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    • 4. 发明授权
    • Catalyst for purifying exhaust gases
    • 废气净化催化剂
    • US06217831B1
    • 2001-04-17
    • US08909049
    • 1997-08-11
    • Hiromasa SuzukiNaoto Miyoshi
    • Hiromasa SuzukiNaoto Miyoshi
    • B01D5360
    • B01D53/945B01D2255/2042B01D2255/2073B01D2255/20738B01D2255/20746B01D2255/20753B01D2255/20761B01D2255/91Y02T10/22
    • A catalyst for purifying exhaust gases which aims to efficiently purify NOx in exhaust gases in oxygen-rich atmospheres whose oxygen concentrations are more than required for oxidizing CO and HC, and to attain improved NOx purifying performance after used for a long time. The catalyst includes, being arranged in an order from the upstream to the downstream of exhaust gas flow, a first catalyst 1 in which a noble metal catalyst 12 is loaded on a porous acidic support, a second catalyst 2 in which at least one kind of metal 22 selected from the group consisting of alkali metals, alkaline-earth metals, and rare earth metals is loaded on a porous support, and a third catalyst 3 in which a noble metal catalyst 32 is loaded on a porous support. Since SO2 is not adsorbed or oxidized by the first catalyst 1, SO2 is discharged downstream from the second catalyst 2 without generating sulfate. Therefore, since the NOx absorber is free from degradation even after used for a long time, the second catalyst 2 maintains high NOx adsorbing performance on the fuel-lean side, and the third catalyst 3 reduces NOx which are emitted from the second catalyst 2 on the stoichiometric point or on the fuel-rich side.
    • 一种用于净化废气的催化剂,其目的是有效地净化氧浓度超过氧化CO和HC所需氧浓度的富氧气氛中的废气中的NOx,并且在长时间使用后获得改善的NOx净化性能。 催化剂包括从排气流的上游到下游的顺序排列有第一催化剂1,其中贵金属催化剂12负载在多孔酸性载体上,第二催化剂2,其中至少一种 将由碱金属,碱土金属和稀土类金属组成的组中选择的金属22负载在多孔载体上,在其上添加贵金属催化剂32的第三催化剂3。 由于SO 2不被第一催化剂1吸附或氧化,所以在不产生硫酸盐的情况下将SO 2从第二催化剂2的下游排出。 因此,即使长时间使用NOx吸收剂也不会劣化,所以第二催化剂2在燃料贫乏侧保持高NOx吸附性能,第三催化剂3将从第二催化剂2排出的NOx还原 化学计量点或富燃料侧。