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    • 3. 发明申请
    • AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF
    • AZO染料,其制备方法及其用途
    • WO2010046192A2
    • 2010-04-29
    • PCT/EP2009062300
    • 2009-09-23
    • HUNTSMAN ADV MAT SWITZERLANDPETERMANN RALFSUPPIGER CHRISTIANLAUK URS
    • PETERMANN RALFSUPPIGER CHRISTIANLAUK URS
    • C09B29/00
    • C09B29/0003C09B29/0033C09B29/0059C09B29/0081C09B29/0085C09B29/081C09B29/0811C09B29/0833C09B29/24C09B29/26Y10S8/92
    • The present invention relates to dyes of formula (I) wherein R1 and R2 are each independently of the other hydrogen, vinyl, allyl or C1-C6alkyl which is unsubstituted or substituted by cyano, carboxy, hydroxy, C1-C6alkoxy or C6-C24aryl, R3 is hydrogen, C1-C6alkyl or C6-C24aryl, R4 is hydrogen, C1-C6alkyl or C6-C24aryl, 2-Cyano-C1-C6alkyl, 2-Alkoxy-C1-C6alkyl, 2-Oxo-C1-C6alkyl, n is 0, 1 or 2, and D denotes a radical of formula (2), (3), (4), (5), (6) or (7) wherein R5 is hydrogen, nitro, cyano or halogen, R6 and R7 are each independently of the other hydrogen, nitro, cyano or halogen, R8 and R9 are each independently of the other hydrogen, nitro, cyano or halogen, R10 and R11 are each independently of the other nitro, cyano, trifluoromethyl, carboxy, C1-C6alkyl, C1-C6alkoxy, C1-C6acylamino or halogen, R12 and R13 are each independently of the other hydrogen, nitro, cyano, trifluoromethyl, carboxy, C1-C6alkoxycarbonyl, C1-C6alkylsulfonyl, C1-C6alkylsulfonylamino, C1-C6acylamino or halogen, R14 represents nitro, cyano or halogen and R15 is C1-C6alkyl, and R16 is nitro, cyano, trifluoromethyl, carboxy, C1-C6alkylsulfonyl, C1-C6alkylsulfonylamino, C1-C6acylamino or halogen, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fibre materials, more especially textile materials.
    • 本发明涉及式(I)的染料,其中R 1和R 2各自独立地为未被取代或被氰基,羧基,羟基,C 1 -C 6烷氧基或C 6 -C 24芳基取​​代的其它氢,乙烯基,烯丙基或C 1 -C 6烷基, R3是氢,C1-C6烷基或C6-C24芳基,R4是氢,C1-C6烷基或C6-C24芳基,2-氰基-C1-C6烷基,2-烷氧基-C1-C6烷基,2-氧代-C1-C6烷基, (2),(3),(4),(5),(6)或(7)的基团,其中R5是氢,硝基,氰基或卤素,R6和R7 各自独立为氢,硝基,氰基或卤素,R 8和R 9各自独立地为氢,硝基,氰基或卤素,R 10和R 11各自独立地为其他硝基,氰基,三氟甲基,羧基,C1- C6烷基,C1-C6烷氧基,C1-C6烷氨基或卤素,R12和R13各自独立地为氢,硝基,氰基,三氟甲基,羧基,C1-C6烷氧基羰基,C1-C6烷基磺酰基,C1-6烷基磺酰基氨基, R14代表硝基,氰基或卤素,R15代表C1-C6烷基,R16代表硝基,氰基,三氟甲基,羧基,C1-C6烷基磺酰基,C1-C6烷基磺酰氨基,C1-C6酰氨基或卤素,和其制备方法和 涉及其在染色或印刷半合成和特别合成的疏水性纤维材料,尤其是纺织材料中的用途。
    • 4. 发明申请
    • ACCELERATOR SYSTEMS FOR LOW-TEMPERATURE CURING
    • 用于低温固化的加速器系统
    • WO2004092244A2
    • 2004-10-28
    • PCT/EP2004050503
    • 2004-04-13
    • HUNTSMAN ADV MAT SWITZERLANDWEIDMANN ULRICH
    • WEIDMANN ULRICH
    • C08G59/68C08G59/00
    • C08G59/686C08G59/68
    • Composition comprising as component A) a 1-imidazoly[mothyl-substituted 2-naphthol compound of the general formula (I) where R1, R2 and R3 each independently of one another are H; C1-17alkyl; C3-12cycloalkyl, optionally substituted by C1-4alkyl groups; C4-2ocycloalkyl-alkyl, optionally substituted by C1-4alkyl groups; C6-10aryl, optionally substituted by 1-3 C1-4alkyl groups; C7-15,phonylalkyl, optionally substituted by 1-3 C1-4alkyl groups; C3-17alkenyl; C3-12alkynyl; or aromatic or aliphatic C3-12acyf; R4, R5, R6, R7, R8, and R9 each independently of one another are H; C1-12alkyl; C3-12cycloalkyl, optionally substituted by C1-4alkyl groups; C4-20cycloalkyl-alkyl, optionally substituted by C1-4alkyf groups; C6-10aryl, optionally substituted by 1-3 C1-4alkyl groups; C7-15phenylalkyl, optionally substituted by 1-3 C1-4alkyl groups; C3-17alkenyl; C3-12alkynyl; C1-12alkoxy; or OH; and as component B) a phenol which is liquid at room temperature, the weight ratio of component A) to component B) being from 10:90 to 80:20. as accelerator for curable epoxy resin compositions which are used as a compression moulding compound, sinter powder, encapsulating system, casting resin, or for producing prepregs and laminates having very good interlaminar shear strength values using impregnating methods or injection methods, for producing components, especially components of large surface area.
