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1. 发明授权

US3364190A Process for polymerizing propylene to syndiotactic polypropylene 失效
标题翻译：将丙烯聚合成间同立构聚丙烯的方法
公开(公告)号：US3364190A
公开(公告)日：1968-01-16
申请号：US36298964
申请日：1964-04-27
申请人： STANDARD OIL CO
发明人： EMRICK DONALD D
IPC分类号： C08F10/00
CPC分类号： C08F110/06 , C08F4/6297 , C08F4/655 , C08F2500/12

2. 发明授权

EP0149558B1 High efficiency polymerization catalyst component for use in the polymerization of propylene and higher alpha-olefins 有权
标题翻译：高效聚合催化剂组分用于丙烯和高级α-烯烃的聚合反应
公开(公告)号：EP0149558B1
公开(公告)日：1989-03-15
申请号：EP85300298.8
申请日：1985-01-16
申请人： EXXON RESEARCH AND ENGINEERING COMPANY
发明人： Huff, Terrence , Poirot, Eugene Edmond
IPC分类号： C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , C08F4/642 , C08F4/6097 , C08F4/6297

3. 发明公开

EP0149558A2 High efficiency polymerization catalyst component for use in the polymerization of propylene and higher alpha-olefins 有权
标题翻译：高度有效的催化剂成分丙烯和高级α-烯烃的聚合中是有用的。
公开(公告)号：EP0149558A2
公开(公告)日：1985-07-24
申请号：EP85300298.8
申请日：1985-01-16
申请人： EXXON RESEARCH AND ENGINEERING COMPANY
发明人： Huff, Terrence , Poirot, Eugene Edmond
IPC分类号： C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , C08F4/642 , C08F4/6097 , C08F4/6297
摘要： An aliphatic hydrocarbon soluble mixed aluminum hydrocarbyl-Lewis base co-catalyst composition comprising (i) at least two different classes of aluminum hydrocarbyls the first being an aluminum hydrocarbyl halide, the second being an aluminum hydrocarbyl hydride and/or aluminum trialkyl and (ii) at least one Lewis base represented by the formula:

wherein each Y can be -OR', -NR 2 and R' with the proviso that at least two be -OR' or -NR 2 , Z is an alkylene radical forming a 5 or 6 membered ring with the carbonyldioxy group or Z is alkyl substituted alkylene group wherein the alkyl radical can have from 1 to 8 carbon atoms, R is an aryl, allyl or alkyl group having from 1 to 20 carbon atoms and R' is an alkyl, cycloalkyl, aryl or aralkyl radical having from 1 to 20 carbon atoms.
The co-catalyst is employed with a titanium halide catalyst for the polymerization of olefins to obtain a advantageous balance of catalytic activity and polymer product stereoregularity.
摘要翻译：脂族烃可溶性混合烃基铝 - 路易斯碱助催化剂组合物，其包含（i）至少两种不同类别的烃基铝首先是一个铝烃基卤化物，第二个是一个铝烃基氢化物和/或三烷基铝和（ⅱ）至少一种路易斯碱由下式表示：... ... worin每个Y可以是-OR分钟，-NR 2和R分钟，其条件没有至少两个是-OR分钟或-NR 2，Z是亚烷基的自由基形成与carbonyldioxy团或Z是5或6元环烷基取代的亚烷基worin所述烷基可以具有1至8个碳原子，R是具有1至20个碳原子，R的芳基，烯丙基或烷基“被的烷基，环烷基，芳基或芳烷基为1〜20个碳原子具有。 ... 助催化剂，采用与卤化钛催化剂烯烃的聚合，以获得催化活性和聚合物产物立构规整性的有利平衡。

4. 发明公开

EP0149558A3 High efficiency polymerization catalyst component for use in the polymerization of propylene and higher alpha-olefins 有权
标题翻译：用于丙烯和高级烯丙基聚合的高效聚合催化剂组分
公开(公告)号：EP0149558A3
公开(公告)日：1985-08-14
申请号：EP85300298
申请日：1985-01-16
申请人： EXXON RESEARCH AND ENGINEERING COMPANY
发明人： Huff, Terrence , Poirot, Eugene Edmond
IPC分类号： C08F10/00 , C08F04/64
CPC分类号： C08F10/00 , C08F4/642 , C08F4/6097 , C08F4/6297
摘要： An aliphatic hydrocarbon soluble mixed aluminum hydrocarbyl-Lewis base co-catalyst composition comprising (i) at least two different classes of aluminum hydrocarbyls the first being an aluminum hydrocarbyl halide, the second being an aluminum hydrocarbyl hydride and/or aluminum trialkyl and (ii) at least one Lewis base represented by the formula:
wherein each Y can be -OR', -NR 2 and R' with the proviso that at least two be -OR' or -NR 2 , Z is an alkylene radical forming a 5 or 6 membered ring with the carbonyldioxy group or Z is alkyl substituted alkylene group wherein the alkyl radical can have from 1 to 8 carbon atoms, R is an aryl, allyl or alkyl group having from 1 to 20 carbon atoms and R' is an alkyl, cycloalkyl, aryl or aralkyl radical having from 1 to 20 carbon atoms. The co-catalyst is employed with a titanium halide catalyst for the polymerization of olefins to obtain a advantageous balance of catalytic activity and polymer product stereoregularity.

