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1. 发明公开

CN1537088A 转移氢化方法和催化剂无效转让
公开(公告)号：CN1537088A
公开(公告)日：2004-10-13
申请号：CN01822470.9
申请日：2001-11-29
申请人：艾夫西亚有限公司
发明人： J·M·J·威廉斯 , C·布伯特 , S·M·布朗 , A·J·布拉克
IPC分类号： C07B53/00 , C07C29/143 , C07C33/18 , C07C33/20 , C07C33/46 , C07C35/32 , C07C41/26 , C07C43/178 , C07M7/00 , B01J31/22 , C07C311/18 , C07C311/20
CPC分类号： B01J31/226 , B01J31/1805 , B01J31/2217 , B01J31/2295 , B01J31/28 , B01J2231/643 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2540/22 , B01J2540/325 , B01J2540/34 , B01J2540/345 , C07B53/00 , C07B2200/07 , C07C29/143 , C07C311/18 , C07C311/20 , C07C2602/08 , C07D339/04 , C07F17/02 , C07C33/46 , C07C35/32 , C07C33/18 , C07C33/22
摘要：提供了一种催化转移氢化方法。该方法中所用的催化剂是一种金属烃基络合物，配位在一定的二配位基配体上，后者被至少一个下列基团所取代：任选地取代的磺化烃基、磺化的全卤代烃基、或任选地取代的磺化杂环基。优选的金属包括铑、钌和铱。优选的二配位基配体有二胺类和氨基醇类，特别是含有手性中心的那些。氢给体有益地是一种仲醇或者三乙胺和甲酸的混合物。这种方法可用于酮类和亚胺类的转移氢化，这些酮类和亚胺类最好是前手性的。也提供了用于这一方法中的催化剂。

2. 发明公开

CN1257468A 转移氢化方法和催化剂失效转让
公开(公告)号：CN1257468A
公开(公告)日：2000-06-21
申请号：CN98805303.9
申请日：1998-03-20
申请人：艾夫西亚有限公司
发明人： A·J·布莱克 , B·J·梅勒
IPC分类号： C07B31/00 , C07C29/143 , C07C209/52 , C07F17/00 , B01J31/22
CPC分类号： B01J31/2243 , B01J31/1805 , B01J31/2295 , B01J2231/643 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2540/34 , B01J2540/345 , C07B31/00 , C07C29/143 , C07C2602/28 , C07F15/008 , C07C33/22 , C07C33/46 , C07C35/36
摘要：本发明提供一种催化转移氢化的方法。在该方法中使用的催化剂是一种与已定义的二齿配位体配价的金属环戊二烯基配合物。优选的金属包括铑、钌和铱。优选的二齿配位体为二胺和氨基醇,特别是那些包括手性中心的二胺和氨基醇。氢给体最好为一种仲醇或一种三乙胺与甲酸的混合物。该方法可用于转移氢化优选为前手性的酮和亚胺。本发明也提供了用于这种方法中的催化剂。

3. 发明授权

CN1130324C 转移氢化方法和催化剂失效转让
公开(公告)号：CN1130324C
公开(公告)日：2003-12-10
申请号：CN98805303.9
申请日：1998-03-20
申请人：艾夫西亚有限公司
发明人： A·J·布莱克 , B·J·梅勒
IPC分类号： C07B31/00 , C07C29/143 , C07C209/52 , C07F17/00 , B01J31/22
CPC分类号： B01J31/2243 , B01J31/1805 , B01J31/2295 , B01J2231/643 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2540/34 , B01J2540/345 , C07B31/00 , C07C29/143 , C07C2602/28 , C07F15/008 , C07C33/22 , C07C33/46 , C07C35/36
摘要：本发明提供一种催化转移氢化的方法。在该方法中使用的催化剂是一种与已定义的二齿配位体配价的金属环戊二烯基配合物。优选的金属包括铑、钌和铱。优选的二齿配位体为二胺和氨基醇，特别是那些包括手性中心的二胺和氨基醇。氢给体最好为一种仲醇或一种三乙胺与甲酸的混合物。该方法可用于转移氢化优选为前手性的酮和亚胺。本发明也提供了用于这种方法中的催化剂。

