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    • 1. 发明授权
    • Heat treatment of anchored nanocatalysts in a non-zero oxidation state and catalysts made by such method
    • 以非零氧化态热处理锚定的纳米催化剂和通过这种方法制备的催化剂
    • US07449423B2
    • 2008-11-11
    • US11101209
    • 2005-04-07
    • Bing ZhouHoracio TrevinoZhihua WuZhenhua ZhouChangkun Liu
    • Bing ZhouHoracio TrevinoZhihua WuZhenhua ZhouChangkun Liu
    • B01J30/00B01J37/00C08F4/02C08F4/60
    • C10G35/09B01J23/40B01J23/42B01J23/56B01J23/626B01J23/8906B01J35/0013B01J35/006B01J37/0203B01J37/08B01J37/18B82Y30/00
    • A catalyst manufacturing process includes heat treating an intermediate catalyst composition that includes catalyst nanoparticles having catalyst atoms in a non-zero oxidation state bonded to a dispersing/anchoring agent. The catalyst nanoparticles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent can be used to form single- or multicomponent supported nanocatalysts. The dispersing agent also acts as an anchoring agent to firmly bond the nanocatalyst to a support. Performing the heat treating process in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation helps maintains a stronger bonding interaction between the dispersing agent and the catalyst atoms. This, in turn, increases the dispersion and/or distribution of catalyst components throughout the supported catalyst.
    • 催化剂制造方法包括热处理包含催化剂纳米颗粒的中间催化剂组合物,所述催化剂纳米颗粒具有与分散/锚固剂结合的非零氧化态的催化剂原子。 催化剂纳米颗粒使用具有至少一个选自羟基,羧基,羰基,酰胺,胺,硫醇,磺酸,磺酰卤,酰基卤, 有机金属络合物,以及它们的组合。 分散剂可用于形成单组分或多组分负载的纳米催化剂。 分散剂也起锚固剂的作用,以将纳米催化剂牢固地粘合到载体上。 在惰性或氧化环境中进行热处理工艺以将催化剂原子维持在非零氧化中有助于在分散剂和催化剂原子之间保持更强的粘合相互作用。 这反过来又增加催化剂组分在整个负载的催化剂中的分散和/或分布。