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1. 发明授权

US06368998B1 Process for preparing catalyst with improved catalytic properties 有权
标题翻译：具有改进催化性能的催化剂制备方法
公开(公告)号：US06368998B1
公开(公告)日：2002-04-09
申请号：US09392523
申请日：1999-09-09
申请人： John Robert Lockemeyer
发明人： John Robert Lockemeyer
IPC分类号： B01J2350
CPC分类号： B01J37/06 , B01J23/50 , C07D301/10
摘要： This invention relates to a process for the preparation of a catalyst having improved properties, the process comprising selecting a carrier, lowering the concentration of ionizable species present on the surface of the carrier, and depositing a catalytically effective amount of one or more catalytically reactive metals on the carrier. The invention further relates to catalyst made from the process.
摘要翻译：本发明涉及制备具有改进性能的催化剂的方法，该方法包括选择载体，降低存在于载体表面上的可离子化物质的浓度，以及沉积催化有效量的一种或多种催化活性金属在载体上。本发明还涉及由该方法制备的催化剂。

2. 发明授权

US06750173B2 Ethylene oxide catalyst 有权
标题翻译：环氧乙烷催化剂
公开(公告)号：US06750173B2
公开(公告)日：2004-06-15
申请号：US10118192
申请日：2002-04-08
申请人： Nabil Rizkalla , Errrol Bornn , Charles W. Zulauf
发明人： Nabil Rizkalla , Errrol Bornn , Charles W. Zulauf
IPC分类号： B01J2350
CPC分类号： B01J37/0207 , B01J21/04 , B01J23/66 , B01J37/0205 , B01J37/06
摘要： The invention relates to an ethylene oxide catalyst comprised of silver deposited on an alumina carrier which has been treated to remove at least 25% of the surface sodium ions and replace the removed sodium ions with up to 10 ppm of lithium ions and to the preparation thereof.
摘要翻译：本发明涉及由沉积在氧化铝载体上的银组成的环氧乙烷催化剂，其被处理以除去至少25％的表面钠离子并用高达10ppm的锂离子代替去除的钠离子及其制备。

3. 发明授权

US06656874B2 Process for preparing catalysts with improved catalytic properties 有权
公开(公告)号：US06656874B2
公开(公告)日：2003-12-02
申请号：US09805317
申请日：2001-03-13
申请人： John Robert Lockemeyer
发明人： John Robert Lockemeyer
IPC分类号： B01J2350
CPC分类号： B01J23/66 , B01J23/50 , B01J37/0201 , B01J37/06 , C07D301/10 , Y02P20/52
摘要： This invention relates to a process for depositing one or more catalytically reactive metals on a carrier, said process comprising selecting a carrier and depositing a catalytically effective amount of one or more catalytically reactive metals on the carrier, the deposition effected by submersing the carrier in an impregnation solution wherein the hydrogen ion activity of the impregnation solution has been lowered. The invention further relates to catalysts made from the process.

4. 发明授权

US06184175B2 Process for preparing silver catalyst 失效
标题翻译：制备银催化剂的方法
公开(公告)号：US06184175B2
公开(公告)日：2001-02-06
申请号：US08195096
申请日：1994-02-14
申请人： Nabil Rizkalla
发明人： Nabil Rizkalla
IPC分类号： B01J2350
CPC分类号： B01J23/50 , B01J23/66 , B01J35/1009 , B01J35/1038 , B01J35/1076 , B01J37/0203 , B01J37/0205 , B01J37/086 , C07D301/10
摘要： An improved silver catalyst for the oxidation of ethylene with molecular oxygen is made by impregnating a porous support with a silver salt of an acid; subjecting the impregnated support to a multi-stage activation in an atmosphere containing less oxygen than air by heating at a first temperature in the range of 150 to 200° C. for less than an hour, heating at a second temperature in the range of from greater than 200° C. to 300° C. for less than one hour, heating at a third temperature in the range of from greater than 300° C. to 400° C. for less than one hour and finally heating at a fourth temperature in the range of from greater than 400° C. to 500° C.; and post impregnating the support with an alkali metal, preferably cesium, from an anhydrous alcohol solution followed by washing with alcohol solvent and rapid drying to produce a finished catalyst having from 1-6×10−3 gew of the alkali metal per kg of catalyst.
摘要翻译：通过用酸的银盐浸渍多孔载体来制备用于用分子氧氧化乙烯的改进的银催化剂; 在150-200℃的第一温度下加热至少于1小时的第二温度，在含氧量比空气少的气氛中进行多级活化，在第二温度范围内加热大于200℃至300℃，持续时间小于1小时，在大于300℃至400℃的第三温度下加热少于1小时，最后在第四温度下加热在大于400℃至500℃的范围内。并用碱金属（优选铯）从无水醇溶液中浸渍载体，然后用醇溶剂洗涤并快速干燥，得到每千克催化剂具有1-6×10 -3 gew碱金属的成品催化剂。

5. 发明授权

US06579825B2 Catalyst composition 有权
公开(公告)号：US06579825B2
公开(公告)日：2003-06-17
申请号：US09992787
申请日：2001-11-06
申请人： John Robert Lockemeyer
发明人： John Robert Lockemeyer
IPC分类号： B01J2350
CPC分类号： B01J21/04 , B01J23/50 , B01J23/58 , B01J23/66 , B01J23/688 , B01J35/002 , B01J35/1009 , B01J35/1038 , B01J35/1076 , B01J37/06 , C07D301/10
摘要： There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.

6. 发明授权

US06511938B1 Alkylene oxide catalysts having enhanced activity and/or stability 失效
标题翻译：具有增强活性和/或稳定性的环氧烷催化剂
公开(公告)号：US06511938B1
公开(公告)日：2003-01-28
申请号：US08619216
申请日：1996-03-21
申请人： Albert Cheng-Yu Liu , Erlind Magnus Thorsteinson , Hwaili Soo , James Herndon McCain , David Michael Minahan
发明人： Albert Cheng-Yu Liu , Erlind Magnus Thorsteinson , Hwaili Soo , James Herndon McCain , David Michael Minahan
IPC分类号： B01J2350
CPC分类号： C07D301/10 , B01J23/8913
摘要： Catalysts for the production of alkylene oxide by the epoxidation of alkene with oxygen comprise a silver-containing support, and a sufficient amount of cobalt component to enhance at least one of activity and/or efficiency and/or stability as compared to a similar catalyst which does not contain cobalt component.
摘要翻译：用于通过用氧环氧化烯烃生产环氧烷的催化剂包含含银载体和足够量的钴组分以增强活性和/或效率和/或稳定性中的至少一种，与类似的催化剂相比，不含钴成分。

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