    • 组合物,其包含作为组分A)的通式(I)的1-咪唑基[桂基取代的2-萘酚化合物,其中R 1,R 2和R 3各自独立地为H; C1-17alkyl; 任选被C 1-4烷基取代的C 3-12环烷基; 任选被C 1-4烷基取代的C 4-8环烷基 - 烷基; 任选被1-3个C 1-4烷基取代的C 6-10芳基; C7-15,任选被1-3个C 1-4烷基取代的芳基烷基; C3-17alkenyl; C3-12alkynyl; 或芳族或脂族C3-12acyf; R 4,R 5,R 6,R 7,R 8和R 9各自独立地为H; C1-12烷基; 任选被C 1-4烷基取代的C 3-12环烷基; 任选被C 1-4烷基取代的C 4-20环烷基 - 烷基; 任选被1-3个C 1-4烷基取代的C 6-10芳基; 任选被1-3个C 1-4烷基取代的C 7-15苯基烷基; C3-17alkenyl; C3-12alkynyl; C 1-12烷氧基; 或OH; 和作为组分B)在室温下为液体的苯酚,组分A)与组分B)的重量比为10:90至80:20。 作为压缩成型用化合物的烧结粉末,密封体系,铸塑用树脂,或用于制备具有非常好的层间剪切强度值的预浸料和层压材料的加固剂,可以使用浸渍方法或注射方法制备组分,特别是 表面积大的部件。
    • 5. 发明申请
    • MIXTURES OF FIBRE-REACTIVE DYES AND THEIR USE IN A METHOD FOR DI- OR TRICHROMATIC DYEING OR PRINTING
    • 纤维反应性染料的混合物及其在二色或三色染色或印刷方法中的用途
    • WO2011101185A9
    • 2012-03-29
    • PCT/EP2011050397
    • 2011-01-13
    • HUNTSMAN ADV MAT SWITZERLANDTZIKAS ATHANASSIOSROENTGEN GEORGCASARTELLI MARCOCODEMO REMOLANDRE JEAN-FRANCOIS
    • TZIKAS ATHANASSIOSROENTGEN GEORGCASARTELLI MARCOCODEMO REMOLANDRE JEAN-FRANCOIS
    • C09B67/22C09B62/513D06P1/38D06P3/66
    • C09B62/513C09B62/4413C09B62/4415C09B67/0042C09B67/0047C09B67/0052D06P1/38D06P3/663Y10S8/917Y10S8/918Y10S8/919Y10S8/924Y10S8/926
    • Dye mixtures, comprising at least one red dyeing dye of the formula (1) and at least one blue, yellow, orange or brown dyeing dye from the group of the formulae (2), (3), (4), (5) and (6), wherein B is an aliphatic bridging member, R1, R3 and R8 are each independently of the others hydrogen or C1-C4alkyl, R2, R4, R5, R9, R11, R12, R13, R14, R15 and R16 are each independently of the others hydrogen, C1-C4alkyl, C1-C4alkoxy or sulfo, R6 and R10 are each independently of the other amino or C1-C4alkyl, (R7)j denotes j identical or different substituents selected from the group C2-C4alkanoylamino, ureido, C1-C4alkyl and C1-C4alkoxy, (R17)i denotes i identical or different substituents selected from the group C2-C4alkanoylamino, ureido, sulfo, C1-C4alkyl and C1-C4alkoxy, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Z1, Z2 and Z3 are each independently of the others a fibre-reactive group of the formula -SO2-Y8, (7a) or -NH-CO-(CH2)2-3-SO2-Y9 (7b), Y1, Y2, Y3, Y4, Y5, Y6, Y7, Y8 and Y9 are each independently of the others vinyl or a radical -CH2-CH2-U and U is a group removable under alkaline conditions, i, j, k and l are each independently of the other the number 0, 1 or 2, m is the number 1 or 2, n and u are each independently of the other the number 1, 2 or 3, p and q are each independently of the other the number 0 or 1, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
