially from B-alkenyl-substituted aromatic dihydroxy compounds, e.g. mono-and diallyl-and-methallyl-hydroquinone 3-mono-and 3, 31-diallyl-and-methallyl-4, 41-di-hydroxy diphenyl and the 3-mono-and 3, 31-diallyl-and-methallyl compounds of bio-(4-diphenylol)-methane, -ethane, -propane, -butene, cyclohexane, ether, sulphide, sulphoxide or sulphane, may be used. 0.5-5% by weight solutions or emulsions of the polycarbonates in benzene, toluene, xylene, methylene chloride, ethylene chloride, chloroform or carbon tetrachloride possibly with the addition of mono-or dichloro-benzene or aniode, or aqueous dispersions of the polycarbonates may be applied to the fibres during their production, after burning off a chromium complex size or after coating with a butadiene-styrene copolymer size.

9. 发明专利

DE1194143B 未知
公开(公告)号：DE1194143B
公开(公告)日：1965-06-03
申请号：DEF0041439
申请日：1963-11-30
申请人： BAYER AG
发明人： HECHELHAMMER DR WILHELM , STREIB DR HUGO
IPC分类号： C03C25/28 , C03C25/285 , C03C25/32 , C03C25/325 , C08G64/04 , C08K7/14 , C08K9/08 , C08L69/00
摘要： A composition, suitable for the manufacture of moulded articles, comprises a mixture of (a) a thermoplastic polycarbonate and (b) glass fibres sized with a thermoplastic polycarbonate (see Specification 1,027,324). Preferably, the sized glass fibre is uniformly distributed in a melt of the polycarbonate and the compositions then extruded in the form of strands which are then comminuted to a granulate (see Specification 988,563). The composition may also contain glass powder, quartz products, graphite, polytetrafluoroethylene, metal threads or powders or fibres of cotton, sisal, asbestos or synthetic materials. The example describes a composition of the polycarbonate of bisphenol A and glass fibres sized with a copolycarbonate of bisphenol A (90 mol. per cent) and 2,2-bis-(4-hydroxy-3-allyl-phenyl)-propane (10 mol. per cent).

10. 发明专利

DE1494868A1 未知
公开(公告)号：DE1494868A1
公开(公告)日：1969-01-30
申请号：DE1494868
申请日：1963-08-03
申请人： BAYER AG
发明人： HUGO STREIB DR , WILHELM HECHELHAMMER DR
IPC分类号： C03C25/32 , C03C25/325
摘要： Glass fibres are sized by applying thereto a linear polycarbonate having a molecular weight above 10,000. The polycarbonate is preferably one prepared from an aromatic dihydroxy compound preferably a bisphenylol-alkane, -cycloalkene, - ether, -sulphide, -sulphane or sulphide or a mixture of aromatic and aliphatic or cycloaliphatic dihydroxy compounds. Polycarbonates or mixed polycarbonates produced wholly or partially from B-alkenyl-substituted aromatic dihydroxy compounds, e.g. mono-and diallyl-and-methallyl-hydroquinone 3-mono-and 3, 31-diallyl-and-methallyl-4, 41-di-hydroxy diphenyl and the 3-mono-and 3, 31-diallyl-and-methallyl compounds of bio-(4-diphenylol)-methane, -ethane, -propane, -butene, cyclohexane, ether, sulphide, sulphoxide or sulphane, may be used. 0.5-5% by weight solutions or emulsions of the polycarbonates in benzene, toluene, xylene, methylene chloride, ethylene chloride, chloroform or carbon tetrachloride possibly with the addition of mono-or dichloro-benzene or aniode, or aqueous dispersions of the polycarbonates may be applied to the fibres during their production, after burning off a chromium complex size or after coating with a butadiene-styrene copolymer size.

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