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    • 1. 发明授权
    • Liquid crystalline diketopyrrolopyrroles
    • 液晶二酮吡咯并吡咯
    • US5969154A
    • 1999-10-19
    • US988419
    • 1997-12-10
    • Zhimin HaoAbul IqbalNancy TebaldiKlaus Praefcke
    • Zhimin HaoAbul IqbalNancy TebaldiKlaus Praefcke
    • C07D487/04C09K19/34C07D317/12C07D319/06
    • C07D487/04C09K19/3483
    • A liquid crystalline compound of formula ##STR1## wherein B and D are each independently of the other C.sub.6 -C.sub.24 alkyl, ##STR2## L is ##STR3## methyl or C.sub.10 -C.sub.18 alkyl, wherein R.sub.1 is C.sub.4 -C.sub.18 alkyl, with the proviso that when L is methyl, at least one of B and D is C.sub.6 -C.sub.24 alkyl;R2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, cyano or nitro,R3, R4 and R5 are each independently of one another hydrogen, OR6, SR6, SeR6, --NHR6, --NR6R7, ##STR4## with the proviso that at least one of R3, R4 and R5 is not hydrogen, R6 is C.sub.7 -C.sub.37 alkyl, C.sub.7 -C.sub.37 alkylene or C.sub.5 -C.sub.18 alkyl which is interrupted by 1 to 6 hetero atoms selected from the group consisting of O, S and N,R7 is hydrogen or R9,R8 is hydrogen or C.sub.1 -C.sub.4 alkyl, andR9 is C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkylene or C.sub.3 -C.sub.12 alkyl which is interrupted by 1 to 6 hetero atoms selected from the group consisting of O, S and N.
    • 一种下式的液晶化合物,其中B和D各自独立于C 6 -C 24烷基,L是甲基或C 10 -C 18烷基,其中R 1是C 4 -C 18烷基,条件是当L是甲基时,B和 D是C 6 -C 24烷基; R 2是氢,C 1 -C 4烷基,C 1 -C 4烷氧基,卤素,氰基或硝基,R 3,R 4和R 5各自彼此独立地是氢,OR 6,SR 6,SeR 6,-NHR 6,-NR 6 R 7,条件是至少一个 的R 3,R 4和R 5不是氢,R 6是被1至6个选自O,S和N的杂原子间隔的C 7 -C 37烷基,C 7 -C 37亚烷基或C 5 -C 18烷基,R 7是氢或R 9, R8为氢或C1-C4烷基,R9为C1-C12烷基,C2-C12亚烷基或C3-C12烷基,其被1至6个选自O,S和N的杂原子间隔。
    • 8. 发明授权
    • Pyrrolo[3,4-c]pyrroles containing cyanimino groups
    • 含有氰氨基的吡咯并[3,4-c]吡咯
    • US5527922A
    • 1996-06-18
    • US407746
    • 1995-03-21
    • John S. ZambounisZhimin HaoAbul Iqbal
    • John S. ZambounisZhimin HaoAbul Iqbal
    • C07D487/04C08K5/3412C08K5/3415C08L101/00C09B57/00C09K11/06
    • C07D487/04C09B57/004
    • The invention relates to pyrrolo[3,4-c]pyrroles of formula ##STR1## wherein D and E are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.7 -C.sub.10 aralkyl, unsubstituted phenyl or phenyl which is substituted by chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl or nitro, or --COO--C.sub.1 -C.sub.5 alkyl or a group --COOR.sub.8,wherein R.sub.8 is benzyl, piperidyl or a group ##STR2## and X and Y are N--CN or O, with the proviso that at least one of X or Y N--CN must be N--CN.These pyrrolo[3,4-c]pyrroles are preeminently suitable for use as colorants, i.e. as pigments or as polymer-soluble dyes, for colouring high molecular weight organic material. They are distinguished by unexpectedly high solid-state fluorescence.The substituents A and B are as defined in claim 1.
    • 本发明涉及式(I)的吡咯并[3,4-c]吡咯,其中D和E各自独立地为另一个氢,C 1 -C 18烷基,C 2 -C 4链烯基,C 7 -C 10芳烷基,未取代的苯基或苯基, 被氯,溴,C 1 -C 6烷基,C 1 -C 4烷氧基,三氟甲基或硝基或-COO-C 1 -C 5烷基或-COOR 8基团取代,其中R 8是苄基,哌啶基或基团,X和Y是N -CN或O,条件是X或Y N-CN中的至少一个必须是N-CN。 这些吡咯并[3,4-c]吡咯非常适合用作着色剂,即作为颜料或作为聚合物可溶性染料用于着色高分子量有机材料。 它们的突出特征是出乎意料的高固态荧光。 取代基A和B如权利要求1中所定义。
    • 9. 发明授权
    • Pyrrolo 3,4-c!pyrroles containing amine oxide groups
    • 含有氧化胺基团的吡咯并[3,4-c]吡咯
    • US5502196A
    • 1996-03-26
    • US404012
    • 1995-03-14
    • Zhimin HaoAbul IqbalRudolf Kirchmayr
    • Zhimin HaoAbul IqbalRudolf Kirchmayr
    • C07D487/04C08K5/3412C08K5/3415C09B57/00G03G5/06C07D211/10
    • C07D487/04G03G5/0648G03G5/0661
    • The invention relates to pyrrolo 3,4-c!pyrroles of formula ##STR1## wherein A and B are each independently of the other a group of formula ##STR2## or Q, wherein Q is a 5- or 6-membered heterocyclic aromatic amine oxide radical which is unsubstituted or substituted by one, two or three C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or ##STR3## and which may contain one or two fused benzene rings, R.sub.1 and R.sub.2 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy, C.sub.1 -C.sub.18 alkylmercapto, --CN, --NO.sub.2 or trifiuoromethyl, D and E are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.7 -C.sub.10 aralkyl, unsubstituted phenyl or phenyl which is substituted by chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 alkoxy, trifiuoromethyl or nitro, with the proviso that at least one of the sustituents A and B is an amine oxide radical Q.These novel diketopyrrolo 3,4-c!pyrroles are suitable for use as pigments, but especially as photoconductive substances in electrophotographic photoreceptors.
    • 本发明涉及式(I)的吡咯并[3,4-c]吡咯,其中A和B各自独立地为下式的基团:其中Q为5- 或6元杂环芳族氧化胺基团,其未被取代或被一个,两个或三个C 1 -C 18烷基,C 1 -C 18烷氧基或者可以含有一个或两个稠合苯环的取代基,R 1和R 2各自独立地为 其它氢,卤素,C 1 -C 18烷基,C 1 -C 18烷氧基,C 1 -C 18烷基巯基,-CN,-NO 2或三氟甲基,D和E各自独立地为C 1 -C 18烷基,C 2 -C 4链烯基,C 7 -C 10芳烷基, 或被氯,溴,C 1 -C 6烷基,C 1 -C 4烷氧基,三氟甲基或硝基取代的苯基,条件是至少一个取代基A和B是氧化胺基团Q.这些新型二酮吡咯并[3,4- c]吡咯适合用作颜料,特别是作为电子照相感光体中的光导物质。