    • 包含至少一种式(1)的红染色剂和至少一种式(2),(3),(4),(5)的基团的蓝,黄,橙或棕染色染料的染料混合物, 和(6)其中B是脂族桥连构件,R 1,R 3和R 8各自独立地为氢或C 1 -C 4烷基,R 2,R 4,R 5,R 9,R 11,R 12,R 13,R 14,R 15和R 16为 各自独立地为氢,C 1 -C 4烷基,C 1 -C 4烷氧基或磺基,R 6和R 10各自独立地为其它氨基或C 1 -C 4烷基,(R 7)j表示相同或不同的选自C 2 -C 4烷酰基氨基, 脲基,C 1 -C 4烷基和C 1 -C 4烷氧基,(R 17)i表示相同或不同的选自C 2 -C 4烷酰基氨基,脲基,磺基,C 1 -C 4烷基和C 1 -C 4烷氧基,X 1,X 2,X 3,X 4,X 5和 X 6各自独立地为卤素,3-羧基吡啶-1-基或3-氨基甲酰基吡啶-1-基,Z1,Z2和Z3各自独立地为式-SO2-Y8的纤维反应性基团( 7A) 或-NH-CO-(CH2)2-3-SO2-Y9(7b),Y1,Y2,Y3,Y4,Y5,Y6,Y7,Y8和Y9各自独立地为乙烯基或基团-CH2- CH2-U和U是在碱性条件下可除去的基团,i,j,k和l各自独立于数字0,1或2中的另一个,m是数字1或2,n和u各自独立地为 数字1,2或3中的另一个,p和q各自独立于数字0或1中的另一个,r和s各自独立于数字0或1中的另一个,并且t是数字0,1或2, r,s和t的总和为2或3,特别适用于纤维素纤维材料的二色或三色染色或印花,并且具有良好的再现性和良好的全面牢固性能的产量染色或印花。
    • 9. 发明申请
    • REACTIVE DYES, THEIR PREPARATION AND THEIR USE
    • 反应性染料及其制备及其使用
    • WO2006042802A9
    • 2007-07-26
    • PCT/EP2005055120
    • 2005-10-10
    • HUNTSMAN ADV MAT SWITZERLANDSCHMIEDL JUERGENSCHOEHN DAMIEN
    • SCHMIEDL JUERGENSCHOEHN DAMIEN
    • C09B62/515C09B62/095C09B62/44C09D11/00C09D11/02
    • C09B62/4416
    • Reactive dyes of formula (1), wherein R 1 is hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, (R 2 ) s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C 1 -C 4 alkyl, C 2 -C 4 alkanoylamino, C 1 -C 4 alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, Me is chromium, cobalt or iron, X is chlorine, T is a fibre-reactive radical of formula -NH-(CH 2 ) 2-3 -SO 2 -Z (2a), -NH-(CH 2 ) 2-3 -O-(CH 2 ) 2-3 -SO 2 -Z (2b), formula (2c), formula (2d), formula (2e), formula (2f), (R 3 ) 0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy and sulfo, Z is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(HaI)-CH 2 -HaI or -C(HaI)=CH 2 group, Hal is halogen, s is the number 0, 1 , 2 or 3 and m, n, r and q are each independently of the others the number 0 or 1 , are especially suitable for dyeing synthetic polyamide fibre materials and yield dyeings or prints having good wet-fastness properties.
    • 式(1)的活性染料,其中R 1是氢或未取代或取代的C 1 -C 4烷基,(R 1) 表示与卤素,硝基,未取代或卤素取代的C 1 -C 4基团相同或不同的取代基。 烷基,C 2 -C 4烷酰基氨基,C 1 -C 4烷基磺酰基,氨基甲酰基,氨磺酰基和磺基 ,Me是铬,钴或铁,X是氯,T是式-NH-(CH 2 CH 2)2-3 -SO 3的纤维反应性基团 (2),-NH-(CH 2)2 - (O)(CH 2)2 - (2b),式(2c),式(2d),式(2e),式(2f),(R< SUB> 0-2表示0至2个相同或不同的取代基,基团为卤素,C 1 -C 4烷基, 烷基,C 1 -C 4烷氧基和磺基,Z是乙烯基或-CH 2 CH 2 -CH 2 -U根本和U是一个可以移除的组 碱性条件,Q是-CH(H 1)-CH 2 -H a或-C(H 1)= CH 2 H 2基,Hal是卤素,s是0 ,1,2或3,m,n,r和q各自独立地为数字0或1,特别适用于染色合成聚酰胺纤维材料,并产生具有良好耐湿性能的染色或印花。