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    • 8. 发明公开
    • RAPID MIXING POLYMERIZATION PROCESS
    • EP4424413A1
    • 2024-09-04
    • EP23158992.0
    • 2023-02-28
    • Borealis AG
    • BERGSTRA, MichielSLEIJSTER, HenryWURNITSCH, Christof
    • B01J19/00B01J19/18C08F222/08B01J19/20
    • B01J19/0066B01J19/1843B01J2204/00220130101B01J19/1875C08F222/08B01J2219/0016820130101B01J19/20B01F27/861B01F27/92B01F27/1921
    • The present invention relates to a process for polymerization of at least one olefin monomer in a polymerization reactor assembly, the polymerization reactor assembly comprising a reactor (1) having a housing (2) defining an inner space (3), the reactor (1) comprising a) at least one inlet (4); b) at least one outlet (5); c) a draft tube (6) having a substantially cylindrical shape and an inner space (7), wherein the draft tube (6) is located within the inner space (3) of the reactor (1) so that an upper opening (10) and a lower opening (11) of the draft tube (6) are fluidly connected with the inner space (3) of the reactor (1), and d) a stirrer (12) located within the inner space (3) of the reactor (1) and comprising a stirrer blade (14) having a helical shape, wherein the axis (8) of the draft tube and the axis (15) of the stirrer blade (14) are coinciding, the stirrer blade (14) extending concentrically with respect to the draft tube (6) and the housing (2) of the reactor (1), and e) secondary mixing means (23) for mixing the fluid inside the reactor (1) by rotating motion, wherein the inner space (3) of the reactor (1) comprises sections A, B, C, and D, wherein section A is the space defined by the upper end of the housing (2) of the reactor (1) and a first plane (10a) oriented transversally to the axis (8) of the draft tube and arranged at the upper end of the stirrer (12), section B is the space defined by the housing (2) of the reactor (1), the outer surface of the draft tube (6), the first plane (10a) and a second plane (11a) oriented transversally to the axis (8) of the draft tube and arranged at the lower opening (11) of the draft tube (6), section C is the space defined by the lower end of the housing (2) of the reactor (1) and the second plane (11a), and section D is the inner space (7) of the draft tube (6), wherein the stirrer (12) is rotatable inside the housing (2) of the reactor (1) to provide a mixing motion to fluids if present inside the reactor (1), the process comprising the steps of I. introducing the at least one olefin monomer, at least one polymerization catalyst, and at least one solvent via the at least one inlet (4) into section C to form a reaction mixture, II. rotating the stirrer (12) to force at least a part of the reaction mixture from section C via section B to section A and from section A via section D to section C, III. thereby polymerizing the at least one olefin monomer forming a polymer in said reaction mixture, IV. withdrawing at least a part of the reaction mixture via the at least one outlet (5) from section A to obtain an olefin polymer as a product.
    • 9. 发明申请
    • A DEGRADING STATION FOR DEGRADING AN ORGANIC MATERIAL HAVING LONG MOLECULAR CHAINS AND A RELATIVE APPARATUS
    • 降解具有长链分子链的有机物质的降解装置和相关装置
    • WO2017103753A1
    • 2017-06-22
    • PCT/IB2016/057486
    • 2016-12-09
    • PECCI, Giorgio
    • PECCI, Giorgio
    • B09B3/00B01J19/18B09B5/00C10G3/00
    • B09B3/0083B01J19/1843B01J19/1887B09B5/00C10G1/02C10G1/10C10G3/40C10G9/00Y02P30/20
    • A degrading station and apparatus for degrading a material having long molecular chains and obtaining a fluid material having short molecular chains. It comprises: a chamber (2) comprising a first wall (20), a first opening (21 ) for inlet of an organic material having long chains, and a second opening (22) for outlet of a fluid organic material having short chains; a second wall (3) arranged in the chamber (2), facing the first wall (20) for defining a space (4), and dimensioned so as to enable communication between the openings. The first wall (20) and/or the second wall (3) is activatable in rotation so that the organic material in inlet crosses the space (4) in an advancement direction (Y) which goes from the first opening (21) to the second opening (22). The first wall (20), the second wall (3), the first opening (21) and the second opening (22) are reciprocally arranged and conformed in such a way that when one of the walls rotates, the tangential velocity perpendicular to the advancement direction (Y) at the rotating wall increases in the advancement direction (Y) along the whole space (4) so that a friction is determined between the molecular chains of the organic material which in turn determines a production of thermal energy internally of the material so as to degrade the material having long molecular chains and obtain the fluid material having short molecular chains.
    • 用于降解具有长分子链的材料并获得具有短分子链的流体材料的降解站和设备。 它包括:包含第一壁(20),用于具有长链的有机材料的入口的第一开口(21)和用于具有短链的流体有机材料的出口的第二开口(22)的腔室(2) 布置在所述腔室(2)中的第二壁(3),所述第二壁面对所述第一壁(20)以限定空间(4),并且所述第二壁的尺寸设计成使得所述开口之间能够连通。 第一壁(20)和/或第二壁(3)可旋转地启动,使得入口中的有机材料沿着从第一开口(21)到第二开口(21)的前进方向(Y)穿过空间(4) 第二开口(22)。 第一壁(20),第二壁(3),第一开口(21)和第二开口(22)以这样的方式相互配置和相互配合,即当其中一个壁旋转时,切向速度垂直于 沿着整个空间(4)在旋转壁处的前进方向(Y)沿着前进方向(Y)增加,从而在有机材料的分子链之间确定摩擦,这又决定了有机材料的内部产生热能 从而降解具有长分子链的材料并获得具有短分子链的流体材料。