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2. 发明授权

US3845080A Blue anthraquinoid acid dyes 失效
标题翻译：蓝色橙子酸性染发剂
公开(公告)号：US3845080A
公开(公告)日：1974-10-29
申请号：US35772673
申请日：1973-05-07
申请人： BASF AG
发明人： GRASER F
IPC分类号： C09B1/32 , C09B1/34 , C09B1/514 , C09B1/52
CPC分类号： C09B1/52 , C09B1/34 , Y10S8/924
摘要： 1. A BLUE ANTHRAQUINOID ACID DYE OBTAINED BY SULFORATING A COMPOUND OF THE FORMULA IN WHICH

1-(R1-OOC-ALK-NH''-),4-(R-NH-)-ANTHRAQUINONE

ALK IS A LINEAR OR BRANCHED ALKYLENE OF ONE TO THREE CARBON ATOMS; R1 IS HYDROGEN OR ALKYL OR CYCLOALKYL OF ONE TO FIFTEEN CARBON ATOMSS WHICH MAY BEAR ALKOXY OR ALKLTHIO OF ONE TO EIGHT CARBON ATOMS, CHLORINE OR BROMINE AS A SUBSTITUENT, R IS SELECTED FROM THE GROUP CONSISTING OF PHENYL, NAPHTHYL AND

-PHENYLENE-X-C6H5

WHREIN X IS A DIRECT LINKAGE, -O-,-S-,-S O2,-CH2-.-CH2-CH2,-CH,-CH3 OR CH-C-CH3, WHEREIN ONE TO FOUR OF THE AROMATIC HYDROGENS IN R MAY BE REPLACED BY IDENTICAL OR DIFFERENTT ALKYL, ALKOXY OR ALKYLTHIO OF ONE TO FOUR CARBON ATOMS AND HALOGEN AND IN WHICH ONE OR TWO OF THE HYDROGENS IN RINGG B MAY BE REPLACED BY HALOGEN OR HYDROXY.

3. 发明授权

US3957822A Anthraquinone dyestuffs 失效
公开(公告)号：US3957822A
公开(公告)日：1976-05-18
申请号：US480853
申请日：1974-06-19
申请人： Friedrich Wilhelm Krock , Rutger Neeff
发明人： Friedrich Wilhelm Krock , Rutger Neeff
IPC分类号： C09B1/14 , C09B1/52 , C09B1/54 , C07D319/20 , C07D319/22
CPC分类号： C09B1/14 , C09B1/52 , C09B1/545 , Y10S8/917 , Y10S8/924
摘要： Anthraquinone dyestuffs of the formula ##SPC1##WhereinX.sub.1 and X.sub.2 represent hydroxyl or amino,R.sub.1, r.sub.2 and R.sub.3 represent hydrogen or a non-ionic substituent, and two adjacent radicals can also represent a fused saturated or unsaturated ring,Z.sub.1, z.sub.2 and Z.sub.3 represent halogen or especially hydrogen andn represents 0 or especially represents 1Are suitable for dyeing natural and synthetic fibre materials, especially those of polyamides.

