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    • 5. 发明申请
    • Method for producing a poly-1olefin in the presence of a ziegler catalyst
    • 在齐格勒催化剂存在下制备聚-1-烯烃的方法
    • US20050239978A1
    • 2005-10-27
    • US10514095
    • 2003-05-22
    • Ludwig BohmJoachim Berthold
    • Ludwig BohmJoachim Berthold
    • C08F10/00C08F4/44C08F4/60C08F4/658C08F10/02C08F110/02
    • C08F110/02C08F10/02C08F4/6555C08F2500/12C08F2500/18C08F2500/24
    • The invention relates to a method for producing a poly-1-olefin by polymerization of a 1-olefin of the formula R4C═CH2, in which R4 is hydrogen or an alkyl radical having from 1 to 10 carbon atoms, in suspension, in solution or in the gas phase, at a temperature of from 20 to 200° C. and a pressure of from 0.5 to 50 bar, in the presence of a catalyst which consists of the product of the reaction of a magnesium alkoxide with a transition-metal compound (component a) and an organometallic compound (component b), whose component (a) has been produced by reacting a transitionmetal compound of titanium, zirconium, vanadium or chromium with a gelatinous dispersion of the magnesium alkoxide in an inert hydrocarbon. In accordance with the invention, the gelatinous dispersion is obtained by stirring, using a stirring element, or shearing, using a high-performance shearing tool, a suspension of a magnesium alkoxide powder having a mean particle size, expressed as the d50 value, in the range from 50 to 1000 um, in an aliphatic hydrocarbon in which the magnesium alkoxide particles are insoluble. The suspension has, before conversion into the dispersion, been subjected to heat treatment at a temperature in the range from 40 to 150° C. over a period of from 10 to 100 hours.
    • 本发明涉及通过聚合式R 4 C-CH 2 2-的1-烯烃制备聚-1-烯烃的方法,其中R 0 > 4是氢或具有1至10个碳原子的烷基,悬浮液,溶液或气相中,温度为20-200℃,压力为0.5至50 在由醇盐与过渡金属化合物(组分a)的反应产物和有机金属化合物(组分b)组成的催化剂的存在下,其组分(a)通过使 钛,锆,钒或铬的过渡金属化合物与烷氧基镁在惰性烃中的凝胶状分散体。 根据本发明,通过使用搅拌元件搅拌或使用高性能剪切工具剪切平均粒度的烷氧基镁粉末的悬浮液(表示为d< 在50〜1000μm的范围内,在烷氧基镁颗粒不溶的脂族烃中。 悬浮液在转化成分散体之前,在10〜100小时的时间内,在40〜150℃的温度下进行热处理。