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1. 发明申请

US20060122345A1 Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins 失效
公开(公告)号：US20060122345A1
公开(公告)日：2006-06-08
申请号：US10537677
申请日：2003-12-02
申请人： Jorg Schulte , Jorg Schottek , Yoshikuni Okumura
发明人： Jorg Schulte , Jorg Schottek , Yoshikuni Okumura
IPC分类号： B01J31/00 , C07F17/00 , C08F4/44
CPC分类号： C07F17/00 , B01J31/2295 , B01J2531/48 , C07C13/465 , C08F4/65912 , C08F4/65916 , C08F110/06 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/03
摘要： The present invention relates to organometallic transition metal compounds of formula (I) where M1 is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements or the lanthanides, X are identical or different and are each halogen, hydrogen, C1-C20-alkyl , C2-C20-alkenyl, C6-C22-aryl, alkylaryl or arylalkyl each having from 1 to 10 carbon atoms in the alkyl part and from 6 to 22 carbon atoms in the aryl part, —OR6 or —NR6R7, where two radicals X may also be joined to one another, n is a natural number from 1 to 4 which corresponds to the oxidation number of M1 minus 2, R1 is hydrogen or a C1-C40 radical, R2 is a substituted or unsubstituted C6-C40-aryl radical or C2-C40-heteroaromatic radical containing at least one heteroatom selected from the group consisting of O, N, S and P, R3 is hydrogen or a C1-C40 radical, or the radicals R2 and R3 together form a ring system, R4 is hydrogen or a C1-C40 radical, R5 is a C1-C40 radical, and Z is a divalent group CR8R9—CR10R11, where R8, R9, R10 and R11 are identical or different and are each hydrogen or a C1-C40 radical, biscyclopentadienyl ligand systems having such a substitution pattern, catalyst systems comprising at least one of the organometallic transition metal compounds of the present invention, a process for preparing polyolefins by polymerization or copolymerization of at least one olefin in the presence of one of the catalyst systems of the present invention and the use of the biscyclopentadienyl ligand systems of the present invention for preparing organometallic transition metal compounds.

2. 发明申请

US20060052542A1 Polyethylene composition for producing l-ring drums 审中-公开
标题翻译：聚乙烯组合物，用于生产l环鼓
公开(公告)号：US20060052542A1
公开(公告)日：2006-03-09
申请号：US10538894
申请日：2003-12-10
申请人： Joachim Berthold , Ludwig Bohm , Peter Krumpel , Rainer Mantel
发明人： Joachim Berthold , Ludwig Bohm , Peter Krumpel , Rainer Mantel
IPC分类号： C08L23/04
CPC分类号： C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2207/068 , C08L2666/02 , C08L2666/06
摘要： The invention relates to a polyethylene composition with multimodal molecular mass distribution, which is particularly suitable for the blow molding of L-ring drums having a volume in the range of from 50 to 250 dm3 (I). The composition has a density in the range of from 0.950 to 0.956 g/cm3 at 23° C. and a MFR1gp/21.6 in the range from 1.5 to 3.5 dg/min. It comprises from 35 to 45% by weight of a low-molecular-mass ethylene homopolymer A, from 34 to 44% by weight of a high-molecular-mass copolymer B made from ethylene and from another 1-olefin having from 4 to 8 carbon atoms, and from 18 to 26 % by weight of an ultrahigh-molecular-mass ethylene copolymer C.
摘要翻译：本发明涉及具有多峰分子量分布的聚乙烯组合物，其特别适用于体积在50-250dm 3（I）范围内的L型环鼓的吹塑。组合物在23℃下的密度范围为0.950-0.956g / cm 3，MFR1 / 1cp / 21.6℃范围为1.5-3.5dg /分钟它包含35至45重量％的低分子量乙烯均聚物A，34至44重量％的由乙烯制成的高分子量共聚物B和具有4至8个的另外的1-烯烃碳原子和18至26重量％的超高分子量乙烯共聚物C.