4. 发明授权

US08735522B2 Gold-polymer nanostructure-immobilized scandium catalyst and its use 有权
标题翻译：金聚合物纳米结构固定钪催化剂及其用途
公开(公告)号：US08735522B2
公开(公告)日：2014-05-27
申请号：US13580312
申请日：2011-02-16
申请人： Shu Kobayashi , Hiroyuki Miyamura
发明人： Shu Kobayashi , Hiroyuki Miyamura
IPC分类号： C08F12/30 , C08K3/10
CPC分类号： C07D455/04 , B01J23/52 , B01J31/0227 , B01J31/0228 , B01J31/165 , B01J31/226 , B01J35/0013 , B01J2231/326 , B01J2231/342 , B01J2231/346 , B01J2231/4205 , B01J2531/0222 , B01J2531/18 , B01J2531/35 , B01J2540/325 , B01J2540/345 , C07C45/75 , C07D491/22 , C07C49/82
摘要： The present invention provides a Scandium catalyst that can be used in water or water-soluble organic solvent with no leaching of Scandium. Provided is a gold-polymer nanostructure-immobilized Scandium catalyst, which is formed by preparing, in liquid phase, a mixture comprising gold clusters with from 1 to 50 nm of diameter, disulfide monomer, sulfonic acid salt of disulfide and Lewis acid metal compound represented by ScY3, wherein Y is OSO2CF3 etc., and polymerizing the mixture in the presence of a radical polymerization initiator, wherein the disulfide monomer is represented by the formula below: CH2═CH—R1—S—S—R1—CH═CH2 wherein R1 represents a divalent hydrocarbon, which may contain an ether bond, and the sulfonic acid salt of disulfide is represented by the formula below: MO3S—R2—S—S—R2—SO3M wherein R2 represents a divalent hydrocarbon, which may contain an ether bond, and M represents an alkali metal. This catalyst is useful as a catalyst for aldol reactions, cyanolation reactions, allylation reactions, Michael reactions, Mannich reactions, Diels Alder reactions and Friedel Crafts reactions in water or water-soluble organic solvent.
摘要翻译：本发明提供了可用于水或水溶性有机溶剂中的钪催化剂，而不会浸出钪。提供了一种金 - 聚合物纳米结构固定的钪催化剂，其通过在液相中制备包含直径为1至50nm的金簇的混合物，二硫化物单体，二硫化物磺酸盐和路易斯酸金属化合物其中Y是OSO 2 CF 3等，并且在自由基聚合引发剂存在下聚合混合物，其中二硫化物单体由下式表示：CH 2 = CH-R 1 -S-S-R 1 -CH = CH 2其中 R1表示可以含有醚键的二价烃，二硫化物的磺酸盐由下式表示：MO 3 S-R 2 -S-S-R 2 -SO 3 M其中R 2表示可以含有醚的二价烃键，M表示碱金属。该催化剂可用作醛醇反应，硅烷醇化反应，烯丙基化反应，迈克尔反应，曼尼希反应，狄尔斯阿尔德反应和弗里德尔·卡夫在水或水溶性有机溶剂中的反应的催化剂。

5. 发明申请

US20020156282A1 Transfer hydrogenation process and catalyst 有权
公开(公告)号：US20020156282A1
公开(公告)日：2002-10-24
申请号：US10083391
申请日：2002-02-27
申请人： Avecia Limited
发明人： Andrew John Blacker , Ben James Mellor
IPC分类号： C07D211/06 , C07C319/02 , C07C29/52 , C07C029/136
CPC分类号： B01J31/2243 , B01J31/1805 , B01J31/2295 , B01J2231/643 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2540/34 , B01J2540/345 , C07B31/00 , C07C29/143 , C07C2602/28 , C07F15/008 , C07C33/22 , C07C33/46 , C07C35/36
摘要： A catalytic transfer hydrogenation process is provided. The catalyst employed in the process is a metal cyclopentadienyl complex which is coordinated to defined bidentate ligands. Preferred metals include rhodium, ruthenium and iridium. Preferred bidentate ligands are diamines and aminoalcohols, particularly those comprising chiral centers. The hydrogen donor is advantageously a secondary alcohol or a mixture of triethylamine and formic acid. The process can be employed to transfer hydrogenate ketones and imines, which are preferably prochiral. Catalysts for use in such a process are also provided.