4. 发明公开

EP3122756A1 ANORGANISCH-ORGANISCHE HYBRIDVERBINDUNG 有权
公开(公告)号：EP3122756A1
公开(公告)日：2017-02-01
申请号：EP15712797.8
申请日：2015-02-26
申请人： Karlsruher Institut für Technologie , Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. , Georg-August-Universität Stiftung öffentlichen Rechts, Universitätsmedizin
发明人： HECK, Joachim , POSS, Marieke , REICHARDT, Holger , NAPP, Joanna , ALVES, Frauke , STÜHMER, Walter , FELDMANN, Claus
IPC分类号： C07F7/00 , C07F9/58 , C07F9/6503 , C07F9/6506 , C07F9/6509 , C07F9/6533 , C07F9/655 , C07F9/6558 , C07F9/6561 , C07F9/6574 , C07C309/47 , C07C309/50 , C07D401/04 , C07D401/10 , C07D403/10 , C07D407/12 , C07D413/04 , C07H19/00 , C07D417/10 , C07D417/12
CPC分类号： A61K49/0041 , A61K31/185 , A61K31/427 , A61K31/519 , A61K31/546 , A61K31/569 , A61K31/65 , A61K31/661 , A61K31/6615 , A61K31/662 , A61K31/663 , A61K31/665 , A61K31/675 , A61K31/683 , A61K31/7008 , A61K31/704 , A61K31/7056 , A61K31/7068 , A61K31/7076 , A61K38/12 , A61K47/02 , A61K49/0021 , A61K49/0032 , A61K49/0034 , A61K49/0036 , C07C237/26 , C07C309/47 , C07C2603/46 , C07D251/50 , C07D401/04 , C07D401/10 , C07D403/10 , C07D407/12 , C07D413/04 , C07D417/10 , C07D417/12 , C07D493/10 , C07F5/069 , C07F7/006 , C07F9/091 , C07F9/117 , C07F9/12 , C07F9/301 , C07F9/3813 , C07F9/3873 , C07F9/582 , C07F9/65033 , C07F9/65061 , C07F9/650958 , C07F9/65335 , C07F9/65505 , C07F9/65515 , C07F9/65517 , C07F9/65522 , C07F9/65583 , C07F9/65586 , C07F9/6561 , C07F9/65744 , C07F9/65746 , C07J1/0033 , C07J51/00 , C09B1/02 , C09B1/52 , C09B11/08 , C09B19/00 , C09B23/06 , C09B23/086 , C09B29/16 , C09B31/072 , C09B31/08 , C09B35/023 , C09B55/006 , C09B55/009 , C09B57/00 , C09B57/02 , C09B57/08 , C09B62/085 , C09B63/005 , Y02A50/411
摘要： The invention relates to an inorganic-organic hybrid compound as an ion compound, composed of an inorganic cation and an organic anion active substance and optionally, an organic anion fluorescent dye.
摘要翻译：本发明涉及作为离子性化合物的无机 - 有机杂化化合物，由无机阳离子和有机活性成分阴离子组成，也可任选地由有机荧光染料阴离子组成。

5. 发明授权

US3915999A Blue anthraquinoid acid dyes 失效
标题翻译：蓝色蒽醌酸染料
公开(公告)号：US3915999A
公开(公告)日：1975-10-28
申请号：US36007573
申请日：1973-05-14
申请人： BASF AG
发明人： GRASER FRITZ
IPC分类号： C09B1/32 , C09B1/34 , C09B1/514 , C09B1/52 , C09B1/40
CPC分类号： C09B1/34 , C09B1/52
摘要： Anthraquinoid acid dyes of the formula

IN WHICH ALK IS A LINEAR OR BRANCHED ALKYLENE OF 1 TO 3 CARBON ATOMS, R1 and R2 are hydrogen or alkyl of 1 to 12 carbon atoms or cycloalkyl of 5 to 10 carbon atoms (which may bear alkoxy or alkylthio as a substituent), or the group -NR1R2 is a five-, sixor seven-membered saturated heterocyclic ring, R is a divalent mononuclear or binuclear aromatic radical in which 1 to 4 hydrogens may be replaced by alkyl, alkoxy or alkylthio of 1 to 4 carbon atoms and/or halogen, and n is one of the integers 1 and 2. The ring B may bear 1 or 2 chlorine atoms or hydroxy groups. The dyes dye nitrogenous fibers, especially polyamide fibers, clear blue shades having good fastness properties.
摘要翻译：式R 1 ONH-alk-CN ANGLE | PARALLEL OR2 | ONH-R-（SO 3 H）n的蒽醌酸染料，其中R 1是1至3个碳原子的直链或分支的亚烷基，R 1和R 2是氢或烷基的1 至12个碳原子或5至10个碳原子的环烷基（其可以含有烷氧基或烷硫基作为取代基），或者-NR 1 R 2是五，六或七元饱和杂环，R是二价单核或其中1至4个氢可以被1至4个碳原子的烷基，烷氧基或烷硫基取代的双核芳族基团和/或卤素，n是整数1和2之一。环B可以带有1或2个氯原子或羟基。

6. 发明授权

US3682978A Anthraquinone dyestuffs 失效
标题翻译： ANTHRAQUINONE DYESTUFFS
公开(公告)号：US3682978A
公开(公告)日：1972-08-08
申请号：US3682978D
申请日：1969-06-04
申请人： BAYER AG
发明人： MACHATZKE HEINZ , SINGER JOSEF
IPC分类号： C09B1/20 , C09B1/36 , C09B1/52 , C09B1/54 , C09B1/58 , C09B1/56
CPC分类号： C09B1/542 , C09B1/202 , C09B1/36 , C09B1/52 , C09B1/585
摘要： The invention relates to new sulphonic acid group-containing anthraquinone dyestuffs of the general formula