3. 发明申请

US20060167195A1 Process for the copolymerization of ethylene 失效
标题翻译：乙烯共聚方法
公开(公告)号：US20060167195A1
公开(公告)日：2006-07-27
申请号：US10529532
申请日：2003-09-10
申请人： Luigi Resconi , Nicoletta Mascellani
发明人： Luigi Resconi , Nicoletta Mascellani
IPC分类号： C08F4/44
CPC分类号： C08F210/16 , C08F4/65912 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/17 , C08F2500/03
摘要： A process for producing a copolymer of ethylene containing from 0.1 to 99% by mol of one or more derived units of alpha-olefins of formula CH2═CHA, wherein A is a C2-C20 alkyl radical, comprising contacting, under polymerization conditions, ethylene and one or more alpha-olefins in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I): wherein M is zirconium, titanium or hafnium; X, same or different, is a hydrogen atom, a halogen atom, or an hydrocarbon group; R1, is a hydrocarbon group; R2 R3, R4, R5 and R6, are hydrogen atoms or hydrocarbon groups; Q is a radical of formula (II), being bonded to the indenyl at the position marked by the symbol *; (II) wherein: T1, T2, T3, T4 and T5, are carbon atoms (C) or nitrogen atoms (N); m1, m2, m3, m4 and m5 are 0 or 1; R7, R8, R9, R10 and R11 are hydrogen atoms or hydrocarbon groups; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：一种制备乙烯共聚物的方法，该乙烯共聚物含有0.1-99％（摩尔）一种或多种衍生的式CH 2 -CH 2的α-烯烃单元，其中A是C < 包括在聚合条件下使乙烯和一种或多种α-烯烃在催化剂体系的存在下接触，所述催化剂体系可通过以下方式获得：a）式（Ⅴ）的茂金属化合物 I）：其中M是锆，钛或铪; X相同或不同，为氢原子，卤素原子或烃基; R 1是烃基; R 2，R 3，R 4，R 5和R 6都是氢原子或烃基; Q是式（II）的基团，在由符号*标记的位置键合到茚基上; （II）其中：T 1，T 2，T 3，T 4和T 5 碳原子（C）或氮原子（N）; m 1，m 2，m 3，m 4和m 5 5是 0或1; R 7，R 8，R 9，R 10和R 11均为氢原子或烃基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

4. 发明授权

US08759460B2 Process for the polymerization of ethylene, and ethylene polymers having broad molecular weight distribution and long-chain branching 有权
标题翻译：乙烯聚合方法和具有宽分子量分布和长链支化的乙烯聚合物
公开(公告)号：US08759460B2
公开(公告)日：2014-06-24
申请号：US13130221
申请日：2009-11-30
申请人： Eleonora Ciaccia , Iakovos Vittorias , Shahram Mihan , Lenka Lukesova , Dieter Lilge , Maclovio Herrera Salinas , Gerhardus Meier , Gerd Mannebach
发明人： Eleonora Ciaccia , Iakovos Vittorias , Shahram Mihan , Lenka Lukesova , Dieter Lilge , Maclovio Herrera Salinas , Gerhardus Meier , Gerd Mannebach
IPC分类号： C08F10/02 , C08F10/04 , C08F10/06 , C08F10/08 , C08F10/14 , C08F110/02 , C08F210/16 , C08F4/70 , C08F4/80
CPC分类号： C08F10/02 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2410/04 , C08F4/6555 , C08F4/7042 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/11 , C08F2500/10
摘要： New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5 s−1, at 150° C.), branching index g′ equal or lower than 0.9 (at Mw of 2·106 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100° C., for a time of at least 10 minutes.
摘要翻译：新的乙烯聚合物具有宽分子量分布和长链支化，首先是高分子量级分; 聚合物具有等于或高于1.4的应变硬化（在150s的恒定伸长率为0.5s -1，支化指数g'等于或等于0.9）（Mw为2·10 6 g / mol）。通过使用包含基于具有三齿配体的后过渡金属组分的聚合催化剂和在高于100℃的温度下退火的齐格勒聚合催化剂至少10分钟的混合催化剂体系来制备聚合物。

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