6. 发明授权

US07250526B2 Transfer hydrogenation process and catalyst 失效
标题翻译：转移氢化工艺和催化剂
公开(公告)号：US07250526B2
公开(公告)日：2007-07-31
申请号：US10433351
申请日：2001-11-29
申请人： Andrew John Blacker , Christian Bubert , Jonathan Michael Jeremy Williams , Stephen Martin Brown
发明人： Andrew John Blacker , Christian Bubert , Jonathan Michael Jeremy Williams , Stephen Martin Brown
IPC分类号： C07F17/02 , C07F15/06 , C07C311/16 , C07C29/14 , C07C29/143 , C07B53/00 , C07B43/04 , C07D217/10 , C07D209/08
CPC分类号： B01J31/226 , B01J31/1805 , B01J31/2217 , B01J31/2295 , B01J31/28 , B01J2231/643 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2540/22 , B01J2540/325 , B01J2540/34 , B01J2540/345 , C07B53/00 , C07B2200/07 , C07C29/143 , C07C311/18 , C07C311/20 , C07C2602/08 , C07D339/04 , C07F17/02 , C07C33/46 , C07C35/32 , C07C33/18 , C07C33/22
摘要： A catalytic transfer hydrogenation process is provided. The catalyst employed in the process is a metal hydrocarbyl complex which is coordinated to defined bidentate ligands substituted with at least one group selected from an optionally substituted sulphonated hydrocarbyl group, a sulphonated perhalogenated hydrocarbyl group, or an optionally substituted sulphonated heterocyclyl group. Preferred metals include rhodium, ruthenium and iridium. Preferred bidentate ligands are diamines and aminoalcohols, particularly those comprising chiral centres. The hydrogen donor is advantageously a secondary alcohol or a mixture of triethylamine and formic acid. The process can be employed to transfer hydrogenate ketones and imines, which are preferably prochiral. Catalysts for use in such a process are also provided.
摘要翻译：提供催化转移氢化方法。在该方法中使用的催化剂是金属烃基络合物，其与由至少一个选自任选取代的磺化烃基，磺化的全卤代烃基或任选取代的磺化杂环基的基团配位的二齿配体配位。优选的金属包括铑，钌和铱。优选的二齿配体是二胺和氨基醇，特别是包含手性中心的那些。氢供体有利地是仲醇或三乙胺和甲酸的混合物。该方法可用于转移氢化酮和亚胺，其优选是前手性的。还提供了用于这种方法的催化剂。

7. 发明授权

US06545188B2 Transfer hydrogenation process and catalyst 有权
公开(公告)号：US06545188B2
公开(公告)日：2003-04-08
申请号：US10083391
申请日：2002-02-27
申请人： Andrew John Blacker , Ben James Mellor
发明人： Andrew John Blacker , Ben James Mellor
IPC分类号： C07C2914
CPC分类号： B01J31/2243 , B01J31/1805 , B01J31/2295 , B01J2231/643 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2540/34 , B01J2540/345 , C07B31/00 , C07C29/143 , C07C2602/28 , C07F15/008 , C07C33/22 , C07C33/46 , C07C35/36
摘要： A catalytic transfer hydrogenation process is provided. The catalyst employed in the process is a metal cyclopentadienyl complex which is coordinated to defined bidentate ligands. Preferred metals include rhodium, ruthenium and iridium. Preferred bidentate ligands are diamines and aminoalcohols, particularly those comprising chiral centers. The hydrogen donor is advantageously a secondary alcohol or a mixture of triethylamine and formic acid. The process can be employed to transfer hydrogenate ketones and imines, which are preferably prochiral. Catalysts for use in such a process are also provided.

