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    • 4. 发明授权
    • Crosslinkable composition of matter III
    • 物质的可交联组成III
    • US4508879A
    • 1985-04-02
    • US458119
    • 1983-01-14
    • Joseph W. Holubka
    • Joseph W. Holubka
    • C08F283/00C08G18/00C08G18/64C08G18/67C08G18/81C08G18/83C08G59/14C09D5/44C09D175/00C08L63/00
    • C09D5/4419C08G18/643C08G18/8158C08G18/8183C08G18/831C08G59/1477
    • A novel composition of matter is provided, which comprises certain polydiene-functionalized polyisocyanate oligomer and certain polydieneophile-functionalized epoxy-amine adduct, which polyisocyanate oligomer and epoxy-amine adduct are reactive at elevated cure temperature. The polydieneophile-functionalized epoxy-amine adduct comprises the reaction product of certain polyhydroxy functional epoxy-amine reactant with dieneophile functional mono-isocyanate reactant. The polydiene-functionalized polyisocyanate oligomer comprises the reaction product of polyisocyanate reactant, preferably a triisocyanate, with approximately equal molar equivalent amount of monohydroxy diene reactant or monoamino diene reactant or like isocyanate-reactive diene reactant. The crosslinkable composition of matter is useful in coating and other applications, especially cathodic electrocoating applications.
    • 提供了一种新的物质组合物,其包含某些聚二烯官能化的多异氰酸酯低聚物和某些聚亲合子官能化的环氧胺加合物,该多异氰酸酯低聚物和环氧胺加合物在升高的固化温度下是反应性的。 聚亲合子官能化的环氧 - 胺加合物包括某些多羟基官能的环氧胺反应物与双亲功能单异氰酸酯反应物的反应产物。 聚二烯官能化多异氰酸酯低聚物包含多异氰酸酯反应物,优选三异氰酸酯与大约相等摩尔当量的单羟基二烯反应物或单氨基二烯反应物或类似异氰酸酯反应性二烯反应物的反应产物。 物质的可交联组合物可用于涂覆和其他应用,特别是阴极电涂层应用。
    • 8. 发明授权
    • Polyimide foam precursor and its use in reinforcing open-cell materials
    • 聚酰亚胺泡沫前体及其在增强开孔材料中的应用
    • US4824874A
    • 1989-04-25
    • US905718
    • 1986-09-09
    • Kyu W. Lee
    • Kyu W. Lee
    • C08G18/34C08G18/67C08G18/81C08J9/02C08J9/00
    • C08J9/02C08G18/346C08G18/674C08G18/6765C08G18/8183B29K2079/00C08J2379/08
    • Open-cell structures are filled with polyimide foam formed in place by the use of a foam precursor in powdered form comprised of a combination of (a) the reaction product of an excess of organic polyisocyanate and a member selected from the group consisting of furfuryl alcohol and condensation products thereof, and (b) an organic polycarboxylic compound containing two carboxylic anhydride groups. The precursor is prepared by combining the species under conditions which favor the reaction of the furfuryl alcohol with the polyisocyanate, but not the polyimide-forming reaction. The polyimide-forming reaction itself is then performed by adding preselected amounts of the powdered precursor, depending on the desired ultimate density of the foam, to each cell of the open-cell structure, then heating to initiate the polyimide reaction, and permitting the carbon dioxide generated by the reaction to escape while confining the resulting foam to the cells.
    • 开孔结构填充有聚酰亚胺泡沫,通过使用粉末形式的泡沫前体填充形成的聚酰亚胺泡沫,粉末形式由以下组合组成:(a)过量有机多异氰酸酯的反应产物和选自糠醇 及其缩合产物,和(b)含有两个羧酸酐基团的有机多元羧酸化合物。 通过在有利于糠醇与多异氰酸酯的反应的条件下组合物种制备前体,而不是聚酰亚胺形成反应。 然后通过将预定量的粉末前体(取决于泡沫的期望的最终密度)加入到开孔结构的每个电池中,然后加热以引发聚酰亚胺反应,并允许碳 通过反应产生的二氧化碳逸出,同时将所得泡沫限制在细胞中。
    • 9. 发明授权
    • Crosslinkable composition of matter - II
    • 可交联的物质组成 - II
    • US4513125A
    • 1985-04-23
    • US456068
    • 1983-01-06
    • Joseph W. Holubka
    • Joseph W. Holubka
    • C08F283/00C08G18/00C08G18/58C08G18/64C08G18/81C08G18/83C09D5/44C09D175/00C08G59/14
    • C09D5/4434C08G18/6415C08G18/8158C08G18/8183C08G18/831
    • A novel composition of matter is provided, which comprises certain polydiene-functionalized epoxy-amine adduct and certain polydieneophile-functionalized polyisocyanate oligomer, which epoxy-amine adduct and polyisocyanate oligomer are co-reactive at elevated cure temperature. The polydiene-functionalized epoxy-amine adduct comprises the reaction product of certain polyhydroxy functional epoxy-amine reactant with diene-functional mono-isocyanate reactant. The polydieneophile-functionalized polyisocyanate oligomer comprises the reaction product of polyisocyanate reactant, preferably a triisocyanate, with approximately equal molar equivalent amount of monohydroxy dieneophile reactant or monoamino dieneophile reactant or like isocyanate-reactive dieneophile reactant. The crosslinkable composition of matter is useful in coating and other applications, especially cathodic electrocoating applications.
    • 提供了一种新的物质组合物,其包含某些聚二烯官能化的环氧 - 胺加合物和某些聚亲合物官能化的多异氰酸酯低聚物,该环氧 - 胺加合物和聚异氰酸酯低聚物在升高的固化温度下是共反应的。 聚二烯官能化的环氧 - 胺加合物包括某些多羟基官能的环氧胺反应物与二烯官能的单异氰酸酯反应物的反应产物。 聚二烯丙酯官能化的多异氰酸酯低聚物包含多异氰酸酯反应物,优选三异氰酸酯与近似等摩尔当量的单羟基亲本亲油反应物或单氨基亲本亲油反应物或类似异氰酸酯反应性亲本亲油反应物的反应产物。 物质的可交联组合物可用于涂覆和其它应用,特别是阴极电涂层应用。