5. 发明申请

US20180134818A1 METHOD FOR PREPARING A SOLUTION OF A RARE-EARTH ALKYL PHOSPHATE 审中-公开
公开(公告)号：US20180134818A1
公开(公告)日：2018-05-17
申请号：US15805923
申请日：2017-11-07
申请人： Korea Kumho Petrochemical Co., Ltd.
发明人： Hyung Jae LEE , Ji Hyun HEO
IPC分类号： C08F4/68 , C08F4/629
CPC分类号： C08F4/68 , C01F17/00 , C08F4/12 , C08F4/6297
摘要： Disclosed is a method of preparing a rare-earth alkyl phosphate solution, the method including step (a) of preparing an alkyl phosphate amine salt solution by reacting an organic amine with an alkyl phosphate in a first solvent; step (b) of preparing a rare-earth metal salt solution by reacting a rare-earth metal oxide with an acid in the second solvent; and step (c) of mixing and reacting the alkyl phosphate amine salt solution with the rare-earth metal salt solution.

6. 发明授权

US3222337A Monosubstituted aluminum dihalide catalysts for olefin polymerization 失效
标题翻译：用于烯烃聚合的单取代二卤化铝催化剂
公开(公告)号：US3222337A
公开(公告)日：1965-12-07
申请号：US38870464
申请日：1964-08-10
申请人： EASTMAN KODAK CO
发明人： COOVER JR HARRY W
IPC分类号： C08F10/00 , C08F110/06
CPC分类号： C08F110/06 , C08F10/00 , C08F4/626 , C08F4/629 , C08F4/6497 , C08F4/6297 , C08F4/6295 , C08F4/6498 , C08F4/6495

7. 发明授权

US3026310A Three-component catalyst containing polymeric methyl halide-metal reaction product and titanium compound for olefin polymerization 失效
标题翻译：含有聚合物甲基卤化物 - 金属反应产物和用于烯烃聚合的钛化合物的三组分催化剂
公开(公告)号：US3026310A
公开(公告)日：1962-03-20
申请号：US72491858
申请日：1958-03-31
申请人： EASTMAN KODAK CO
发明人： SHEARER JR NEWTON H , COOVER JR HARRY W
IPC分类号： C08F4/16 , C08F4/629 , C08F4/64 , C08F10/00 , C08F12/08 , C08F36/04 , C08F110/06 , C08F110/14 , C08G79/14
CPC分类号： C08G79/14 , C08F10/00 , C08F12/08 , C08F36/04 , C08F110/06 , C08F110/14 , C08F4/629 , C08F4/6498 , C08F4/6495 , C08F4/6297 , C08F4/6497 , C08F4/6295 , C08F2500/26 , C08F4/68 , C08F4/69 , C08F4/695 , C08F4/649

8. 发明授权

US3205208A Three-component organometallic-transition metal halide catalysts and olefin polymerization 失效
标题翻译：三组分有机金属 - 过渡金属卤化物催化剂和烯烃聚合
公开(公告)号：US3205208A
公开(公告)日：1965-09-07
申请号：US6499960
申请日：1960-10-26
申请人： EASTMAN KODAK CO
发明人： COOVER JR HARRY W , JOYNER FREDERICK B
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/6295 , C08F4/6297

9. 发明授权

US3088942A Monosubstituted aluminum dihalide catalysts for olefin polymerization 失效
标题翻译：用于烯烃聚合的单取代二卤化铝催化剂
公开(公告)号：US3088942A
公开(公告)日：1963-05-07
申请号：US72491158
申请日：1958-03-31
申请人： EASTMAN KODAK CO
发明人： COOVER JR HARRY W
IPC分类号： C08F12/08 , C08F36/04 , C08F110/06 , C08F110/14
CPC分类号： C08F12/08 , C08F110/06 , C08F110/14 , C08F4/6495 , C08F4/6498 , C08F4/6295 , C08F4/6297 , C08F4/6497 , C08F2500/26

10. 发明授权

US2956991A Three-component alkyl aluminum halide catalysts for olefin polymerization and olefin polymerization process therewith 失效
标题翻译：用于烯烃聚合和烯烃聚合方法的三组分烷基卤化铝催化剂
公开(公告)号：US2956991A
公开(公告)日：1960-10-18
申请号：US72491058
申请日：1958-03-31
申请人： EASTMAN KODAK CO
发明人： COOVER JR HARRY W , JOYNER FREDERICK B
IPC分类号： C08F4/16 , C08F4/629 , C08F4/64 , C08F10/00 , C08F12/08 , C08F36/04 , C08F110/06 , C08F110/14 , C08G79/14
CPC分类号： C08G79/14 , C08F10/00 , C08F12/08 , C08F36/04 , C08F110/06 , C08F110/14 , C08F4/629 , C08F4/6498 , C08F4/6495 , C08F4/6297 , C08F4/6497 , C08F4/6295 , C08F2500/26 , C08F4/68 , C08F4/69 , C08F4/695 , C08F4/649

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