8. 发明公开

EP2545991A1 GOLD POLYMER NANO-STRUCTURE-SUPPORTED SCANDIUM CATALYST AND USE OF THE SAME 有权
标题翻译：金聚合物纳米结构支撑钪催化剂及其应用
公开(公告)号：EP2545991A1
公开(公告)日：2013-01-16
申请号：EP11753144.2
申请日：2011-02-16
申请人： Japan Science and Technology Agency
发明人： KOBAYASHI Shu , MIYAMURA Hiroyuki
IPC分类号： B01J23/66 , B01J35/02 , B01J37/04 , C07C45/75 , C07C49/82 , C07D455/04 , C07B61/00
CPC分类号： C07D455/04 , B01J23/52 , B01J31/0227 , B01J31/0228 , B01J31/165 , B01J31/226 , B01J35/0013 , B01J2231/326 , B01J2231/342 , B01J2231/346 , B01J2231/4205 , B01J2531/0222 , B01J2531/18 , B01J2531/35 , B01J2540/325 , B01J2540/345 , C07C45/75 , C07D491/22 , C07C49/82
摘要： The present invention provides a Scandium catalyst that can be used in water or water-soluble organic solvent with no leaching of Scandium. Provided is a gold-polymer nanostructure-immobilized Scandium catalyst, which is formed by preparing, in liquid phase, a mixture comprising gold clusters with from 1 to 50 nm of diameter, disulfide monomer, sulfonic acid salt of disulfide and Lewis acid metal compound represented by ScY 3 , wherein Y is OSO 2 CF 3 etc., and polymerizing the mixture in the presence of a radical polymerization initiator, wherein the disulfide monomer is represented by the formula below:

CH 2 =CH-R 1 -S-S-R 1 -CH=CH 2

wherein R 1 represents a divalent hydrocarbon, which may contain an ether bond, and the sulfonic acid salt of disulfide is represented by the formula below:

MO 3 S-R 2 -S-S-R 2 -SO 3 M

wherein R 2 represents a divalent hydrocarbon, which may contain an ether bond, and M represents an alkali metal.
This catalyst is useful as a catalyst for aldol reactions, cyanolation reactions, allylation reactions, Michael reactions, Mannich reactions, Diels Alder reactions and Friedel Crafts reactions in water or water-soluble organic solvent.
摘要翻译：本发明提供了一种可用于水或水溶性有机溶剂而不浸出钪的钪催化剂。本发明提供一种固定有金 - 聚合物纳米结构的钪催化剂，其通过在液相中制备包含直径为1-50nm的金簇，二硫化物单体，二硫化物的磺酸盐和路易斯酸金属化合物的混合物其中Y是OSO 2 CF 3等，并且在自由基聚合引发剂存在下聚合该混合物，其中二硫化物单体由下式表示：CH 2 = CH-R 1 -SS-R 1 -CH = CH 2其中R 1代表可含有醚键的二价烃和二硫化物的磺酸盐由下式表示：MO3S-R2-SS-R2-SO3M其中R2表示二价烃，其可含有醚键，且M 代表碱金属。该催化剂可用作在水或水溶性有机溶剂中用于醇醛缩合反应，氰化反应，烯丙基化反应，迈克尔反应，曼尼希反应，狄尔斯阿尔德反应和Friedel Crafts反应的催化剂。