IN WHICH A stands for an optionally substituted alkyl, cycloalkyl, alkylamine, cycloalkylamine, alkyloxy or cycloalkyloxy radical; for an optionally substituted, preferably sulphonated, arylamine or aryloxy radical; for an optionally substituted aralkyl, aralkylamine or aralkyloxy radical preferably sulphonated in the aromatic part; or for an amino group, Y represents a direct linkage or a bridge member, R1 to R5 denote, independently of one another, hydrogen, Halogen (Cl, Br, F), -NO2, -NH2, NH-alkyl, -NH-aryl, -NH-acyl, -Oalkyl, O-aryl, -OH, -S-alkyl, -S-aryl, -SO2NH-alkyl, SO2N(alkyl)2, -SO2NH-aryl, -SO2-alkyl, -SO2-aryl, -aryl. R1 may also stand for a lower alkyl radical, the radicals X denote sulphonic acid groups, p and p'' represent the number 1, 2 or 3, m denotes the number 0, 1 or 2, and n represents the number 0, 1 or 2, the sum total of m and n, in addition to the sulphonic acid groups which may be contained in the radical A, being at least 1.
摘要翻译：本发明涉及通式为A的新的含磺酸基的蒽醌染料，其中A代表任选取代的烷基，环烷基，烷基胺，环烷基胺，烷氧基或环烷氧基; 对于任选取代的，优选磺化的芳基胺或芳氧基; 对于芳族部分中优选磺化的任选取代的芳烷基，芳烷基胺或芳烷氧基; 或对于氨基，Y表示直链或桥连，R1至R5彼此独立地表示氢，卤素（C1，Br，F），-NO2，-NH2，NH-烷基，-NH- 芳基，-NH-酰基，-O-烷基，O-芳基，-OH，-S-烷基，-S-芳基，-SO 2 NH-烷基，-SO 2 N（烷基）2，-SO 2 NH-芳基，-SO 2 - 烷基，-SO 2 - 芳基， - 芳基。

7. 发明授权

US1782747A Process of splitting off sulphogroups from anthraquinone sulphonic acid derivatives 失效
标题翻译：从蒽醌磺酸衍生物中分离出磺基的方法
公开(公告)号：US1782747A
公开(公告)日：1930-11-25
申请号：US10178026
申请日：1926-04-13
申请人： GEN ANILINE WORKS INC
发明人： EMANUEL SCHMIDT ROBERT
IPC分类号： C07C225/34 , C09B1/06 , C09B1/52
CPC分类号： C09B1/06 , C07C225/34 , C09B1/52

9. 发明授权

US3900472A Anthraquinone dyes containing a 2-aryloxy alkoxy carbamate moiety, their intermediates, and a process for their preparation 失效
标题翻译：含有二芳基烷氧基羧酸酯基的蒽醌染料，其中间体及其制备方法
公开(公告)号：US3900472A
公开(公告)日：1975-08-19
申请号：US21010971
申请日：1971-12-20
申请人： GAF CORP
发明人： CHANG CHARLES H
IPC分类号： C07D295/20 , C07D295/205 , C09B1/503 , C09B1/51 , C09B1/514 , C09B1/515 , C09B1/52 , C07D87/46
CPC分类号： C07D295/205 , C07D295/20 , C09B1/503 , C09B1/51 , C09B1/52
摘要： IN WHICH A is a monocyclic, bicyclic or tricyclic aryl radical; B is halogen, lower alkyl, lower alkylmercapto, amino, lower alkylamino, di-lower alkylamino or phenylamino, n is an integer of from 0 to 4; each of R1, R2, R3 and r4 is hydrogen lower alkyl, cycloalkyl or phenyl; alternatively, R3 and R4 taken together with the nitrogen atom to which they are attached may be a 5 or 6 membered heterocyclic ring optionally interrupted by oxygen or another nitrogen atom; X is SO3H or hydrogen; and m is an integer of from 1 to 4. The new compounds in which X is SO3H are prepared by reacting an anthrarufindisulfonic acid of the formula

WITH A NEW INTERMEDIATE ARYLOXY ALKOXY CARBAMATE COMPOUND OF THE FORMULA

in the presence of boric and concentrated sulfuric acids, treating the reaction mixture with ammonium hydroxide, and subsequent acidification. Compounds in which X is hydrogen are prepared from compounds of Formula I (X SO3H) by treatment with sodium hydrosulfide. The new anthraquinone compounds of this invention are useful for dyeing synthetic fibers such as polyester, polyamide, acetate or triacetate.
New dyestuff compounds having the structure

10. 发明授权

US2333402A Ent ofmge 失效
公开(公告)号：US2333402A
公开(公告)日：1943-11-02
申请号：US2333402D
CPC分类号： C09B1/52 , C09B1/24 , C09B1/503

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