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4. 发明专利

CH558384A Phenolic antioxidants and stabilisers for polyolefins 未知
公开(公告)号：CH558384A
公开(公告)日：1975-01-31
申请号：CH484274
申请日：1968-08-28
申请人： SANDOZ AG
IPC分类号： C07F9/12 , C07F9/145 , C08K5/52 , C07F9/02 , B01J1/16
摘要： Phenolic antioxidants and stabilisers for polyolefins. M1-. By reacting (I) (in which one X is a hydroxylic group, possibly in the form of a phosphoric ester or acid, and the other X is H or tert. butyl; R1, R2 are H or tert. butyl but at least one is tert. butyl; A is phenyl possibly carrying one or two tert. butyl; (I) contains at least 3 tert. butyl), and (II) a compound capable of producing B-(-Y-B-)n-H (in which B is th residue of (I), n is an integer, Y is one of -S-, -S-S-, -P(or3)-, -P(O)(OR4)-, R5-C(R5)(R6)-where R3, R4 are H, 1-18C alkyl, (methyl) cyclohexyl, C2-6 hydroxyalkyl, alkylene residue of a C2-6 polyol, phenyl, alkylphenyl having a C1-18 alkyl, hydroxyphenyl, phenylene from resorcinol or hydroquinone, (di)hydroxydiphenyl or (di)hydroxydiphenylpropane; R5, R6 are H, C1-4 alkyl or alkylene, or (methyl)cyclohexyl). Generally 0.5 to 1 mole of (II) are used per mole of (I). Specifically (I) is a mixture of isomers from reacting 1 mole of 2- or 4-hydroxy-diphenyl and 1.3 to 2.9 moles of isobutylene, and (II) is from S2Cl2, SOCl2, HCHO and PCl3. The additives have a low volatility and show only slight migration and are added in amts. of 0.05-2% pref. to polypropylene.

6. 发明专利

DE2150787C3 未知
公开(公告)号：DE2150787C3
公开(公告)日：1974-09-05
申请号：DE2150787
申请日：1971-10-12
申请人： SANDOZ AG, BASEL (SCHWEIZ)
发明人： HOFER, KURT, MUENCHENSTEIN , MOESCH, RUDOLF, DR., STEIN
IPC分类号： C07F9/09 , C07F9/141 , C07F9/145 , C07F9/146 , C07F9/165 , C07F9/18 , C08K5/52 , C08K5/5398 , C09K15/32 , C07F9/12 , C09K3/00 , B01J1/16
摘要： 1372042 Stabilizing textiles SANDOZ Ltd 28 Sept 1971 [13 Oct 1970] 45180/71 Heading D1P [Also in Divisions C2 and C3] Textile materials are stabilised against the action of ultraviolet light, visible light, heat or air by applying thereto a compound of formula I where each ring A and/or B may be substituted, m is 1 or 2, n is 1, 2 or 3, each R is hydrogen or optionally substituted alkyl, cycloalkyl or phenyl, X is O or S and each Y is a direct single bond or is alkylene which is bound to B either directly or through O or S and which may be interrupted by one or more oxygen atoms. The textile material may be a polyethylene terephthalate or cellulose acetate material.

7. 发明专利

NL7317614A 未知
公开(公告)号：NL7317614A
公开(公告)日：1974-06-28
申请号：NL7317614
申请日：1973-12-21
IPC分类号： C10M133/16 , C08K5/00 , C08K5/20 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09K3/00 , C09K15/22 , C09K15/24 , C10L1/22 , C10N30/00 , C10N30/08 , C10N30/10 , C08K1/44 , B01J1/16 , C07C103/76

9. 发明专利

FR2196842A1 未知
公开(公告)号：FR2196842A1
公开(公告)日：1974-03-22
申请号：FR7330487
申请日：1973-08-22
申请人： AJINOMOTO KK
IPC分类号： C08K5/00 , C07D217/26 , C08K5/16 , C08K5/3412 , C08K5/3437 , C08L7/00 , C08L21/00 , C09K15/30 , C11B5/00 , B01J1/16 , A23D5/04 , C07D33/00
摘要： Small amounts of isoquinoline derivatives of the formula RETARD OXIDATION OF FATS, OIL, PLASTICS, RUBBERS, AND OTHER ORGANIC COMPOUNDS BY ATMOSPHERIC OXYGEN, WHEN R1 is hydrogen or lower alkyl; R2 is hydrogen, lower alkyl, carboxy or carbo-alkoxy having up to 24 carbon atoms in the alkoxy moiety; R3 is hydrogen, or R2 and R3 jointly constitute a second carbon-to-nitrogen bond; R4 is hydrogen or lower alkyl; and R5 is hydrogen, alkali metal, or alkyl having up to 24 carbon atoms.

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