9. 发明申请

US20130059999A1 GOLD-POLYMER NANOSTRUCTURE-IMMOBILIZED SCANDIUM CATALYST AND ITS USE 有权
标题翻译：金聚合物纳米结构固体超临界催化剂及其用途
公开(公告)号：US20130059999A1
公开(公告)日：2013-03-07
申请号：US13580312
申请日：2011-02-16
申请人： Shu Kobayashi , Hiroyuki Miyamura
发明人： Shu Kobayashi , Hiroyuki Miyamura
IPC分类号： C08F28/02 , C07C45/00
CPC分类号： C07D455/04 , B01J23/52 , B01J31/0227 , B01J31/0228 , B01J31/165 , B01J31/226 , B01J35/0013 , B01J2231/326 , B01J2231/342 , B01J2231/346 , B01J2231/4205 , B01J2531/0222 , B01J2531/18 , B01J2531/35 , B01J2540/325 , B01J2540/345 , C07C45/75 , C07D491/22 , C07C49/82
摘要： The present invention provides a Scandium catalyst that can be used in water or water-soluble organic solvent with no leaching of Scandium. Provided is a gold-polymer nanostructure-immobilized Scandium catalyst, which is formed by preparing, in liquid phase, a mixture comprising gold clusters with from 1 to 50 nm of diameter, disulfide monomer, sulfonic acid salt of disulfide and Lewis acid metal compound represented by ScY3, wherein Y is OSO2CF3 etc., and polymerizing the mixture in the presence of a radical polymerization initiator, wherein the disulfide monomer is represented by the formula below: CH2═CH—R1—S—S—R1—CH═CH2 wherein R1 represents a divalent hydrocarbon, which may contain an ether bond, and the sulfonic acid salt of disulfide is represented by the formula below: MO3S—R2—S—S—R2—SO3M wherein R2 represents a divalent hydrocarbon, which may contain an ether bond, and M represents an alkali metal. This catalyst is useful as a catalyst for aldol reactions, cyanolation reactions, allylation reactions, Michael reactions, Mannich reactions, Diels Alder reactions and Friedel Crafts reactions in water or water-soluble organic solvent.
摘要翻译：本发明提供了可用于水或水溶性有机溶剂中的钪催化剂，而不会浸出钪。提供了一种金 - 聚合物纳米结构固定的钪催化剂，其通过在液相中制备包含直径为1至50nm的金簇的混合物，二硫化物单体，二硫化物磺酸盐和路易斯酸金属化合物其中Y是OSO 2 CF 3等，并且在自由基聚合引发剂存在下聚合混合物，其中二硫化物单体由下式表示：CH 2 = CH-R 1 -S-S-R 1 -CH = CH 2其中 R1表示可以含有醚键的二价烃，二硫化物的磺酸盐由下式表示：MO 3 S-R 2 -S-S-R 2 -SO 3 M其中R 2表示可以含有醚的二价烃键，M表示碱金属。该催化剂可用作醛醇反应，硅烷醇化反应，烯丙基化反应，迈克尔反应，曼尼希反应，狄尔斯阿尔德反应和弗里德尔·卡夫在水或水溶性有机溶剂中的反应的催化剂。

10. 发明申请

US20040102313A1 Transfer hydrogenation process and catalyst 失效
标题翻译：转移氢化工艺和催化剂
公开(公告)号：US20040102313A1
公开(公告)日：2004-05-27
申请号：US10433351
申请日：2003-10-15
发明人： Andrew John Blacker , Christian Bubert , Jonathan Michael Jeremy Williams , Stephen Martin Brown
IPC分类号： C07F015/00 , B01J031/00
CPC分类号： B01J31/226 , B01J31/1805 , B01J31/2217 , B01J31/2295 , B01J31/28 , B01J2231/643 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2540/22 , B01J2540/325 , B01J2540/34 , B01J2540/345 , C07B53/00 , C07B2200/07 , C07C29/143 , C07C311/18 , C07C311/20 , C07C2602/08 , C07D339/04 , C07F17/02 , C07C33/46 , C07C35/32 , C07C33/18 , C07C33/22
摘要： A catalytic transfer hydrogenation process is provided. The catalyst employed in the process is a metal hydrocarbyl complex which is coordinated to defined bidentate ligands substituted with at least one group selected from an optionally substituted sulphonated hydrocarbyl group, a sulphonated perhalogenated hydrocarbyl group, or an optionally substituted sulphonated heterocyclyl group. Preferred metals include rhodium, ruthenium and iridium. Preferred bidentate ligands are diamines and aminoalcohols, particularly those comprising chiral centres. The hydrogen donor is advantageously a secondary alcohol or a mixture of triethylamine and formic acid. The process can be employed to transfer hydrogenate ketones and imines, which are preferably prochiral. Catalysts for use in such a process are also provided.
摘要翻译：提供催化转移氢化方法。在该方法中使用的催化剂是金属烃基络合物，其与由至少一个选自任选取代的磺化烃基，磺化的全卤代烃基或任选取代的磺化杂环基的基团配位的二齿配体配位。优选的金属包括铑，钌和铱。优选的二齿配体是二胺和氨基醇，特别是包含手性中心的那些。氢供体有利地是仲醇或三乙胺和甲酸的混合物。该方法可用于转移氢化酮和亚胺，其优选是前手性的。还提供了用于这种方法的催化剂。

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